Effects of annealing parameters on phase, structure and thermochromic properties of VO2 (M) derived from nanostructured VO2(B)

• Autorzy: Barra Hamdi Muhyuddin , Chen Soo Kien , Tamchek Nizam , Talib Zainal Abidin , Lee Oon Jew , Tan Kar Ban

Identyfikatory

DOI

10.2478/msp-2020-0071

• Języki publikacji: EN

Abstrakty

EN

Synthesis of thermochromic VO₂ (M) was successfully done by annealing hydrothermally-prepared VO₂ (B) at different temperatures and times. Conversion of the metastable VO₂ (B) to the thermochromic VO₂ polymorph was studied using thermogravimetric analyzer (TGA) under N₂ atmosphere. Moreover, the phase and morphology of the synthesized samples were studied using X-ray diffraction (XRD) and field-emission scanning electron microscopy (FE-SEM), respectively. Accordingly, the XRD scans of all the annealed samples exhibited the presence of monoclinic VO₂ (M), while the FE-SEM images of the samples showed the formation of nanorods and nanospheres, particularly those heated at high temperatures (650 °C and 700 °C). Meanwhile, differential scanning calorimetry (DSC) was used to measure the phase transition temperature (tc), hysteresis, and enthalpy of the prepared VO₂. Based on these results, all samples displayed a tc of about 66 °C. However, the hysteresis was high for the samples annealed at lower temperatures (550 °C and 600 °C), while the enthalpy was very low for samples heated at lower annealing time (1.5 h and 1 h). These findings showed that crystallinity and nanostructure formation affected the thermochromic properties of the samples. In particular, the sample annealed at 650 °C showed better crystallinity and improved thermochromic behavior.

Słowa kluczowe

EN

annealing; hydrothermal synthesis; thermochromic; vanadium dioxide

• Wydawca: De Gruyter
• Czasopismo: Materials Science Poland
• Rocznik: 2020
• Tom: Vol. 38, No. 4
• Strony: 661--666
• Opis fizyczny: Bibliogr. 33 poz., rys., tab.

Twórcy

autor

Barra Hamdi Muhyuddin

• Department of Physics, Faculty of Science, Universiti Putra Malaysia, 43400 UPM Serdang, Selangor, Malaysia
• Physics Department, Mindanao State University – Main Campus, Marawi City, 9700, Philippines

autor

Chen Soo Kien

• Department of Physics, Faculty of Science, Universiti Putra Malaysia, 43400 UPM Serdang, Selangor, Malaysia

autor

Tamchek Nizam

• Department of Physics, Faculty of Science, Universiti Putra Malaysia, 43400 UPM Serdang, Selangor, Malaysia

autor

Talib Zainal Abidin

• Department of Physics, Faculty of Science, Universiti Putra Malaysia, 43400 UPM Serdang, Selangor, Malaysia

autor

Lee Oon Jew

• School of Fundamental Science, Universiti Malaysia Terengganu, 21300 Kuala Terengganu, Terengganu, Malaysia

autor

Tan Kar Ban

• Department of Chemistry, Faculty of Science, Universiti Putra Malaysia, 43400 UPM Serdang, Selangor, Malaysia

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Uwagi

Opracowanie rekordu ze środków MNiSW, umowa Nr 461252 w ramach programu "Społeczna odpowiedzialność nauki" - moduł: Popularyzacja nauki i promocja sportu (2021).