Influence of NaCl Additive on the Reduction Process of MoO₃ to Mo₂C by High-Purity CO Gas

• Autorzy: Que Biao-Hua , Wang Lu , Wang Bao , Chen Yi , Xue Zheng-Liang

Identyfikatory

DOI

10.24425/amm.2022.137819

• Języki publikacji: EN

Abstrakty

EN

In this work, influence of NaCl additive on the transformation process of MoO₃ to Mo₂C under pure CO atmosphere in the range of room temperature to 1170 K was investigated. The results showed that transformation of MoO₃ to Mo₂C can be roughly divided into two stages: the reduction of MoO₃ to MoO₂ (the first stage) and the carburization of MoO₂ to Mo₂C (the second stage). As to the first stage, it was found that increasing the content of NaCl (from 0 to 0.5 wt.%) was beneficial for the increase of reaction rate due to the nucleation effect; while when the content of NaCl increased to 2 wt.%, the reaction rate will be decreased in turn. As to the second stage, the results showed that reaction rate was decreased with the increase of NaCl, which may be due to the formation of low-melting point eutectic. The work also found that morphology of as-prepared Mo₂C was irregular and particle size of it was gradually increased with increasing the NaCl content. According to the results, the possible reaction mechanism was proposed.

Słowa kluczowe

EN

Mo2C; MoO3; CO; NaCl

• Wydawca: Institute of Metallurgy and Materials Science of Polish Academy of Sciences ; Committee of Materials Engineering and Metallurgy of Polish Academy of Sciences
• Czasopismo: Archives of Metallurgy and Materials
• Rocznik: 2022
• Tom: Vol. 67, iss. 2
• Strony: 787--796
• Opis fizyczny: Bibliogr. 41 poz., fot., rys., wzory

Twórcy

autor

Que Biao-Hua

• Wuhan University of Science And Technology, Hubei Provincial Key Laboratory For New Processes of Ironmaking and Steelmaking, Wuhan 430081, China

• https://orcid.org/0000-0002-5750-7879

autor

Wang Lu

• Wuhan University of Science and Technology, Hubei Provincial Key Laboratory for New Processes of Ironmaking and Steelmaking, Wuhan 430081, China
• Foshan (Southern China) Institute for New Materials, Foshan 528200, Guangdong, China

• https://orcid.org/0000-0002-0317-2225

autor

Wang Bao

• Wuhan University of Science and Technology, The State Key Laboratory of Refractories and Metallurgy, Wuhan 430081, China

• https://orcid.org/0000-0002-2987-7127

autor

Chen Yi

• Wuhan University of Science and Technology, The State Key Laboratory of Refractories and Metallurgy, Wuhan 430081, China

• https://orcid.org/0000-0002-9812-2836

autor

Xue Zheng-Liang

• Wuhan University of Science and Technology, The State Key Laboratory of Refractories and Metallurgy, Wuhan 430081, China

• https://orcid.org/0000-0002-0173-4909

Bibliografia

• [1] F.X. Ma, B.H. Wu, B.Y. Xia, C.Y. Xu, X.W. Lou, Angew. Chem., Int. Ed. 54 (51), 15395-15399 (2015).
• [2] E.J. Pavlina, J.G. Speer, C.J. Van Tyne, Scripta Mater. 66 (5), 243-246 (2012).
• [3] N. Perret, X. Wang, L. Delannoy, C. Potvin, C. Louis, M.A. Keane, J. Catal. 286, 172-183 (2012).
• [4] Y. Chen, S. Choi, L.T. Thompson, J. Catal. 343, 147-156 (2016).
• [5] H. Wang, S. Liu, K.J. Smith, J. Catal. 369, 427-439 (2019).
• [6] S. Liu, H. Wang, K.J. Smith, C.S. Kim, Energ. Fuel 31 (6), 6378-6388 (2017).
• [7] J.C. Schlatter, S.T. Oyama, J.E. Metcalfe III, J.M. Lambert Jr, Ind. Eng. Chem. Res. 27 (9), 1648-1653 (1988).
• [8] A. Szymańska-Kolasa, M. Lewandowski, C. Sayag, D. Brodzki, G. Djéga-Mariadassou, Catal. Today. 119 (1-4), 35-38 (2007).
• [9] T.C. Xiao, A.P. York, H. Al-Megren, C.V. Williams, H.T. Wang, M.L. Green, J. Catal. 202 (1), 100-109 (2001).
• [10] L. Wang, Z.L. Xue, A. Huang, F.F. Wang, ACS Omega. 4 (22), 20036-20047 (2019).
• [11] L. Wang, G.H. Zhang, K.C. Chou, J. Aust. Ceram. Soc. 54 (1), 97-107 (2018).
• [12] Z. Lv, J. Dang, Y. Wu, X. Lv, S. Zhang, J. Mater. Sci. 53 (14), 10059-10070 (2018).
• [13] J. Dang, G. Zhang, L. Wang, K. Chou, P.C. Pistorius, J. Am. Ceram. Soc. 99 (3), 819-824 (2016).
• [14] J.A. Nelson, M.J. Wagner, Chem. Mater. 14 (4), 1639-1642 (2002).
• [15] T. Hyeon, M. Fang, K.S. Suslick, J. Am. Chem. Soc. 118 (23), 5492-5493 (1996).
• [16] X. Liu, N Fechler, M. Antonietti, Chem. Soc. Rev. 42 (21), 8237-65 (2013).
• [17] L. Zhu, Q. Huang, Ceram. Int. 3 7(1), 239-255 (2011).
• [18] X. Chen, Y. Li, Y. Li, J. Zhu, S. Jin, L. Zhao, Z. Lei, X. Hong, Ceram. Int. 34 (5), 1253-1259 (2008).
• [19] X. Liu, C. Gioradno, M. Antonietti, Chem. Mater. 25 (10), 2021-2027 (2013).
• [20] N. Fechler, T.P. Fellinger, M. Antonietti, Adv. Mater. 25 (1), 75-79 (2013).
• [21] W. Han, K. Liu, S. Yang, F. Wang. J. Su. B. Jin. H. Li, T. Zhai, Sci. China Chem. 62 (10), 1300-1311 (2019).
• [22] J. Zhou, J. Lin, X. Huang, Y. Zhou, Y. Chen, J. Xia, H. Wang, Y. Xie, H. Yu, J. Lei, D. Wu, F. Liu, Q. Fu, Q. Zeng, C. Hsu, C. Yang, L. Lu, T. Yu, Z. Shen, H. Lin, B.I. Yakobson, Q. Liu, K. Suenaga, G. Liu, Z. Liu, Nature 556 (7701), 355-359 (2018).
• [23] X. Hu, P. Huang, B. Jin, X. Zhang, H. Li, X. Zhou, T. Zhai, J. Am. Chem. Soc. 140 (40), 12909-12914 (2018).
• [24] C. Lan, Z. Zhou, R. Wei, J.C. Ho, Mater. Today Energy 11, 61-82 (2019).
• [25] Z. Zhang, P. Chen, X. Duan, K. Zang, J. Luo, X. Duan, Science. 357 (6353), 788-792 (2017).
• [26] G.H. Zhang, J.J. Li, L. Wang, K.C. Chou, Int. J. Refract. Met. H. 69, 180-188 (2017).
• [27] G.D. Sun, G.H. Zhang, S.Q. Jiao, K.C. Chou, J. Phys. Chem. C. 122 (18), 10231-10239 (2018).
• [28] G.D. Sun, G.H. Zhang, K.C. Chou, Int. J. Refract. Met. H. 78, 68-75 (2019).
• [29] D.A. Johnson, J.H. Levy, J.C. Taylor, A.B. Waugh, J. Brough, Polyhedron. 1 (5), 479-482 (1982)
• [30] P.V. Aleksandrov, A.S. Medvedev, M.F. Milovanov, V.A. Imideev, S.A. Kotova, D.O. Moskovskikh, Int. J. Miner. Process. 161, 13-20 (2017).
• [31] S. Li, Y.C. Lin, W. Zhao, J. Wu, Z. Wang, Z. Hu, Y. Shen, D.M. Tang, J. Wang, Q. Zhang, H. Zhu, Nat. Mater. 17 (6), 535-542 (2018).
• [32] Y.G. Petrosyan, V.M. Zhukovskii, O.A. Ustinov, T.M. Panfilova. Zh. Neorg. Khim. 22 (10), 2841-2844 (1977).
• [33] L. Wang, C.Y. Bu, G.H. Zhang, J.S. Wang, K.C. Chou, Metall. Mater. Trans. B. 48 (4), 2047-2056 (2017).
• [34] G.D. Sun, G.H. Zhang, X.P. Ji, J.K. Liu, H. Zhang, K.C. Chou, Int. J. Refract. Met. H. 80, 11-22 (2019).
• [35] W.V. Schulmeyer, H.M. Ortner, Int. J. Refract. Met. H. 20 (4), 261-269 (2002).
• [36] J. Dang, G H. Zhang, K.C. Chou, R.G. Reddy, Y. He, Y. Sun, Int. J. Refract. Met. H. 41, 216-223 (2013).
• [37] J. Dang, G.H. Zhang, K.C. Chou, High Temp. Mater. Proc. 33 (4), 305-312 (2014).
• [38] R. Burch, J. Chem. Soc., Faraday Trans. 1. 74, 2982 (1978).
• [39] T. Leisegang, A.A. Levin, J. Walter, D.C. Meyer, Cryst. Res. Technol. 40 (1‐2), 95-105 (2005).
• [40] L. Wang, G.H. Zhang, K.C. Chou, Int. J. Refract. Met. H. 54, 342-350 (2016).
• [41] L. Wang, G.H. Zhang, K.C. Chou, J. Aust. Ceram. Soc. 54 (1), 97-107 (2018).

Uwagi

1. The authors gratefully acknowledge the financial support from the Guangdong Province Basic and Applied Basic Research Foundation (2019A1515110361), and the Special Project of Central Government for Local Science and Technology Development of Hubei Province (2019ZYYD076).

2. Opracowanie rekordu ze środków MEiN, umowa nr SONP/SP/546092/2022 w ramach programu "Społeczna odpowiedzialność nauki" - moduł: Popularyzacja nauki i promocja sportu (2022-2023).