Development of a Catalyst for Flue Gas Purification from Carbon Monoxide of Multi-Chamber Furnaces for Baking Electrode Blanks

• Autorzy: Ivanenko Olena , Trypolskyi Andrii , Gomelya Nikolai , Karvatskii Anton , Vahin Andrii , Didenko Olga , Konovalova Viktoria , Strizhak Peter

Identyfikatory

DOI

10.12911/22998993/128857

• Języki publikacji: EN

Abstrakty

EN

The catalysts based on natural zeolite-clinoptilolite of Sokyrnytsia deposit modified with oxides of Mn⁴⁺, Fe²⁺, Fe³⁺, Cu²⁺, Cr³⁺ were synthesized. It was determined that 100% conversion of carbon monoxide was achieved at a temperature of 390°C when using the copper-manganese-oxide catalyst (30% CuO + 70% MnO₂). It was shown that although the use of the manganese-oxide catalyst provided 92.8% of CO conversion degree, this catalyst had the most advantages for application compared to the other studied solids. The structural parameters of the manganese-oxide catalyst were determined using XRD, SEM, and nitrogen adsorption. The composition of the main elements of the catalyst samples was determined by micro-X-ray spectral analysis. It was shown that using the catalyst containers in chambers heated by flue gases in the fire channels of a multi-chamber furnace for baking of electrode blanks can be one of the constructive solutions to the problem of flue gas purification from carbon monoxide. The environmental safety of the copper-manganese-oxide catalyst application for the treatment of the flue gases of electrode production is justified by obtaining a catalyst from spent sorbents for purification of the manganese-containing natural water and its non-toxicity in the case of burial or storage in landfills.

Słowa kluczowe

EN

carbon monoxide; flue gas; purification; catalyst; oxidation; conversion; multi-chamber furnace

• Wydawca: Polskie Towarzystwo Inżynierii Ekologicznej ; Lublin University of Technology
• Czasopismo: Journal of Ecological Engineering
• Rocznik: 2021
• Tom: Vol. 22, nr 1
• Strony: 174--187
• Opis fizyczny: Bibliogr. 41 poz., rys., tab.

Twórcy

autor

Ivanenko Olena

• Faculty of Chemical Engineering, Igor Sikorsky Kyiv Polytechnic Institute, Prosp. Peremohy, 37/4, 03056 Kyiv, Ukraine

• https://orcid.org/0000-0001-6838-5400

autor

Trypolskyi Andrii

• L.V. Pisarzhevskii Institute of Physical Chemistry of the National Academy of Sciences of Ukraine, Prosp. of Science, 31, 03028 Kyiv, Ukraine

• https://orcid.org/0000-0003-1682-0241

autor

Gomelya Nikolai

• Faculty of Chemical Engineering, Igor Sikorsky Kyiv Polytechnic Institute, Prosp. Peremohy, 37/4, 03056 Kyiv, Ukraine

• https://orcid.org/0000-0003-1165-7545

autor

Karvatskii Anton

• Faculty of Chemical Engineering, Igor Sikorsky Kyiv Polytechnic Institute, Prosp. Peremohy, 37/4, 03056 Kyiv, Ukraine

• https://orcid.org/0000-0003-2421-4700

autor

Vahin Andrii

• Private Joint Stock Company «Ukrainian Graphite», Pivnichne shose str., 20, 69600 Zaporizhzhia, Ukraine

autor

Didenko Olga

• L.V. Pisarzhevskii Institute of Physical Chemistry of the National Academy of Sciences of Ukraine, Prosp. of Science, 31, 03028 Kyiv, Ukraine

• https://orcid.org/0000-0003-2841-9965

autor

Konovalova Viktoria

• National University of Kyiv-Mohyla Academy, Skovorody Street, 2, 04070 Kyiv, Ukraine

autor

Strizhak Peter

• L.V. Pisarzhevskii Institute of Physical Chemistry of the National Academy of Sciences of Ukraine, Prosp. of Science, 31, 03028 Kyiv, Ukraine

• https://orcid.org/0000-0003-0280-8719

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Uwagi

Opracowanie rekordu ze środków MNiSW, umowa Nr 461252 w ramach programu "Społeczna odpowiedzialność nauki" - moduł: Popularyzacja nauki i promocja sportu (2021).