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Solvent extraction of zinc(II) from ammonia leaching solution by LIX 54-100, LIX 84 i and TOA

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Języki publikacji
EN
Abstrakty
EN
Commercial extractants LIX 54 -100, LIX 84 I and TOA were used to recover zinc(II) from ammonia solutions. The effect of extractant and ammonia concentration, contact time and reextraction were studied. It was found that extraction of zinc depended on the ammonia, ammonium sulphate and extractant concentration but did not depend on the contact time. The McCabe-Thiele distribution isotherm for LIX 54-100 showed that 95% of zinc(II) ions can be recovered in four stages of extraction. Reextraction of Zn(II) ions from the loaded organic phase showed that the metal can be removed almost completely using sulphuric acid.
Słowa kluczowe
Rocznik
Strony
202--211
Opis fizyczny
Bibliogr. 18 poz., rys., tab.
Twórcy
  • Wroclaw University of Technology, Faculty of Chemistry, Division of Analytical Chemistry and Chemical Metallurgy, Wybrzeze Wyspianskiego 27, 50-370 Wroclaw, Poland
  • Wroclaw University of Technology, Faculty of Chemistry, Division of Analytical Chemistry and Chemical Metallurgy, Wybrzeze Wyspianskiego 27, 50-370 Wroclaw, Poland
  • Wroclaw University of Technology, Faculty of Chemistry, Division of Analytical Chemistry and Chemical Metallurgy, Wybrzeze Wyspianskiego 27, 50-370 Wroclaw, Poland
Bibliografia
  • ALGUACIL F.J., ALONSO M., 1999, The effect of ammonium sulphate and ammonia on the liquid–liquid extraction of zinc using LIX 54, Hydrometallurgy 53, 203–209.
  • ALGUACIL F.J., COBO A., 1998, Extraction of zinc from ammoniacal/ammonium sulphate solutions by LIX 54, Journal of Chemical Technology & Biotechnology 71(2), 162−166.
  • ALI A.M.I., AHMAD I.M., DAOUD J.A., 2006, Cyanex 272 for the extraction and recovery of zinc from aqueous waste solution using a mixer-settler unit, Separation and Purification Technology 47, 135–140.
  • CARAVACA C., ALGUACIL J.F., 1991, Study of ZnSO4–Cyanex 302 extraction equilibrium system, Hydrometallurgy 27, 327-338.
  • CHEN Q., LI L., BAI L., HU H., LI J., LIANG Q., LING J., 2011, Synergistic extraction of zinc from ammoniacal ammonia sulfate solution by a mixture of a sterically hindered beta-diketone and tri-n-octylphosphine oxide (TOPO), Hydrometallurgy 105, 201–206.
  • DZIWINSKI E., SZYMANOWSKI J., 1996, Composition of copper extractant LIX 54-100, Solvent Extraction and Ion Exchange 14, 219-226.
  • FLETT D.S., 2005, Solvent extraction in hydrometallurgy: the role of organophosphorus extractants, Journal of Organometallic Chemistry 690, 2426-2438.
  • GOTFRYD L., PIETEK G., 2013, Contaminants of post-leaching copper solutions and their behavior during extraction with industrial extractants, Physicochem. Probl. Miner. Process. 49(1), 133−143.
  • HU J., CHEN Q., HU H., YIN Z., 2012, Synergistic extraction of zinc from ammoniacal solutions using β-diketone mixed with CYANEX 923 or LIX 84I, Trans. Nonferrous Met. Soc. China 22, 1217-1223.
  • HU J., CHEN Q., YANG X., HU F., HU H., YIN Z., 2012, Extractions of zinc from ammoniacal solutions with β-diketone: A comperative study of solvents used, Separation and Purification Technology 87, 15-21.
  • JHA M.K., KUMAR V., SINGH R.J., 2001, Review of hydrometallurgical recovery of zinc from industrial wastes, Resources Conservation and Recycling 33, 1-22.
  • PAWLICKI G., STANISZEWSKI B., WITT K., URBANIAK W., LIS S., 2011, Complexation studies of 3-substituted β-diketones with selected d- and f-metal ions, Chemical Papers 65(2), 221–225.
  • NATHSARMAA K.C., DEVIB N., 2006, Separation of Zn(II) and Mn(II) from sulphate solutions using sodium salts of D2EHPA, PC88A and Cyanex 272, Hydrometallurgy 84, I 3-4, 49-154.
  • RAO K.S., SAHOO P.K., JENA P.K., 1992, Extractions of zinc from ammoniacal solutions by Hostarex DK-16, Hydrometallurgy 31, 91–100.
  • REGEL-ROSOCKA M., ALGUACIL F.J. 2013, Recent trends in metals extraction, Revistade Metalurgia 49(4), 292–315.
  • RICKELTON W.A., BOYLE R.J., 1990, The selective recovery of zinc with new thiophosphinic acids, Solv. Extraction and Ion Exchange 8(6), 783-797.
  • RITCEY G.M., 2006, Solvent extraction in hydrometallurgy: present and future, Tsinghua Science and Technology 11, 137-152.
  • SZYMANOWSKI J., 1990. Ekstrakcja miedzi hydroksyoksymami, PWN, Warszawa-Poznań, 164-222 (in Polish).
Uwagi
Opracowanie ze środków MNiSW w ramach umowy 812/P-DUN/2016 na działalność upowszechniającą naukę (zadania 2017).
Typ dokumentu
Bibliografia
Identyfikator YADDA
bwmeta1.element.baztech-4ba65d48-4b8a-4caa-bea1-309c4f81862d
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