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Corrosion resistance of laser-borided Inconel 600 alloy

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Warianty tytułu
PL
Odporność na korozję borowanego laserowo stopu Inconel 600
Języki publikacji
EN
Abstrakty
EN
Inconel 600 alloy is used extensively for a variety of industrial applications involving high temperature and aggressive environments. However, under conditions of appreciable mechanical wear (adhesive or abrasive), this material has to be characterized by suitable wear protection. The diffusion boronizing efficiently improved the tribological properties of this alloy. Nevertheless, the long duration of this process was necessary in order to obtain the layers of the thickness up to about 100 μm. In this study, instead of the diffusion process, the laser alloying with boron was used for producing a boride layer on Inconel 600 alloy. During this process, the external cylindrical surface of base material was coated by paste, including amorphous boron, and remelted by a laser beam. In the remelted zone, the three areas were observed: compact borides zone consisting of nickel and chromium borides (close to the surface), zone of increased percentage of Ni–Cr–Fe matrix (appearing in the greater distance from the surface) and zone of dominant percentage of Ni–Cr–Fe matrix (at the end of the layer). The hardness was comparable to that-obtained in case of diffusion boriding. Simultaneously, the laser-borided layer was significantly thicker. In order to evaluate the corrosion behaviour, the immersion corrosion test in a boiling solution of H2O, H2SO4 and Fe2(SO4)3 was used. As a consequence of selective laser alloying, the difference in electrochemical potentials between the layer and base material caused the accelerated corrosion of the substrate in areas without laser-borided layer. The results showed that laser-borided Inconel 600 alloy could be characterized by the excellent corrosion resistance in such corrosive solution if the whole surface would be covered with laser-alloyed layer.
PL
Celem pracy było wytworzenie warstwy borków na stopie niklu Inconel 600 z zastosowaniem laserowego stopowania borem oraz ocena odporności korozyjnej stopu z wytworzoną warstwą. Warstwa ta powinna charakteryzować się zwiększoną odpornością na zużycie mechaniczne (adhezyjne lub ścierne) oraz wykazywać znaczną odporność na działanie agresywnego środowiska. Borowanie dyfuzyjne skutecznie poprawia właściwości tribologiczne tego stopu, jednak do uzyskania warstwy o grubości ok. 100 μm dotychczas był potrzebny długi czas procesu. Zamiast tradycyjnego procesu dyfuzyjnego w pracy do wytworzenia warstwy borków na stopie Inconel 600 zastosowano nowoczesną, bardziej ekologiczną metodę laserowego stopowania borem.
Rocznik
Strony
149--156
Opis fizyczny
Bibliogr. 20 poz., fig.
Twórcy
autor
  • Institute of Materials Science and Engineering, Poznan University of Technology, Poznan
autor
  • Institute of Materials Science and Engineering, Poznan University of Technology, Poznan
autor
  • Institute of Materials Science and Engineering, Poznan University of Technology, Poznan
  • Institute of Materials Science and Engineering, Poznan University of Technology, Poznan
Bibliografia
  • [1] Cramer S. D., Covino B. S.: ASM Handbook: Volume 13B: Corrosion: Materials. ASTM International, Materials Park, Ohio (2005).
  • [2] Craig B. D., Anderson D. B.: Handbook of corrosion data. ASM International, Ohio (1995).
  • [3] Kasparova O. V.: Intergranular corrosion of nickel alloys (Review). Protection of Metals 36 (6) (2000) 524÷532.
  • [4] Eliasen K. M., Christiansen T. L., Somers M. A. J.: Low temperature gaseous nitriding of Ni based superalloys. Surface Engineering 26 (4) (2010) 248÷255.
  • [5] Borowski T., Brojanowska A., Kost M., Garbacz H., Wierzchoń T.: Modifying the properties of the Inconel 625 nickel alloy by glow discharge assisted nitriding. Vacuum 83 (2009) 1489÷1493.
  • [6] Singh V., Meletis E. I.: Synthesis, characterization and properties of intensified plasma-assisted nitrided superalloy Inconel 718. Surface & Coatings Technology 201 (2006) 1093÷1101.
  • [7] Ozbek I., Akbulut H., Zeytin S., Bindal C., Ucisik A. H.: The characterization of borided 99.5% purity nickel. Surface and Coatings Technology 126 (2000) 166÷170.
  • [8] Lou D. C., Akselsen O. M., Solberg J. K., Onsoien M. I., Berget J., Dahl N.: Silicon-boronising of Nimonic 90 superalloy. Surface & Coatings Technology 200 (2006) 3582÷3589.
  • [9] Mu D., Shen B. I., Yang C., Zhao X.: Microstructure analysis of boronized pure nickel using boronizing powders with SiC as diluents. Vacuum 83 (2009) 1481÷1484.
  • [10] Gunes I., Kayali Y.: Investigation of mechanical properties of borided Nickel 201 alloy. Materials and Design 53 (2014) 577÷580.
  • [11] Petrova R. S., Suwattananont N., Samardzic V.: The effect of boronizing on metallic alloys for automotive applications. Journal of Materials Engineering and Performance 17 (2008) 340÷345.
  • [12] Lou D. C., Solberg J. K., Akselsen O. M., Dahl N.: Microstructure and property investigation of paste boronized pure nickel and Nimonic 90 superalloy. Materials Chemistry and Physics 115 (2009) 239÷244.
  • [13] Makuch N., Kulka M., Dziarski P.: Gas boriding of Inconel 600 alloy. Inżynieria Materiałowa 6 (2013) 745÷748.
  • [14] Makuch N., Kulka M., Piasecki A.: The effects of chemical composition of Nimonic 80A alloy on the microstructure and properties of gas-borided layer. Surface & Coatings Technology 276 (2015) 440÷455.
  • [15] Majumdar J. D., Manna I.: Laser-surface alloying of nimonic 80 with silicon and aluminum and its oxidation behavior. Metallurgical and Materials Transactions A 43A (2012) 3786÷3796.
  • [16] Rodriguez G. P., Garcia I., Damborenea J.: Effects of laser surface modification of nimonic with aluminum on oxidation behavior. Oxidation of Metals 58 (2002) 235÷248.
  • [17] Kulka M., Dziarski P., Makuch N., Piasecki A., Miklaszewski A.: Microstructure and properties of laser-borided Inconel 600 alloy. Applied Surface Science 284 (2013) 757÷771.
  • [18] Cooper K. P., Slebodnick P., Thomas E. D.: Seawater corrosion behavior of laser surface modified Inconel 625 alloy. Materials Science and Engineering A206 (1996) 138÷149.
  • [19] ASTM G28 Norm, Standard test methods of detecting susceptibility to intergranular corrosion in wrought, nickel-rich, chromium-bearing alloys. ASTM International (2003).
  • [20] Aspden R. G., Economy G., Pement F. W., Wilson I. L.: Relationship between magnetic properties, sensitization, and corrosion of lncoloy Alloy 800 and Inconel alloy 600. Metallurgical Transactions 3 (1972) 2691÷2697.
Uwagi
Opracowanie ze środków MNiSW w ramach umowy 812/P-DUN/2016 na działalność upowszechniającą naukę (zadania 2017).
Typ dokumentu
Bibliografia
Identyfikator YADDA
bwmeta1.element.baztech-4b8f2b61-e695-4646-b3fe-c7973c6fbd34
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