Studies on FOX-7 Based Melt Cast High Explosive Formulations

• Autorzy: Mishra V. S. , Vadali S. R. , Garg R. K. , Joshi V. S. , Wasnik R. D. , Asthana S.
• Języki publikacji: EN

Abstrakty

EN

The key driving force in modern explosive research is the development of low vulnerable high explosive (LOVEX) compositions for future applications in insensitive munitions (IMs). The increasing demand for LOVEX has led to exhaustive studies on low vulnerable explosives as a replacement for conventional cyclo-1,3,5-trimethylene-2,4,6-trinitramine (RDX) in 2,4,6-trinitrotoluene (TNT) melt cast high explosive formulations. In the present study, 1,1-diamino-2,2dinitroethene (FOX-7) has been evaluated as a possible RDX replacement in TNT based, non-aluminized as well as aluminized, melt cast formulation. FOX-7 based melt cast formulations were characterized for their sensitivity to mechanical/shock stimuli, velocity of detonation (VOD), blast parameters and thermal decomposition behavior. These characteristics are compared with the corresponding RDX based compositions as reference standard. The studies show that with little sacrifice on performance parameters, FOX-7 based, non-aluminized and aluminized, melt cast formulations are found to be less vulnerable, compared with the corresponding RDX based formulations.

Słowa kluczowe

EN

melt cast; FOX-7; LOVEX; shock sensitivity; VOD; impulse; IMs

• Wydawca: Sieć Badawcza Łukasiewicz - Instytut Przemysłu Organicznego
• Czasopismo: Central European Journal of Energetic Materials
• Rocznik: 2013
• Tom: Vol. 10, no. 4
• Strony: 569--580
• Opis fizyczny: Bibliogr. 11 poz., wykr.

Twórcy

autor

Mishra V. S.

• High Energy Materials Research Laboratory, Sutarwadi, Pune-411 021, India

autor

Vadali S. R.

• High Energy Materials Research Laboratory, Sutarwadi, Pune-411 021, India

autor

Garg R. K.

• High Energy Materials Research Laboratory, Sutarwadi, Pune-411 021, India

autor

Joshi V. S.

• High Energy Materials Research Laboratory, Sutarwadi, Pune-411 021, India

autor

Wasnik R. D.

• High Energy Materials Research Laboratory, Sutarwadi, Pune-411 021, India

autor

Asthana S.

• High Energy Materials Research Laboratory, Sutarwadi, Pune-411 021, India

Bibliografia

• [1] Vadhe et al., Cast Aluminized Explosives, Combust., Explos. Shock Waves (Engl. Transl.), 2008, 44, 461-467.
• [2] Lochert I.J., FOX-7 − a New Insensitive Explosive, Weapons System Division, Aeronautical and Maritime Research Laboratory, DSTO-TR-1238, 2001.
• [3] Wild R., Teipel U., Characterization and Explosive Properties of FOX-7, 35th Int. Annu. Conf. of ICT, 69, Karsruhe, Germany, 2004.
• [4] Dorsett H., Computational Studies of FOX-7, a New Insensitive Explosive, Weapons Systems Division, Aeronautical and Maritime Research Laboratory, DSTOTR- 1054, 2000.
• [5] Karlsson S. et al., Detonation and Sensitivity Properties of FOX-7 and Formulations Containing FOX-7, FOI Swedish Defence Research Agency, Grindsjöns Research Center, SE-147 25 Tumba, Sweden, 2002.
• [6] Progress Report Swedish Defence Research Agency, FOI-R--1611--SE ISSN 1650-1942, March 2005.
• [7] Nandi A.K., Paramsivan P., Singh S.K., Mandal A.K., Pandey R.K., Assay of the Insensitive High Explosive FOX-7 by Non-Aqueous Titration, Cent. Eur. J. Energ.Mater., 2012, 9(4), 343-352.
• [8] Crawford M.J., Evers J., Göbel M., Klapötke T.M., Mayer P., Oehlinger G., Welch J.M., γ-FOX-7: Structure of a High Energy Density Material Immediately Prior to Decomposition, Propellants Explos. Pyrotech., 2007, 32, 478-495.
• [9] Evers J., Klapötke T.M., Mayer P., Oehlinger G., Welch J., α and ß-FOX-7, Polymorphs of a High Energy Density Material, Studied by X-ray Single, Crystal and Powder Investigations in the Temperature Range from 200 to 423 K, Inorg. Chem., 2006, 45, 4996-5007.
• [10] de Klerk W.P.C., Popescu C., van der Heijden A.E.D.M., Study on Decomposition Kinetics of FOX-7 and HNF, J. Therm. Anal. Cal., 2003, 72, 955-966.
• [11] Burnham A.K., Weese R.K., Wang R., Kwok Q.S.M., Jones D.E.G., Thermal Properties of FOX-7, 36th Int. Annu. Conf. of ICT & 32nd International Pyrotechnics Seminar, Karlsruhe, Germany, June 28 to July 01, 2005.