Preliminary electrochemical characterization of anode supported solid oxide cell (AS-SOC) produced in the Institute of Power Engineering operated in electrolysis mode (SOEC)

• Autorzy: Kupecki J. , Motyliński K. , Skrzypkiewicz M. , Wierzbicki M. , Naumovich Y.

Identyfikatory

DOI

10.1515/aoter-2017-0024

• Języki publikacji: EN

Abstrakty

EN

The article discusses the operation of solid oxide electrochemical cells (SOC) developed in the Institute of Power Engineering as prospective key components of power-to-gas systems. The fundamentals of the solid oxide cells operated as fuel cells (SOFC – solid oxide fuel cells) and electrolysers (SOEC – solid oxide fuel cells) are given. The experimental technique used for electrochemical characterization of cells is presented. The results obtained for planar cell with anodic support are given and discussed. Based on the results, the applicability of the cells in power-to-gas systems (P2G) is evaluated.

Słowa kluczowe

EN

SOFC; SOEC; electrolysis; power-to-gas

PL

SOFC; SOEC; elektroliza; moc na gaz

• Wydawca: Wydawnictwo Instytutu Maszyn Przepływowych PAN ; Komitet Termodynamiki i Spalania PAN
• Czasopismo: Archives of Thermodynamics
• Rocznik: 2017
• Tom: Vol. 38, no. 4
• Strony: 53–--63
• Opis fizyczny: Bibliogr. 11 poz., fot., rys., tab.

Twórcy

autor

Kupecki J.

• Department of High Temperature Electrochemical Processes, Institute of Power Engineering, Augustowka 36, 02-981 Warsaw, Poland

autor

Motyliński K.

• Department of High Temperature Electrochemical Processes, Institute of Power Engineering, Augustowka 36, 02-981 Warsaw, Poland

autor

Skrzypkiewicz M.

• Department of High Temperature Electrochemical Processes, Institute of Power Engineering, Augustowka 36, 02-981 Warsaw, Poland

autor

Wierzbicki M.

• Department of High Temperature Electrochemical Processes, Institute of Power Engineering, Augustowka 36, 02-981 Warsaw, Poland

autor

Naumovich Y.

• Department of High Temperature Electrochemical Processes, Institute of Power Engineering, Augustowka 36, 02-981 Warsaw, Poland

Bibliografia

• [1] Milewski J., Wołowicz M., Lewandowski J.: Optimization of the working conditions of a laboratory size (100 cm2) molten carbonate fuel cell. ECS Transactions 51(2013), 1, 37-45.
• [2] Schwarze K., Posdziech O., Kroop S. et al.: Green industrial hydrogen via reversible high-temperature electrolysis. ECS Transactions 78(2017), 1, 2943-2952.
• [3] Pozzo M., Lanzini A., Santarelli M.: Enhanced biomass-to-liquid (BTL) conversion process through high temperature co-electrolysis in a solid oxide electrolysis cell (SOEC). Fuel 145(2015), 39-49.
• [4] Virkar A.V.: Mechanism of oxygen electrode delamination in solid oxide electrolyzer cells. Int. J. Hydrogen Energ. 35(2010), 18, 9527-9543.
• [5] Sun X., Chen M., Jensen S.H., et al.: Thermodynamic analysis of synthetic hydrocarbon fuel production in pressurized solid oxide electrolysis cells. Int. J. Hydrogen Energ. 37(2012), 22, 17101-17110.
• [6] Graves C., Ebbesen S.D., Jensen S.H., et al.: Eliminating degradation in solid oxide electrochemical cells by reversible operation. Nat. Mater. 14(2015), 239-244.
• [7] Jae S., Gyeong K., Choi M.: Stability of LSCF electrode with GDC interlayer in YSZ-based solid oxide electrolysis cell. Solid State Ionics 262(2014), 303-306.
• [8] Kim S.J., Kim K.J., Dayaghi A.M., et al.: Polarization and stability of La2NiO4+δ in comparison with La0.6Sr0.4Co0.2Fe0.8O3-δ as air electrode of solid oxide electrolysis cell. Int. J. Hydrogen Energ. 41(2016), 33, 14498-14506.
• [9] Hansen J.B.: Solid oxide electrolysis - a key enabling technology for sustainable energy scenarios. Faraday Discuss. 182(2015), 9-48.
• [10] Milewski J.: Solid oxide electrolysis cell co-methanation supported by molten carbonate fuel cell - a concept. J. Power Technologies 96(2016), 1, 8-14.
• [11] Bartela L., Skorek-Osikowska A., Kotowicz J.: Integration of a supercritical coal-fired heat and power plant with carbon capture installation and gas turbine. Rynek Energii 100(2012), 3, 56-62.

Uwagi

EN

This work was financially supported by the Ministry of Science and Higher Education of the Republic of Poland through the Statutory Grant CPE/1/STAT/2017 in the Institute of Power Engineering.