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Production of zinc powder from Co-Zn plant residue using selective alkaline leaching followed by electrowinning

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Warianty tytułu
Języki publikacji
EN
Abstrakty
EN
Annually, gigagrams of cobalt residues, called hot filter cake (HFC), are produced from the Co neutralization step at Iranian zinc plants. With respect to the composition of HFC )i.e., 15-25% Zn, 0.5–1.5% Co, 3–8% Mn(, it can be used as a secondary source of zinc, cobalt and manganese. In the present study, for the first time, treatment of HFC for separation and recovery of zinc has been studied. The residue was treated by employing selective alkaline leaching, in order to recover the maximum amount of zinc, followed by zinc electrowinning process. As a results, a solution was obtained from alkaline leaching under the optimum condition of 75 °C, sodium hydroxide of 8 M, solid-to-liquid ratio dm3 of 1:10, and stirring speed of 600 rpm, having zinc recovery of 88.5 %. In the following step, the electrowinning process, under the optimum working conditions being current density 350 A/m2 and time 10 hours, was carried out to produce a zinc powder with high purity of 99 percent. Finally, a simple and effective conceptual flow diagram was proposed for the process.
Rocznik
Strony
411--425
Opis fizyczny
Bibliogr. 29 poz., rys., tab.
Twórcy
  • Department of Mining and Metallurgical Engineering, Amirkabir University of Technology, Tehran, Iran
  • University of Applied Science and Technology, Calcimin Branch, Zanjan, Iran
  • Department of Mining and Metallurgical Engineering, Amirkabir University of Technology, Tehran, Iran
  • Research & Engineering Co. for Non-ferrous Metals, Zanjan, Iran
  • Department of Mineral Processing, Faculty of Engineering, University of Sahand Technology, Tabriz, Iran
autor
  • Research & Engineering Co. for Non-ferrous Metals, Zanjan, Iran
Bibliografia
  • CHEN, A., ZHAO, Z.W., JIA, X., LONG, S., HUO, G., CHEN, X., 2009, Alkaline leaching Zn and its concomitant metals from refractory hemimorphite zinc oxide ore. Hydrometallurgy 97, 228–232.
  • CHEN D.-s., ZHAO L.-s., QI T., HU G.-p., ZHAO H.-x., Li J., WANG L.-n., 2013, Desilication from titanium–vanadium slag by alkaline leaching. Transactions of Nonferrous Metals Society of China 23, 3076-3082.
  • CHENGLONG, Z., YOUCAI, Zh., 2009, Mechanochemical leaching of sphalerite in an alkaline solution containing lead carbonate. Hydrometallurgy 100, p. 56.
  • CUSANELLI, D.C., COFFIN, L.D., RAJCEVIC, H.P., 1973, U.S. Patent 3, in: 743 (Ed.), p. 501.
  • EACOTT, J.G., ROBINSON, M.C., BUSSE, E., BURGENER, J.E., BURGENER, P.E., 1984, Technoeconomic feasibility of zinc and lead recovery from electric arc furnace bag-house dust. Can. Min. Metall. Bull 77 75–81.
  • DUTRA, A.J.B., PAVIA, P.R.P., TAVARES, L.M., 2006, Alkaline leaching of zinc from electric arc furnace steel dust. Miner. Eng. 19, 478–485.
  • EIVAZI, A.R.H., ALAMDARI, E.K., MPRADKHANI, D., 2008a, Dissolution kinetics of zinc from zinc plant residue, in: In: Young, C.A. (Ed.), Proceedings of the 6th International Symposium: Hydrometallurgy 2008, Vancouver, Canada, pp. 196-200.
  • EIVAZI, A.R.H., MOEADKHANI, D., ALAMDARI, E.K., DARVISHI., D., 2008b, Solvent extraction separation of zinc, manganese and cobalt in sulfate solutions by D2EHPA., Int. Solvent Extraction Conference, pp. 233-238.
  • FRENAY, J., 1985, Leaching of oxidized zinc ore in various media. Hydrometallurgy 15, 243–253.
  • GURMEN, S., EMRE, M., 2003, A laboratory-scale investigation of alkaline zinc electrowinning. Miner. Eng. 16, 559-562.
  • JHA, M.K., KUMAR, V., SINGH, R.J., 2001, Review of hydrometallurgical recovery of zinc from industrial wastes. Resour. Conserv. Recycl. 33, 1–22.
  • KIM, T.H., KANG, J.G., SOHN, J.S., RHEE, K.I., LEE, S.W., SHIN, S.M., 2008, Preparation of Mn-Zn ferrite from spent zinc-carbon batteries by alkali leaching, acid leaching and co-precipitation. Met. Mater. Int. 14, 655-658.
  • LIU W., YANG T., ZHANG D., CHEN L., LIU Y., 2014, Pretreatment of copper anode slime with alkaline pressure oxidative leaching. International Journal of Mineral Processing 128, 48-54.
  • MERRILL, C.C., LANG, R.S., 1965, USBM Report, p. 6576.
  • MIRVALIEV, R., INOUE, K., 2001, Pressure oxidative leaching of molybdenite in alkaline media. J. Min. Mater. Process. Inst. Jpn. 117, 72–76.
  • MOHAPATRA M., NAYAK B., SANJAY K., SUBBAIAH T., MISHRA B.K., 2014, Ligand mediated eco-friendly leaching of zinc from spent catalyst in alkaline media. Journal of Industrial and Engineering Chemistry 20, 2217-2223.
  • MORDODAN, H., i EK, T., I IK, A., 1999, Caustic soda leach of electric arc furnace dust. Turk. J. Eng. Environ. Sci. 23, 199–207.
  • MORADKHANI, D., RASOULI, M., BEHNIAN, D., ARJMANDFAR, H., P., A., 2012, Selective zinc alkaline leaching optimization and cadmium sponge recovery by electrowinning from cold filter cake (CFC) residue. Hydrometallurgy 115-116, 84–92.
  • ORHAN, G., 2005, Leaching and cementation of heavy metals from electric arc furnace dust in alkaline medium. Hydrometallurgy 78, 236–245.
  • OGNYANOVA, A., OZTURK, A.T., MICHELIS, I.D., FERELLA, F., TAGLIERI, G., AKCIL, A., VEGLIÒ, F.,2009, Metal extraction from spent sulfuric acid catalyst through alkaline and acidic leaching. Hydrometallurgy 100, 20–28.
  • OLPER, M., 1997, Extraction of antimony from sulfide ores by alkaline leaching, recovery of elemental sulfur and electrowinning antimony from fluoborate solution. European Patent Application, Appl. num. 97201300.7.
  • PEREIRA, J.A.M., SCHWAAB, M., DELL'ORO, E., PINTO, J.C., MONTERIO, J.L.F., 2009, The kinetics of gibbsite dissolution in NaOH. Hydrometallurgy 96, 6–13.
  • REED, W.A., GARNOV, A.Y., RAO, L., NASH, K.L., BOND, A.H., 2005, Oxidative alkaline leaching of americium from simulated high-level nuclear waste sludge. Sep. Sci. Technol. 40, 1029–1046.
  • SAFARZADEH M.S., MORADKHANI D., ILKHCHI M.O., GOLSHAN N.H., 2008, Determination of the optimum conditions for the leaching of cd–ni residues from electrolytic zinc plant using statistical design of experiments. Separation and Purification Technology 58, 367-376.
  • SAFARZADEH, M.S., MORADKHANI, D., ATASHI, P., 2009, Recovery of zinc from Cd–Ni zinc plant residues. Hydrometallurgy 97, 67–72.
  • SHIN, S.M., 2008, Separation of zinc from spent zinc-carbon batteries by selective leaching with sodium hydroxide. Hydrometallurgy 96, 349–353.
  • ST-PIERRE, J., PIRON, D., 1986, Electrowinning of zinc from alkaline solutions. J Appl Electrochem 16, 447-456.
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  • ZHAO, Y., STANFORTH, R., 2000, Production of Zn powder by alkaline treatment of smithsonite Zn–Pb ores. Hydrometallurgy 56, 237–249.
Typ dokumentu
Bibliografia
Identyfikator YADDA
bwmeta1.element.baztech-4a258de4-df01-45f3-a659-3bdd5bcfe777
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