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The Impact Evaluation of Zeolitization Parameters on the Properties of Sewage Sludge Ash

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Warianty tytułu
Języki publikacji
EN
Abstrakty
EN
The incineration of municipal sewage sludge causes the formation of ash, which needs further utilization. The literature gives only few examples of the chemical sewage sludge ash conversion with the hydrothermal method. The effect of conversion depends on the properties of the raw material and the process parameters. According to the domestic and foreign test results of the conversion of fly ash from coal, the fusion method is more effective. The aim of the paper was to evaluate the impact of chemical sewage sludge ash conversion with the fusion method on the chosen properties of the obtained material. The applied conversion parameters were the ratio of sewage sludge ash:NaOH, the concentration of NaOH, the activation time and temperature as well as the crystallization temperature and time. In some of the samples, the introduction of the fusion caused the formation of the following, e.g. (hydroxy)sodalite, zeolite X and zeolite Y, zeolite P, (hydroxy)cancrinite. The temperature of the thermal treatment of sludge, the ratio of ash:NaOH and the crystallization time were the parameters having a statistically significant impact on the effect of zeolitization and the properties of the obtained material, but the changes of their values had little effect on the tested features of the modified ash. On the basis of the leaching of Cd, Cr and Ni from the samples after the conversion it was proven that a higher temperature of the thermal treatment of sewage sludge was favourable for the formation of permanent structures.
Słowa kluczowe
Rocznik
Strony
195--205
Opis fizyczny
Bibliogr. 20 poz., rys., tab.
Twórcy
  • Kielce University of Technology, Al. Tysiąclecia Państwa Polskiego 7, 25-341, Kielce, Poland
Bibliografia
  • 1. Bao W, Zou H., Gan S., Xu X., JI G., Zheng K. 2013. Adsorption of heavy metal ions from aqueous solutions by zeolite based on oil shale ash: kinetic and equilibrium studies. Chemical Research in Chinese Universities, 29, 126–131.
  • 2. Deng L., Xu Q., Wu H. 2016. Synthesis of zeolitelike material by hydrothermal and fusion methods using municipal solid waste fly ash. Procedia Environmental Sciences, 31, 662–667.
  • 3. EPA Regulations on Land Disposal Restrictions. 1991. Appendix II – Toxicity Characteristic Leaching Procedure, 161:1877. The Bureau of National Affaris, Inc.,Washington D.C. 20037
  • 4. Fan Y., Zhang F.S., Zhu J., Liu Z. 2008. Effective utilization of waste ash from MSW and coal cocombustion power plant – zeolite synthesis, Journal of Hazardous Materials, 153, 382–388.
  • 5. Filipiak J. 2011. Fly Ash in Construction Industry. Strength Tests of Soil Stabilized with Mixture of Ash and Cement. Annual Set the Environment Protection, 13, 1043–1054, (in Polish).
  • 6. Franus W. 2012. The use of zeolites produced from fly ash to remove impurities from water and sewage. Polish Academy of Sciences, Lublin (in Polish).
  • 7. General Statistic Office, 2019, https://bdl.stat.gov. pl, (in Polish).
  • 8. Kappel A., Ottosen L.M., Kirkelund G.M. 2017. Colour, compressive strength and workability of mortars with an iron rich sewage sludge ash. Construction and Building Materials, 157, 1199–1205.
  • 9. Kirov G., Filizova L., Petrov O. 1997. Natural Zeolites–SOFIA95. Minato H.: Standardization of methods for zeolite speciality determination and techniques for zeolite resources utilization. PENSOFT, Sofia-Moscow.
  • 10. Latosińska J. 2016. Zeolitization of sewage sludge ash with a fusion method. Journal of Ecological Engineering, 17, 138–146.
  • 11. Latosińska J. 2017. The influence of temperature and time of sewage sludge incineration on the mobility of heavy metals. Environment Protection Engineering, 44, 105–122.
  • 12. Latosińska J. 2019. Modification of municipal sewage sludge ash by zeolitization – selected issues. Kielce University of Technology. Kielce (in Polish).
  • 13. Latosińska J., Gawdzik J. 2012. The effect of incineration temperatures on mobility of heavy metals in sewage sludge ash. Environment Protection Engineering, 14, 31–44.
  • 14. National Waste Management Plan 2022, 2016, (in Polish).
  • 15. Pimraksa K., Chindaprasirt P., Setthaya N. 2010. Synthesis of zeolite phases from combustion byproducts. Waste Management and Resources, 28, 1122–1132.
  • 16. Regulation of the Ministry of Economy of 16.07.2015, on the acceptance of waste for storage in landfills, Journal of Laws, No 0, item 1277, (in Polish).
  • 17. Regulation of the Ministry of Health of 7 December 2017 on the quality of water intended for human consumption, Journal of Laws No 0, item 2294, (in Polish).
  • 18. Smol M., Kulczycka J., Henclik A, Gorazda K., Wzorek Z. 2015. The possible use of sewage sludge ash (SSA) in the construction industry as a way towards a circular economy. Journal of Cleaner Production, 95, 45–54.
  • 19. Zabielska-Adamska K. 2015. Combustion product of municipal sewage sludge as anthropogenic soil. Annual Set The Environment Protection, 17, 1286–1305, (in Polish).
  • 20. Zhang Y., Leng Z., Zou F., Wang L., Chen S.S., Tsang D.C.W. 2018. Synthesis of zeolite A using sewage sludge ash for applicaton in warm mix asphalt. Journal of Cleaner Production, 172, 686–695.
Typ dokumentu
Bibliografia
Identyfikator YADDA
bwmeta1.element.baztech-48fbefa1-ded1-4b21-93ce-8083895036e9
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