Assessment of the Harmfulness of Moulding Sands with Alkyd Resin Subjected to the High Temperature Influence

• Autorzy: Holtzer M. , Dańko R. , Żymankowska-Kumon S. , Kubecki M. , Bobrowski A.

Identyfikatory

DOI

10.1515/amm-2016-0346

• Języki publikacji: EN

Abstrakty

EN

Out of moulding sands used in the foundry industry, sands with organic binders deserve a special attention. These binders are based on synthetic resins, which ensure obtaining the proper technological properties and sound castings, however, they negatively influence the environment. These resins in their initial state these resins are not very dangerous for people and for the environment, thus under an influence of high temperatures they generate very harmful products, being the result of their thermal decomposition. Depending on the kind of the applied resin, under an influence of a temperature such compounds as: furfuryl alcohol, formaldehyde, phenol, BTEX group (benzene, toluene, ethylbenzene, xylene), and also polycyclic aromatic hydrocarbons (PAHs) can be formed and released. The aim of the study was the development of the method, selection of analytical methods and the determination of optimal conditions of formation compounds from the BTEX and PAHs group. Investigations were carried out in the specially designed set up for the thermal decomposition of organic substances in a temperature range: 500 – 1 300°C at the laboratory scale. The object for testing was alkyd resin applied as a binding material for moulding sands. The qualitative and quantitative analyses of compounds were performed by means of the gas chromatography coupled with the mass spectrometry (GC/MS).

Słowa kluczowe

EN

moulding sand; binding; BTEX; thermal analysis; GC/MS

• Wydawca: Institute of Metallurgy and Materials Science of Polish Academy of Sciences ; Committee of Materials Engineering and Metallurgy of Polish Academy of Sciences
• Czasopismo: Archives of Metallurgy and Materials
• Rocznik: 2016
• Tom: Vol. 61, iss. 4
• Strony: 2171--2176
• Opis fizyczny: Bibliogr. 26 poz., tab., wykr.

Twórcy

autor

Holtzer M.

• AGH University of Science and Technology, Faculty of Foundry Engineering, 30-059 Kraków, 23 Reymonta Str., Poland

autor

Dańko R.

• AGH University of Science and Technology, Faculty of Foundry Engineering, 30-059 Kraków, 23 Reymonta Str., Poland

autor

Żymankowska-Kumon S.

• AGH University of Science and Technology, Faculty of Foundry Engineering, 30-059 Kraków, 23 Reymonta Str., Poland

autor

Kubecki M.

• Institute for Ferrous Metallurgy in Gliwice, 44-100 Gliwice, 12-14 K. Miarki Str., Poland

autor

Bobrowski A.

• AGH University of Science and Technology, Faculty of Foundry Engineering, 30-059 Kraków, 23 Reymonta Str., Poland

Bibliografia

• [1] C. D. N Humfrey, L. S. Levy, S. P. Faux, Food and Chemical Toxicology 34, 1103-1111 (1996).
• [2] M. G. Ribeiro, W. R. P. Filho, Journal of Hazardous Materials A136, 432-437 (2006).
• [3] P. Scarbel, C. E. Bats, J. Griffin, AFS Transactions 114, 435-445 (2006).
• [4] J. Faber, K. Perszewska, M. Żmudzińska, M. Latała-Holtzer. Archives of Foundry Engineering 10, 39-42 (2010) (in Polish).
• [5] M. T. Teles, C. Delerue-Matos, M. Alvim-Ferraz, Analytica Chimica Acta 537, 47-51 (2005).
• [6] M. Holtzer, D. Kwaśniewska-Królikowska, A. Bobrowski, R. Dańko, B. Grabowska, S. Żymankowska-Kumon, W. Solarski, Przegląd Odlewnictwa 3-4,124-132 (2012) (in Polish).
• [7] M. Kubecki, M. Holtzer, B. Grabowska, A. Bobrowski, Archives of Foundry Engineering 11, 125-130 (2011).
• [8] V. S LaFay, G. Crandell, J. Schifo, AFS Transcations 115, 977-989 (2007).
• [9] S. Ji, L. Wan, Z. Fan, Water, Air and Soil Pollution 132, 347-364 (2001).
• [10] M. Holtzer, R. Dańko, A. Kmita Water, Air and Soil Pollution 227 (1), 12-16 (2016).
• [11] Y. Wang, F. S. Cannon, X. Li, Environmental Science and Technology 45, 8529–8535 (2011).
• [12] M. Holtzer, Archives of Foundry 2 (3), 50-56 (2002) (in Polish).
• [13] A. Wolff, T. Steinhäuser, Foundry Trade Journal 179, 57 (2005).
• [14] M. Patterson, J. Thiel, Foundry Mangement &Technology 6, 14-17 (2010).
• [15] A. Ch. Psimenos, W. Scheitz, G. Eder, Giesserei Praxis 9, 318-320 (2008).
• [16] M. Holmgren, Proceedings of the 69th World Foundry Congress, Hangzhou, China, 697-699 (2010).
• [17] G. R. Crandell, J.F. Schifo, G. Moser, AFS Transactions 113, 27-29 (2006).
• [18] V. S. LaFay, S. Neltner, D. Carroll, D. J. Couture, Modern Casting 10, 27-29 (2010).
• [19] M. Kubecki, W. Spiewok, Report from the researches No S0-0654/BC Institute for Ferrous Metallurgy 2008 (in Polish).
• [20] M. Kubecki, W. Spiewok, Report from the researches No BO-1316 Institute for Ferrous Metallurgy 2011 (in Polish).
• [21] A. Kmita, C. Fischer, K. Hodor, M. Holtzer, A. Roczniak Arabian Journal of Chemistry http://dx.doi.org/10.1016/j.arabjc.2016.11.003 (2016)
• [22] M. Kubecki, M. Holtzer, A. Bobrowski, R. Dańko, B. Grabowska, S. Żymankowska-Kumon, Archives of Foundry Engineering 12 (1), 119-124 (2012) (in Polish).
• [23] M. Kubecki, M. Holtzer, Conference materials on CD. Hutni a Prumyslova Analytika, Tale, Slovakia (2012).
• [24] M. Holtzer, R. Dańko, Monograph, Foundry commission PAN. Ed. J. Szajnar, Katowice-Gliwice, 133-152 (2009).
• [25] M. Holtzer, B. Grabowska., S. Żymankowska-Kumon, D. Kwaśniewska-Królikowska R. Dańko, W. Solarski, A. Bobrowski, Metalurgiija 51 (4), 437-440 (2012).
• [26] M. Holtzer, Dańko J., Lewandowski J. L., Solarski W., Dańko R., Grabowska B., Bobrowski A., Żymankowska-Kumon S., Sroczyński A., Różycki A., Skrzyński M. Polish Patent Nr PL 398709 (2013), Polish Patent Office (in Polish).

Uwagi

EN

The research is financed by NCBiR within the Project No. PBS/A5/3072013 realised in years: 2013-2015 at AGH University of Science and Technology - Faculty of Foundry Engineering, Krakow. Poland.