The philipsbornite–segnitite solid-solution series from Rędziny, eastern metamorphic cover of the Karkonosze granite (SW Poland)

Gołębiowska, B.; Włodek, A.; Pieczka, A.; Borkiewicz, O.; Polak, M.

doi:10.14241/asgp.2015.036

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Tytuł artykułu

The philipsbornite–segnitite solid-solution series from Rędziny, eastern metamorphic cover of the Karkonosze granite (SW Poland)

Autorzy

Gołębiowska B. , Włodek A. , Pieczka A. , Borkiewicz O. , Polak M.

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DOI

10.14241/asgp.2015.036

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Abstrakty

Supergene minerals of the philipsbornite–segnitite series, PbAl₃(AsO₄)(AsO₃OH)(OH)₆–PbFe₃+3(AsO₄) (AsO₃OH)(OH)₆, accompanied by carminite, PbFe³⁺₂(AsO₄)2(OH)₂, were found in relics of hydrothermal quartz– chlorite–arsenopyrite veins, associated with subordinate polymetallic ores disseminated in contact zones of a dolomitic marble deposit at Rędziny, Western Sudetes, Poland, and recognized by means of electron microprobe and X-ray and electron-back-scattered diffraction (XRD and EBSD). Philipsbornite and segnitite, as the two minerals of the series, exhibit highly variable compositions, especially in terms of the range of Fe₃+ Al³⁺ substitution at the G site, with a distinct gap between the values of 0.52 and 0.89 for the Fe/(Al+Fe) ratio; substitutions at the D and T sites are less important. In this respect, the minerals are almost identical with philipsbornite and segnitite, known from other localities. The gap might be a consequence of the limited miscibility of the end-members, but also might be attributed to crystallization under the changing and distinctly differing activities of Al³⁺ and Fe³⁺. The unit-cell parameters of philipsbornite, a = 7.1245(13) Ο, c = 17.0967(45) Ο, make the mineral comparable with philipsbornites from other occurrences. The EBSD analysis confirmed the rhombohedral structure of both minerals and the space group symmetry R-3m. The minerals crystallized in the sequence: philipsbornite -> segnitite -> carminite, which reflects (i) decreasing acidity in the oxidation zone, due to the leaching of sulphate ions and interaction of the solutions with a nearby dolomite lens, and (ii) varying activities of Al³⁺, Fe³⁺ and Pb²⁺ cations, mobilized by the solutions through interaction with the silicate host containing disseminated arsenopyrite and subordinate sulphides, up to complete Pb²⁺ depletion.

Słowa kluczowe

arsenates oxidation zone philipsbornite segnitite carminite chemical composition Rędziny

Wydawca

Polskie Towarzystwo Geologiczne

Czasopismo

Annales Societatis Geologorum Poloniae

Rocznik

2016

Tom

Vol. 86, No. 1

Strony

73--83

Opis fizyczny

Bibliogr. 48 poz., rys., tab.

Twórcy

autor

Gołębiowska B.

goleb@agh.edu.pl

AGH University of Science and Technology, Department of Mineralogy, Petrography and Geochemistry, Mickiewicza 30, 30-059 Kraków, Poland

autor

Włodek A.

AGH University of Science and Technology, Department of Mineralogy, Petrography and Geochemistry, Mickiewicza 30, 30-059 Kraków, Poland

autor

Pieczka A.

AGH University of Science and Technology, Department of Mineralogy, Petrography and Geochemistry, Mickiewicza 30, 30-059 Kraków, Poland

autor

Borkiewicz O.

X-ray Science Division, Advanced Photon Source, Argonne National Laboratory, Argonne, IL60563, USA

autor

Polak M.

AGH University of Science and Technology, Department of Mineralogy, Petrography and Geochemistry, Mickiewicza 30, 30-059 Kraków, Poland

Bibliografia

1. Bayliss, P., Kolitsch, U., Nickel, E. H. & Pring, A., 2010. Alunite supergroup: recommended nomenclature. Mineralogical Magazine, 74: 919-927.
2. Birch, W. D., Pring, A. & Gatehouse, B. M., 1992. Segnitite, PbFe3H(AsO4)2(OH)6, a new mineral in the lusungite group from Broken Hill, New South Wales, Australia. American Mineralogist, 77: 656-659.
3. Brophy, G. P., Scott, E. S. & Snellgrove, R. A., 1962. Sulfate studies 2. Solid solution between alunite and jarosite. American Mineralogist, 47: 112-126.
4. Cooper, M. A. & Hawthorne, F. C., 2012. Refinement of the crystal structure of zoned philipsbornite-hidalgoite from Tsumeb mine, Namibia, and hydrogen bonding in the D2+G3+3(T5+O4) (TO3OH)(OH)6 alunite structures. Canadian Mineralogist, 76: 839-849.
5. David, J., Jahnsa, J., Novák, F. & Prachař, I., 1990. Philipsbornite from the Sn-W deposit Cínovec in Krušné hory Mts. (Czechoslovakia). Vestnik Ustredniho Ustavu Geologickeho, 65: 367-369.
6. Duthou, J.-L., Couturie, J. P., Mierzejewski, M. P. & Pin, C., 1991. Age determination of the Karkonosze granite using the Rb-Sr isochrone whole-rock method. Przegląd Geologiczny, 36: 75-79. [In Polish, with English summary.]
7. Gołębiowska, B., 1999. Strashimirite and cornwallite (copper arsenates) from Rędziny (Lower Silesia, Poland). Mineralogia Polonica, 30: 3-11.
8. Gołębiowska, B., 2003. Okruszcowanie w złożu dolomitu „Rędziny” ze szczególnym uwzględnieniem minerałów strefy hipergenicznej. Unpublished Ph.D. Thesis, AGH-University of Science and Technology, Kraków, Poland. 249 pp. [In Polish.]
9. Gołębiowska, B., 2005. Solid solution within vanadates and arsenates of the descloizite and the adelite groups from Rędziny (the Sudetes). Mineralogical Society of Poland, Special Papers, 25: 85-88.
10. Gołębiowska, B., Pieczka, A. & Borkiewicz, O., 2008. Pb-(Al,Fe3+)-arsenate association from Rędziny, Rudawy Janowickie, Southwestern Poland. Mineralogia - Special Papers, 32: 69.
11. Gołębiowska, B., Pieczka, A. & Franus, W., 1998. Conichalcite, clinotyrolite and tyrolite (Ca-Cu arsenates) from Rędziny (Lower Silesia, Poland). Mineralogia Polonica, 29(2): 13-22.
12. Gołębiowska, B., Pieczka, A. & Franus, W., 2002. Ca-bearing phosphatian mimetite from Rędziny, Lower Silesia, Poland. Neues Jahrbuch für Mineralogie, Monatshefte, 2002(6), 1-13.
13. Gołębiowska, B., Pieczka, A. & Franus, W., 2006. Olivenite- adamite solid solution from oxidation zone in Rędziny (West Sudetes, Poland). Mineralogia Polonica, 37(2): 97- 107.
14. Gołębiowska, B., Pieczka, A. & Parafiniuk, J., 2012. Substitution of Bi for Sb and As in minerals of the tetrahedrite series from Rędziny, Lower Silesia, southwestern Poland. Canadian Mineralogist, 50: 267-279.
15. Jambor, J. L. & Dutrizac, J. E., 1983. Beaverite-plumbojarosite solid solution. Canadian Mineralogist, 21: 101-113.
16. Jansa, J., Novák, F., Pauliš, P. & Scharmová, M., 1998. Supergenní minerály Sn-W ložiska Cínovec v Krušných horách (Česká republika). Bulletin mineralogicko-petrografického oddělení Národního muzea v Praze, 6: 83-101. [In Czech.]
17. Kolitsch, U., Bernhardt, F., Brandstätter, F. & Schachinger, T., 2010. Arsenopyrit, Bariopharmakosiderit, Baryt, Covellin, Jarosit, Karminit?, Mawbyit?, Mimetesit, Philipsbornit, Plumbojarosit, Pyrit, Pyromorphit, Schwefel, Segnitit, Sphalerit und Wulfenitvom Sperkerriegelbei Wiesmath, Bucklige Welt. Pp. 243-245. In: Niedermayr, G., Auer, Ch., Bernhard, F., Blass, G., Bojar, H.-P., Brandstätter, F., Hammer, V. M. F., Hirche, Th., Huber, P. A., Knobloch, G., Köller, R., Kolitsch, U., Löffler, E., Neuhold, F., Poeverlein, R., Postl, W., Prasnik, H., Pristacz, H., Schachinger, T., Strasser, M. & Walter, F. (eds), Neue Mineralfundeaus Österreich LIX. CarinthiaII, 200/120: 199-260.
18. Kozdrój, W., 2003. Geotectonic evolution of the East Karkonosze crystalline complex. In: Ciężkowski, W., Wojewoda, J. & Żelaźniewicz, A. (eds), Sudety Zachodnie: Od wendu do czwartorzędu. Polskie Towarzystwo Geologiczne, WIND Wrocław, pp. 67-80. [In Polish, with English abstract.]
19. Kusiak, M. A., Williams, I. S., Dunkley, D. J., Konecny, P., Słaby, E. & Martin, H. M., 2014. Monazite to the rescue: U-Th-Pb dating of the intrusive history of the composite Karkonosze pluton, Bohemian Massif. Chemical Geology, 364: 76-92.
20. Marciniak, H., Diduszko, R. & Kozak, M., 2006. XRAYAN. Program do rentgenowskiej analizy fazowej, wersja 4.0.1. Koma, Warszawa.
21. Mazur, S., 2003. Eastern envelope of the Karkonosze granite - cross-section of a Variscan suture zone. In: Cięzkowski, W., Wojewoda, J. & Żelaźniewicz, A. (eds), Sudety Zachodnie: Od wendu do czwartorzędu. Polskie Towarzystwo Geologiczne. WIND Wrocław, pp. 53-65. [In Polish, with English abstract.]
22. Mazur, S. & Aleksandrowski, P., 2001. The Tepla(?) Saxothuringian suture in the Karkonosze-Izera Massif, western Sudetes, Central European Variscides. International Journal of Earth Sciences, 90: 341-360.
23. Mazur, S., Aleksandrowski, P., Turniak, K. & Awdankiewicz, M., 2007 Geology, tectonic evolution and Late Palaeozoic magmatism of Sudetes - an overview. In: Kozłowski, A. & Wiszniewska, J. (eds), Granitoids in Poland. Archivum Minera- logiae Monograph, 1, Warszawa, pp. 59-87.
24. Mikulski, S. Z., 2007. Metal ore potential of the parent magma of granite - the Karkonosze massif example. In: Kozłowski, A. & Wiszniewska, J. (eds) Granitoids in Poland, Archivum Mineralogiae Monograph, 1, Warszawa, pp. 123-145.
25. Mills, S. J., Hattert, F., Nickel, E. H. & Ferraris, G., 2009. The standardisation of mineral group hierarchies: application to recent nomenclature proposals. European Journal of Mineralogy, 21: 1073-1080.
26. Mochnacka, K., Oberc-Dziedzic, T., Mayer, W. & Pieczka, A., 2007 Ti remobilization and sulphide/sulphoarsenide mineralization in amphibolites: effect of granite intrusion (the Karkonosze-Izera Massif, SW Poland). Geological Quarterly, 52: 349-368.
27. Mochnacka, K., Oberc-Dziedzic, T., Mayer, W., Pieczka, A. & Góralski, M., 2007. Occurrence of sulphides in Sowia Dolina near Karpacz (SW Poland) - an example of ore mineralization in the contact aureole of the Karkonosze granite. Mineralogia Polonica, 38(2): 185-207.
28. Moura, M. A., Botelho, F. N. & de Mendonca, F. C., 2007. The indium-rich sulfides and rare arsenates of the Sn-In-mineralized Mangabeira A-type granite, Central Brazil. Canadian Mineralogist, 45: 485-496.
29. Parafiniuk, J., 2003. Secondary bismuth and tellurium minerals from Rędziny (SW Poland). Mineralogia Polonica, 34(2): 3-14.
30. Parafiniuk, J. & Domańska, J., 2002. Bismuth minerals from Rędziny (Rudawy Janowickie, SW Poland). Mineralogia Polonica, 33(2): 3-14.
31. Pieczka, A., Gołębiowska, B. & Franus, W., 1998. Yukonite, a rare Ca-Fe arsenate from Rędziny (Sudetes, Poland). European Journal of Mineralogy, 10: 1367-1370.
32. Pieczka, A., Gołębiowska, B. & Parafiniuk, J., 2009. Conditions of formation of polymetallic mineralization in the eastern envelope of the Karkonosze granite - the case of Rędziny. Canadian Mineralogist, 47: 765-786.
33. Pin, C., Mierzejewski, M. P. & Duthou, J. L., 1987. Rb-Sr isochron age of the Karkonosze granite from the quarry Szklarska Poręba Huta and determination of its 87Sr/86Sr initial ratio. Przegląd Geologiczny, 35: 512-517. [In Polish, with English summary.]
34. Pouchou, I. L. & Pichoir, F., (1985). “PAP” (phi-rho-z) procedure for improved quantitative microanalysis. In: Armstrong, I. T. (ed.), Microbeam Analysis. San Francisco Press, San Francisco, pp. 104-106.
35. Rattray, K. J., Taylor, M. R., Bevan, D. J. M. & Pring, A., 1996. Compositional segregation and solid solution in the lead-dominant alunite-type minerals from Broken Hill, N.S.W. Mineralogica! Magazine, 60: 779-785.
36. Schmetzer, K., Tremmel, G. & Medenbach, O., 1982. Philipsbornit, PbAl3H[(OH)6(AsO4)2] from Tsumeb, Namibia - a second occurrence. Neues Jahrbuch für Mineralogie, Monatshefte, 1982(6): 248-254. [In German, with English abstract.]
37. Schwab, R., Goetz, C., Herold, H. & de Oliveira, N., 1991. Compouds of the crandallite type: Synthesis and properties of pure (calcium, strontium, barium, lead, lanthanum, cerium to europium) - arsenocrandallites. Neues Jahrbuch für Mineralogie, Monatshefte, 1991(3): 97-112.
38. Scott, K. M., 1987. Solid solution in, and classification of, gossan-derived members of the alunite-jarosite family, northwest Queensland, Australia. American Mineralogist, 72: 178-187.
39. Sejkora, J., Cejka, J. & Šrein, V., 2001a. Pb dominant members of crandalite group from Cínovec and Moldava deposits, Krušné hory Mts. (Czech Republic). Journal Czech Geological Society, 46: 53-67.
40. Sejkora, J., Cejka, J., Šrein, V., Novotná, M. & Ederová, J., 1998. Minerals of plumbogummite-philipsbornite series from Moldava deposit, Krušné hory Mts., Czech Republic. Neues Jahrbuch für Mineralogie, Monatshefte, 1998(4): 145-163.
41. Sejkora, J., Houzar, S. & Šrein, V., 2001b. Segnitite from Štěpánov nad Svratkou, Western Moravia. Acta Musei Moraviae, Scientiae Geologicae, 86: 85-92. [In Czech, with English abstract.]
42. Sejkora, J., Plášil, J., Císařová, I., Škoda, R., Hloušek, J., Veselovský, F. & Jebavá, I., 2011. Interesting supergene Pb-rich mineral association from the Rovnost mining field, Jáchymov (St. Joachimsthal), Czech Republic. Journal of Geosciences, 56: 257-271.
43. Sejkora, J., Škovíra, J., Cejka, J. & Plášil, J., 2009. Cu-rich members of the beudantite-segnitite series from Krupka ore district, the Krušné hory Mountains, Czech Republic. Journal of Geosciences, 54: 355-371.
44. Słaby, E. & Martin, H., 2008. Mafic and felsic magma interactions in granites: the Karkonosze Hercynian pluton (Sudetes, Bohemian Massif). Journal of Petrology, 49: 353-391.
45. Smith, D. K., Roberts, A. C., Bayliss, P. & Liebau, F., 1998. A systematic approach to general and structure-type formulas for minerals and other inorganic phases. American Mineralogist, 83: 126-132.
46. Walenta, K., Zwiener, M. & Dunn, P. J., 1982. Philipsbornite, a new mineral of the crandalite series from Dundas, Tasmania. Neues Jahrbuch für Mineralogie, Monatshefte, 1982(1): 1-5.
47. Williams, P. A., 2005. Solutions in the “big laboratory”: Towards a model for metals at the Earth’s surface. Pure Applied Chemistry, 3: 643-651.
48. Wolcysz, M., Urbanik, W., Mazgaj, S., Matuszewski, J., Andruszkiewicz, M. & Paszkowicz, W., 1993. DHNPowder Diffraction System. [Freeware version.]

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Opracowanie ze środków MNiSW w ramach umowy 812/P-DUN/2016 na działalność upowszechniającą naukę.

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