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In search of an efficient frother for pre-flotation of carbonaceous shale from the kupferschiefer stratiform copper ore

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Języki publikacji
EN
Abstrakty
EN
This papers shows that frothers such as aliphatic alcohols (CnH2n+1OH), poly(propylene glycols) (HO(C3H6O)mH), poly(propylene glycol) alkyl ethers (CnH2n+1O(C3H6O)mH) and poly(ethylene glycol) alkyl ethers (CnH2n+1O(C2H4O)mH), can be used for collectorless flotation of a sample of carbonaceous copper shale manually separated from the Kupferschiefer stratiform copper ore. It was shown that flotation is influenced by the type and dose of frothers. The best flotation results were obtained with tri(propylene glycol) butyl ether C4P3, tri(propylene glycol) propyl ether C3P3 and tri(propylene glycol) P3. For these frothers, the yield vs. frother dose relationship was in the form of convex curves indicating that carbonaceous copper shale can float at relatively low dosages of the frother. It means that these frothers can be used for pre-flotation of carbonaceous matter from the investigated copper ore. Other frothers formed concave yield–frother dose relationships and were less effective.
Słowa kluczowe
Rocznik
Strony
835--840
Opis fizyczny
Bibliogr. 13 poz., rys., tab.
Twórcy
  • Wroclaw University of Technology, Wybrzeze Wyspianskiego 27, 50-370 Wroclaw, Poland
autor
  • Department of Mining Engineering, Dumlupinar University, Kutahya, Turkey
autor
  • Department of Mining Engineering, Dumlupinar University, Kutahya, Turkey
autor
  • Wroclaw University of Technology, Wybrzeze Wyspianskiego 27, 50-370 Wroclaw, Poland
Bibliografia
  • 1. CHO Y.S., LASKOWSKI J.S., 2002, Effect of flotation frothers on bubble size and foam stability, Int. J. Miner. Process., 64, 69–80.
  • 2. BEDNAREK P., 2014, Contact angle of carbonaceous copper shale for different chemical reagents. BSc Thesis, Wroclaw University of Technology, in Polish.
  • 3. DAVIES J.T., 1957, A quantitative kinetic theory of emulsion type, I. Physical chemistry of the emulsifying agent, Gas/liquid and liquid/liquid interface. Proceedings of the International Congress of Surface Activity, 426–438.
  • 4. DRZYMALA J., MILCZARSKI E., MILCZARSKI J., 2007, Adsorption and flotation of hydrophilic and hydrophobic materials in the presence of hydrocarbon polyethylene glycol ethers, Colloids and Surfaces A: Physicochem. Eng. Aspects, 308(1–3), 111–117.
  • 5. FOSZCZ D., DRZYMALA J., 2011, Differentiation of organic carbon, copper and other metals contents by segregating flotation of final Polish industrial copper concentrates in the presence of dextrin, Physicochem. Probl. Miner. Process., 47, 17–26.
  • 6. HARRIS G.H., JIA R., 2000, An improved class of flotation frothers, Int. J. Miner. Process., 58(1–4), 35–43.
  • 7. KONIECZNY A., PAWLOS W., KRZEMINSKA M., KALETA R., KURZYDLO P., 2013, Evaluation of organic carbon separation from copper ore by pre-flotation, Physicochem. Probl. Miner. Process., 49(1), 189–201.
  • 8. KOWALCZUK P.B., 2013, Determination of critical coalescence concentration and bubble size for surfactants used as flotation frothers, Ind. Eng. Chem. Res., 52(33), 11752–11757.
  • 9. KOWALCZUK P.B., ZALESKA E., DANCZAK O., 2014, Flotation of a model carbonaceous copper shale-quartz mixture with poly(ethylene glycol) alkyl ethers, submitted to Transactions of Nonferrous Metals Society of China.
  • 10. LASKOWSKI J.S., 2001, Coal flotation and fine coal utilization, Vol. 14, in Developments in mineral processing, Elsevier Science Publishing, Amsterdam, The Netherlands.
  • 11. MALYSA E., MALYSA K., CZARNECKI J., 1987, A method of comparison of the frothing and collecting properties of frothers, Colloids and Surfaces, 23, 29–39.
  • 12. PUGH R.J., 2000, Non-ionic polyethylene oxide frothers in graphite flotation, Miner. Eng., 13(2), 161–162.
  • 13. ZHANG W., NESSET J.E., RAO R., FINCH J.A., 2012, Characterizing frothers through critical coalescence concentration (CCC)95-hydrophile-lipophile balance (HLB) relationship, Minerals, 2, 208–227.
Typ dokumentu
Bibliografia
Identyfikator YADDA
bwmeta1.element.baztech-4812fa77-df03-4e81-bca4-e767bc07f91d
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