Wytwarzanie i mikrostruktura osadzanych elektrolitycznie stopów Ni-Co i kompozytów TiO2 / Ni-Co

• Autorzy: Ledwig Piotr , Dubiel Beata , Kopia Agnieszka

Identyfikatory

DOI

10.15199/24.2020.4.7

Warianty tytułu

EN

Manufacturing and microstructure of electrolytically deposited Ni-Co alloys and TiO2 / Ni-Co composites

• Języki publikacji: PL

Abstrakty

PL

Stopy Ni-Co oraz kompozyty TiO2/Ni-Co osadzono elektrolitycznie z kąpieli siarczanowo-cytrynianowych o względnej zawartości jonów Co:Ni równej 1:49, 1:24 i 1:9 stosując gęstości prądu 2,5, 5 i 7,5 A/dm2. Wpływ parametrów osadzania na morfologię powierzchni, mikrostrukturę, skład chemiczny i skład fazowy zbadano za pomocą skaningowej i transmisyjnej mikroskopii elektronowej, spektroskopii dyspersji energii charakterystycznego promieniowania rentgenowskiego oraz dyfrakcji promieniowania rentgenowskiego. Wytworzone kompozyty charakteryzowały się globularną morfologią i nanokrystaliczną mikrostrukturą. Wykazano, że w osnowie kompozytów występują pojedyncze nanocząstki oraz aglomeraty TiO2. Zawartość TiO2 w kompozytach wynosiła około 4% mas. Stwierdzono, że wielkość ziarna kompozytów TiO2/Ni-Co zależy od obecności fazy umacniającej, warunków prądowych podczas osadzania oraz stężenia Co w osnowie Ni-Co.

EN

TiO2/Ni-Co composites were electrodeposited from citrate-sulfate bath with varying Ni:Co ratios. Effect of deposition conditions on chemical composition, surface morphology, microstructure and phase composition were investigated using scanning and transmission electron microscopy, energy dispersive X-ray spectroscopy and X-ray diffraction. Manufactured composites were characterized by typical cauliflower surface morphology and nanocrystalline structure. Nanocrystalline TiO2 particles were embedded in the Ni-Co matrix both in the form of dispersive nanoparticles and clusters. The concentration of nc-TiO2 in composites was about 4 wt. %. Grain size of TiO2/Ni-Co composites depended on the content of strengthening phase, deposition current conditions and Co concentration in the Ni-Co matrix.

Słowa kluczowe

PL

kompozyty na osnowie metalowej; osadzanie elektrolityczne; mikrostruktura; kompozyty TiO2/Ni-Co; stop Ni-Co

EN

metal matrix composites; electrodeposition; microstructural characterization; nc TiO2/Ni-Co composites; Ni-Co alloy

• Wydawca: Wydawnictwo SIGMA-NOT
• Czasopismo: Hutnik, Wiadomości Hutnicze
• Rocznik: 2020
• Tom: Vol. 87, nr 4
• Strony: 107--113
• Opis fizyczny: Bibliogr. 40 poz., rys., tab.

Twórcy

autor

Ledwig Piotr

• AGH Akademia Górniczo-Hutnicza, \Vydział Inżynierii Metali i Informatyki Przemysłowej, Katedra Metalurgii Stopów Żelaza , al. A. Mickiewicza 30, 30-059 Kraków

autor

Dubiel Beata

• AGH Akademia Górniczo-Hutnicza, \Vydział Inżynierii Metali i Informatyki Przemysłowej, Katedra Metalurgii Stopów Żelaza , al. A. Mickiewicza 30, 30-059 Kraków

autor

Kopia Agnieszka

• AGH Akademia Górniczo-Hutnicza, Katedra Inżynierii Powierzchni i Analiz Materiałów, al. A. Mickiewicza 30, 30-059 Kraków

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Uwagi

Opracowanie rekordu ze środków MNiSW, umowa Nr 461252 w ramach programu "Społeczna odpowiedzialność nauki" - moduł: Popularyzacja nauki i promocja sportu (2020).