Synthesis, growth and characterization of NaAl(SO4)·H2O triangular prism single crystal for inorganic NLO application

• Autorzy: Sakthi P. , Rajasekaran R. , Arun A.

Identyfikatory

DOI

10.2478/msp-2019-0033

• Języki publikacji: EN

Abstrakty

EN

An inorganic coordination complex of single crystal containing sodium and aluminum (SA) was grown at room temperature by slow evaporation technique. The crystal was characterized using single crystal X-ray diffraction (XRD), FT-IR, UV-Vis, SHG, SEM, EDX and TG/DTA analyses. The size of the grown crystal was around 17 mm × 15 mm × 5 mm. Both optical and SEM photographs confirmed that the crystal is transparent with smooth surface. The XRD data showed that the crystal belongs to the BCC crystal structure. The crystal shows excellent transparency in the entire region of visible light (cut-off value is 339 cm⁻¹ ). The dielectric constant as well as dielectric loss of the sample was calculated by varying frequencies at different temperatures and the presence of low dielectric loss proved that this crystal can be used for the NLO application.

Słowa kluczowe

EN

crystal growth; X-ray diffraction; optical properties; dielectric properties

• Wydawca: De Gruyter
• Czasopismo: Materials Science Poland
• Rocznik: 2019
• Tom: Vol. 37, No. 2
• Strony: 142--148
• Opis fizyczny: Bibliogr. 10 poz., rys., tab.

Twórcy

autor

Sakthi P.

• PG & Research Deportment of Physics, Government Arts College, Thiruvannamalai-606603, Tamil Nadu, India

autor

Rajasekaran R.

• Principal, Government Arts College, Virudhachalam-606001, Tamil Nadu, India

autor

Arun A.

• PG & Research Department of Chemistry, Government Arts College, Thiruvannamali-606603, Tamil Nadu, India

Bibliografia

• [1] Rajasekaran R., Mohan Kumar R., Jayavel R., Ramasamy P., J. Cryst. Growth, 252 (2003), 317.
• [2] Ilango E., Rajasekaran R., Shankar K., Krishnan S., Chithambaram V., Opt. Mater., 37 (2014), 666.
• [3] Rajesh Kumar T., Jeyesekaran R., Ravi Kumar S.M., Vimala M., Sagayaraj P., Appl. Sururf. Sci., 257 (2010), 1684.
• [4] Duorong Y., Zhenwu Z., Mingguo, Suoying S., Minhua J., J. Cryst. Growth, 186 (1998), 240.
• [5] Vijayabhaskaran B., C. Ramachandra Raja C., Optik., 124 (2013), 1366.
• [6] Selvakumar S., Ravi Kumar S.M., Joseph G.P., Rajarajan K., Madhavan J., S.A. Rajasekar S.S., Sagayaraj P., Mat. Chem. Phys., 103 (2007), 153.
• [7] Kirubavathi K., Selvaraju K., Valluvan R., Kumararaman S., Mater. Lett., 61(2007), 4173.
• [8] Wojciechowska R., Wojciechowski W., Kaminski J., J. Therm. Anal. Calorim., 33 (1988), 503.
• [9] Selvarajan P., Das B.N., Gon H.B., Rao K.V., J. Mater. Sci., 29 (1994), 4031.
• [10] Prasad N.V., Prasad G., Bhimasankaran T., Suryanarayana S.V., Kumar G.S., Indian J. Pure Ap. Phy., 34 (1996), 639.

Uwagi

PL

Opracowanie rekordu w ramach umowy 509/P-DUN/2018 ze środków MNiSW przeznaczonych na działalność upowszechniającą naukę (2019).