High temperature transformation of iron-bearing minerals in basalt: Mössbauer spectroscopy studies

• Autorzy: Kądziołka-Gaweł Mariola , Wojtyniak Marcin , Klimontko Joanna

Identyfikatory

DOI

10.2478/mipo-2022-0002

• Języki publikacji: EN

Abstrakty

EN

The high temperature decomposition of basalt from Lower Silesia (Poland) was followed by Mössbauer spectroscopy investigation. The Fe content of the sample was ~9.0 at.%. The X-ray diffraction analysis shows that augite (37%) and olivine (12%) are major Fe-bearing mineral components. The sample also contains significant amount of anorthite (22%) and nepheline (17%). The sample was heated at various temperatures between 200o C and 1100o C for three hours. Up to a temperature of 500o C changes in contribution of Fe-bearing minerals are insignificant. Heating in the temperature range from 500o C to 1100o C leads to a systematic increase in contribution of iron oxides at the cost of contribution of silicate minerals, like augite and olivine. Mössbauer spectrum obtained after heating at 1100o C showed hematite as the main iron oxide phase. The ratio of Fe3+/Fetot in the non-heated sample was equal to 0.51 and after heating at 1100o C this ratio amounted to 0.89.

Słowa kluczowe

EN

basalts; high temperature affects; Mössbauer spectroscopy; Fe-bearing minerals

• Wydawca: Mineralogical Society of Poland
• Czasopismo: Mineralogia
• Rocznik: 2022
• Tom: Vol. 53, iss. 1
• Strony: 10--19
• Opis fizyczny: Bibliogr. 32 poz., tab., wykr.

Twórcy

autor

Kądziołka-Gaweł Mariola

• Institute of Physics, University of Silesia, 75 Pułku Piechoty 1, 41-500 Chorzów, Poland

autor

Wojtyniak Marcin

• Institute of Physics, Silesian University of Technology, Konarskiego 22B, 44-100 Gliwice, Poland

autor

Klimontko Joanna

• Institute of Physics, University of Silesia, 75 Pułku Piechoty 1, 41-500 Chorzów, Poland

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