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The effect of selected transition metal powders (Zn, Ti, Mo and nano-Fe), in the concentration range from 0-5 wt.%, when used as activators in the highly calorific mixture Fe-KClO4 (containing 16 wt.% KClO4), has been studied. It has been established that zinc and molybdenum powders can act as factors in decreasing the activation temperature and increasing the effectiveness of the oxidant used. Titanium powder increases the oxygen conversion rate and the amount of energy released. Iron nano-powder has only a slight influence on the above mentioned parameters.
Rocznik
Tom
Strony
271--283
Opis fizyczny
Bibliogr. 22 poz., rys., tab.
Twórcy
autor
- Institute of Non-Ferrous Metals Division in Poznań
autor
- Faculty of Commodity Science, Poznań University of Economic, 10 Niepodległości St., 61-875 Poznań Poland
autor
- Faculty of Chemistry, Adam Mickiewicz University, 6 Grunwaldzka St., 60-780 Poznań, Poland
Bibliografia
- [1] Guidotti R.A., Development History of Fe-KClO4 Heat Powders at Sandia and Related Aging for Thermal Batteries, Sandia National Laboratories Report SAND2001-2191, July 2001.
- [2] Piercey D.G., Klapötke T.M., Nanoscale Aluminum-metal Oxide Thermite Reactions for Application in Energetic Materials, Cent. Eur. J. Energ. Mater., 2010, 7, 115-129.
- [3] Riffault M.L., Determining the Development of Certain Pyrotechnic Compounds During the Period Proceeding Ignition, Proc. 3rd Symposium Chemical Problems Connected with Stability of Explosive, 1974, pp. 302-309.
- [4] Nagaishi T., Yoshimura J., Shinchi F., Matsumoto M., Yoshinaga S., The Burn Rate and the Deflagration Limit Pressure, Kogyo Kayaku, 1981, 42, 137-144.
- [5] Wittberg T.N., Moddeman W.E., Collins L.W., Wang P.S., (1980), The Dissolution of the Native Oxide Film on Titanium for Pyrotechnics Applications, Proc. 8th International Vacumm Congres, 1981, 562-570.
- [6] Zhang Y., Kshirsagar G., Ellison J.E., Cannon J.C., Catalytic Effects of Metal Oxides on the Decomposition of the Potassium Perchlorate, Thermochim. Acta, 1996, 278, 119-124.
- [7] Moddeman W.E., Collins L.W., Wang P.S., Wittberg T.N., Role of Surface Chemistry in the Ignition of Pyrotechnic Materials, Proc. 7th International Pyrotechnic Seminar, 1980, 408-412.
- [8] Czajka B., Wachowski L., Foltynowicz Z., Lipinska K., Lipinski M., Tabat S., The Influence of Mo and Ti on Selected Properties of High Calorific Fe-KClO4 Mixture, New Trends Res. Energ. Mater., Proc. Semin., 12th, Pardubice, 2009, Vol. II , 481-486.
- [9] Chermysov V.V., Korneeva N.P., Nakhshin M.I., Trush F.F., Pyrotechnical Mixture for Heater of Thermal Chemical Current Source, RU Patent 2091917, 1984.
- [10] Bush D.M., Mex T.N., Thermal Battery Having a Thermal Reservoir Pellet, US Patent 3677822, 1972.
- [11] Dekel D.R., Yishay R., Heat Source for Thermal Batteries, WO 2006/046245 A1, 2006.
- [12] Dekel D.R., Yishay R., Laser D., Thermal Batteries Using Cathode Precursor Pyrotechnic Pellet, US Patent 0137318, 2004.
- [13] Wachowski L., Czajka B., Activator − Induced Modification of Selected Properties of Heat Generation Fe-KClO4 Mixture, Cent. Eur. J. Energ. Mater., 2006, 3, 51-63.
- [14] Wachowski L., Czajka B., Textural and Catalytic Properties of the FexOy/Fe-KClO4 System, Thermochim. Acta, 2005, 435, 102-107.
- [15] Czajka B., Wachowski L., Zieliński M., Oxide Phases as an Activator Properties of High Calorific Mixture, Oxid. Commun., 2006, 29, 152-164.
- [16] Czajka B., Studies of the Effectiveness of Fe-KClO4 as a Thermal Activator of Special Equipment (in Polish), Poznań Technical University, Poznań, 2011.
- [17] Czajka B., Styczyński S., Tabat S., Szal D., Wachowski L., Determination of the Ignition Sensitivity on Selected Heat Powders, Cent. Eur. J. Energ. Mater., 2011, 8, 3-13.
- [18] CRC Handbook of Chemistry and Physics, (Lide D.R., Ed.), 79th ed., 1998-1999, CRC Press Boca Raton, Boston, London, N.Y., Washington D.C., 1998.
- [19] Miyata K., Kubota N., Combustion of Ti and Zr Particles with KNO3, Propellants Explos. Pyrotech., 1996, 21, 29-35.
- [20] Seetharamacharyulu D., Mallaya R.M., Varneker Pai V.R., Differential Thermal Analysis of Potassium Perchlorate, J. Thermal. Anal., 1981, 21, 17-24.
- [21] Song M., Chen M., Zhang Z., Effect of Zn Powders on the Thermal Decomposition of Ammonium Perchlorate, Propellants Explos. Pyrotech., 2008, 33, 261-265.
- [22] Czajka B., Styczyński S., Szal D., Tabat S., Wachowski L., Active Materials for Thermal Reserve Batteries, 8th International Conference IPOEX’2011, 2011, p. 27.
Typ dokumentu
Bibliografia
Identyfikator YADDA
bwmeta1.element.baztech-453b3447-4880-42f7-803e-778d9e26bc97