Fabrication and properties of magnesium based alloys Mg-Ca

• Autorzy: Nowosielski R. , Gawlas-Mucha A. , Borowski A. , Guwer A.
• Języki publikacji: EN

Abstrakty

EN

Purpose: The paper describes the preparation, structure and mechanical properties of magnesium based alloys with chemical composition of Mg-1 (wt%) Ca prepared in the form of ingot. Design/methodology/approach: The studied samples were prepared by the tubular resistance furnace melting in silicon crucible. The structure of the alloy was examined by X-ray diffractometry (phase analysis) and scanning electron microscope (chemical analysis of the micro-regions). Microhardness was measured using Vickers hardness testing machine with automatic track measurement. Microstructure was examined by optical light microscopy. Findings: The X-ray diffraction investigations have revealed that the studied cast ingot the two-phase alloy structure. Chemical analysis confirmed the expected chemical composition. Values of the microhardness tests of materials were compared before and after remelting. Practical implications: Magnesium alloys are new class of biodegradable materials other bioresorbable biomaterials for orthopedic applications. The potential benefits of ownership of Mg alloys are the closer modulus of elasticity to the bone than stainless steel or titanium, biocompatibility and bone- active properties and the elimination of necessity of a second operation to remove the implant body. Two- component Mg-Ca alloy is characterized in that a solid solution limit, and creates a stable intermetallic phase Mg2Ca. Originality/value: Fabrication and properties of magnesium based alloys to thermomechanical processing.

Słowa kluczowe

EN

magnesium based alloys; biomaterials; magnesium; calcium; tubular resistance furnace melting

PL

stopy na osnowie magnezu; biomateriały; magnez; wapń; piec rurowy odporny na topnienie

• Wydawca: International OCSCO World Press
• Czasopismo: Journal of Achievements in Materials and Manufacturing Engineering
• Rocznik: 2013
• Tom: Vol. 61, nr 2
• Strony: 367--374
• Opis fizyczny: Bibliogr. 40 poz., rys., tab.

Twórcy

autor

Nowosielski R.

• Institute of Engineering Materials and Biomaterials, Silesian University of Technology,ul. Konarskiego 18a, 44-100 Gliwice, Poland

autor

Gawlas-Mucha A.

• Institute of Engineering Materials and Biomaterials, Silesian University of Technology,ul. Konarskiego 18a, 44-100 Gliwice, Poland

autor

Borowski A.

• Institute of Engineering Materials and Biomaterials, Silesian University of Technology,ul. Konarskiego 18a, 44-100 Gliwice, Poland

autor

Guwer A.

• Institute of Engineering Materials and Biomaterials, Silesian University of Technology,ul. Konarskiego 18a, 44-100 Gliwice, Poland

Bibliografia

• [1] W.M. Smith, Surface Materials Processing, Second Edition, Backmann Verlag, Berlin -London -Paris -Warsaw, 2006.
• [2] A. Białobrzeski, E. Czekaj, M. Heller, Corrosion properties of aluminum alloys processed and magnesium die-casting technology, Archives of Foundry 2/4 (2002) 1642-5308 (in Polish).
• [3] Y. Wana, G. Xiong, H. Luoa, F. Hea, Y. Huanga, X. Zhoua, Preparation and characterization of a new biomedical magnesium -calcium alloy, Materials and Design 29 (2008) 2034 -2037.
• [4] J. Piątkowski, F. Bińczyk, Properties and applications of casting Mg-Al alloys Archives of Foundry 2/4 1642-5308 (in Polish).
• [5] K. Martynowicz-Lis, M. Pachota, A. Kryczek, Casting in Poland - results of 2006, Founding contemporary - Poland and the Word 1-2 (2008) 12 -15 (in Polish).
• [6] J. Dudek, A. Fajkiel, T. Reguła, K. Saja, Selected issues of preparation technology of liquid magnesium alloy AZ91, National Research Institute of Foundry, 2009 (in Polish).
• [7] A. Fajkiel, A. Obrzeski, P. Dudek, T. Reguła, Modern methods of casting alloys and magnesium in automotive applications, Review of Foundry Engineering 59/1-2 (2009) 48-55 (in Polish).
• [8] M. Holtzer, A. Bobrowski, Protective atmosphere used for melting and casting of magnesium alloys, Review Foundry Engineering 58/3 (2008) (in Polish).
• [9] E.C. Lee, C.Y. Nian, Y.S. Tarng, Design of a materials processing technologies, Archives of Materials Science and Engineering 28 (2007) 48-56.
• [10] M. Salahshoor, Y. Guo, Biodegradable Orthopedic Magnesium-Calcium (MgCa) Alloys,Processing, and Corrosion Performance, Materials 5 (2012) 135-155.
• [11] N. Kirkland, N. Birbilis, J. Walker, T. Woodfield, G.J. Dias, M.P. Staiger, Development and biocompatibility of a novel corrodible fluoride-coated magnesium-calcium alloy with improved degradation kinetics and adequate mechanical properties for cardiovascular applications, Publishing house Wiley Periodicals, Inc., Hoboken, 2010.
• [12] A. Drynda, T. Hassel, R. Hoehn, A. Perz, F.-W. Bach, M. Peuster, Development and biocompatibility of a novel corrodible fluoride-coated magnesium-calcium alloy with improved degradation kinetics and adequate mechanical properties for cardiovascular applications, Publishing house Wiley Periodicals, Inc., Hoboken, 2009.
• [13] Z. Li, X. Gu, S. Lou, Y. Zheng, The development of binary MgeCa alloys for use as biodegradable materials within bone, Biomaterials 29 (2008) 1329-1344.
• [14] X. Gu, Y. Zheng, S. Zhong, T. Xi, J. Wang, W. Wang, Corrosion of, and cellular responses to Mg-Zn-Ca bulk metallic glasses, Biomaterials 31 (2010) 1093 -1103.
• [15] M. Nałęcz, Biocybernetics and Biomedical Engineering 2000, PAS, EXIT, Warsaw, 1999.
• [16] M. Avedesian, H. Baker, ASM Specialty Handbook. Magnesium and magnesium alloys, ASM International, The Materials Information Society, USA, 1999.
• [17] C.G. Musso, Magnesium metabolism in health and disease, International Urology and Nephrology 41 (2009) 357-362.
• [18] R.K. Rude, H.E. Gruber, Magnesium deficiency and osteoporosis: animal and human observations, Journal of Nutritional Biochemistry 15 (2004) 710 -716.
• [19] C. Weaver, R. Heaney, Calcium in human health, Human Press Inc., New York, 2006.
• [20] W. Szkliniarz, Modern Metallic Materials - Present and Future, Department of Materials Science and Metallurgy, Silesian University of Technology, Katowice, 2009 (in Polish).
• [21] M. Staiger, A. Piertak, J. Huadmai, G. Dias, Magnesium and its alloys orthopedic biomateriale: A review, Biomaterials 27 (2006) 1728 -1734.
• [22] N. Kirkland, N. Birbilis, J. Warker, T. Woodfield, G. Dias, M. Staiger, In -vitro dissolution of magnesium-calcium binary alloys: Claryfiing the unique role of calcium additins In bioresorbable magnesium implant alloys, Wielly Periodicals, Inc., Hoboken, 2010.
• [23] N. Li, Y. Zheng, Novel Magnesium Alloys Developed for Biomedical Application: A Review, Journal of Materials Science and Technology 29/3 (2013) 489-502.
• [24] Z. Jasminka, J. Kerstetter, Nutrition In bone health revisited: a story beyond calcium, Journal of American College of Nutrition, 19/6 (2000) 715-737.
• [25] Y.C. Li, C.S. Wong, C. Wen, P. H. Hodgson, Biodegradable Mg-Zr-Ca alloys for bone implant materials, Materials Technology, 27/1 (2012) 49-51.
• [26] N. Kirkland, J. Lespagnol, N. Birbilas, M.P. Staiger, A survery of bio-corrosion rates of magnesium alloys Corrosion Science, 52 (2010) 287 -291.
• [27] J. Marciniak, Biomaterials, Silesian University of Technology Press, Gliwice, 2002 (in Polish).
• [28] K. Przybyłowicz, Metallography, WNT, Warszawa, 2003 (in Polish).
• [29] J. Adamczyk, Engineering of metal materials - cz.1, Silesian University of Technology Publisher, Gliwice, 2004 (in Polish).
• [30] J. Adamczyk, Engineering of metal materials - cz.2, Silesian University of Technology Publisher, Gliwice, 2004 (in Polish).
• [31] Z. Górny, Z. Lech, K. Rutkowski, T. Strojny, Welkens, Casting of non-ferrous alloys, WNT, Warsaw, 1963 (in Polish).
• [32] Z. Górny, J. Sobczak, Modern plastic molding on the basis of non-ferrous metals, ZA-PIS, Cracow, 2005 (in Polish).
• [33] B. Mordike, T. Ebert, Magnesium, properties - applications - potential, Materials Science and Engineering A302 (2001) 37-45.
• [34] R. Zeng, W. Dietzel, F. Witte, N. Hort, C. Blawert, Progress and challenge for magnesium alloys as biomaterials, Advanced Engineering Materials 10/8 (2008) B3 -B14.
• [35] M.P. Staigera, A.M. Pietaka, J. Huadmaia, G. Diasb, Magnesium and its alloys as orthopedic biomaterials: A review, Biomaterials 27 (2006) 1728 -1734.
• [36] H. Zhang, S. Shang, Y. Wang, L. Chen, Z. Liu, Thermodynamic properties of Laves phases in the Mg-Al-Ca system at finite temperature from first-principles, Intermetallics 22 (2012) 17-23.
• [37] S. Wasiur-Rahman, M. Medraj, Critical assessment and thermodynamic modeling of the binary Mg -Zn, Ca -Zn and ternary Mg-Ca-Zn systems, Intermetallics 17 (2009) 847-864.
• [38] R. Nowosielski, R. Babilas, A. Guwer, A. Borowski: Fabrication of ternary Ca-Mg-Zn bulk metallic glasses. Journal of Achievements in Materials and Manufacturing Engineering 56/2 (2013) 67-74.