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Abstrakty
The vast majority of experimental techniques used for the measurements of hydrogen permeability through metallic membranes whose one or both surfaces are covered with a thin Pd film is based on the assumption that a ratio of film-to-membrane thickness is small enough to cause hydrogen flow to be independent of the Pd film thickness. In an attempt to verify this assumption, we have measured the hydrogen flow through the Pd33Ni52Si15 amorphous membrane covered with Pd film of 10, 20, and 30 nm in thickness. Contrary to our expectations, we have found a dramatic decrease in hydrogen flow with the increase in Pd film thickness. Our findings are discussed in terms of potential barrier between the two different phases.
Słowa kluczowe
Wydawca
Czasopismo
Rocznik
Tom
Strony
56--58
Opis fizyczny
Bibliogr. 8 poz., rys.
Twórcy
autor
- Institute of Chemistry and Environmental Protection, Jan Długosz University of Częstochowa, Armii Krajowej 13/15, 42-200 Częstochowa, Poland
autor
- The Faculty of Microsystem Electronics and Photonics, Wrocław University of Technology, Janiszewskiego 11/17, 50-372 Wrocław, Poland
autor
- The Faculty of Microsystem Electronics and Photonics, Wrocław University of Technology, Janiszewskiego 11/17, 50-372 Wrocław, Poland
autor
- Institute of Physics, Jan Długosz University of Częstochowa, Armii Krajowej 13/15, 42-200 Częstochowa, Poland
Bibliografia
- [1] ITOH N., AICHE J., 33 (1987), 1576.
- [2] GRYAZNOV V.M., Platin. Met. Rev., 30 (1986), 68.
- [3] KIM K.B., KIM K.D., LEE D.Y., KIM Y.C., FLEURY E., KIMB D.H., Mat. Sci. Eng. A-Struct., 449 – 451 (2007), 934.
- [4] YAMAKAWA K., EGE M., LUDESCHER B., HIRSCHER M., KRONMÜLLER H., J. Alloy. Compd., 321 (2001), 17.
- [5] PROCHWICZ W., ST ˛ EPIE´N Z.M., Elektronika, 8 (2011), 19.
- [6] SHU J., GRANDJEAN B.P.A., VAN NESTE A., KALIAGUINE S., Can. J. Chem. Eng., 69 (1991), 1036.
- [7] BARRIE J.A., LEVINE J.D., MICHAELS A.S., WONG P., Trans. Faraday Soc., 59 (1963), 869.
- [8] YAMAURA S., INOUE A., J. Membrane Sci., 349 (2010), 138.
Typ dokumentu
Bibliografia
Identyfikator YADDA
bwmeta1.element.baztech-43fc41a9-ee15-4a57-8dc3-37dfc7094f5d