Identyfikatory
Warianty tytułu
Języki publikacji
Abstrakty
The paper presents the results of studies on the use of adsorptive properties of selected powdered activated carbons (Norit SA Super and Carbopol MB5) for removal of ibuprofen from water. The tests were performed on non-flow conditions, series depending on the type and dose of powdered adsorbents. The research was carried out on a model solution of ibuprofen at initial concentration C0 = 20 mg/dm3, at 20 °C. Froundlich and Langmuir adsorption isotherms were used. Lagergrene kinetic models (PFO) and Ho (PSO) were used to describe adsorption kinetics. Both carbons exhibited a higher affinity for the adsorbent at pH above 7. Norit SA Super was a better adsorbent, for which, the highest adsorption capacity q = 0.448 g/g was achieved with dose D = 35 mg/dm3. The effectiveness of adsorption (decrease of ibuprofen in water) was 78%. The total removal of ibuprofen was obtained for a dose of carbon D = 200 mg/ dm3. With respect to Carbopol, the highest adsorption capacity (q = 0.353 g/g) was achieved at a dose of 30 mg/dm3, resulting in a 53% efficiency. Studies have shown that both tested powdered activated carbons have contributed to effective cleaning of aqueous solutions containing ibuprofen.
Słowa kluczowe
Czasopismo
Rocznik
Tom
Strony
169--177
Opis fizyczny
Bibliogr. 17 poz., tab., rys.
Twórcy
autor
- Rzeszow University of Technology, The Faculty of Civil and Environmental Engineering and Architecture, Dept. of Water Purification and Protection, Poznańska St. 2, 35-084 Rzeszów, Poland
autor
- Rzeszow University of Technology, The Faculty of Civil and Environmental Engineering and Architecture, Dept. of Water Purification and Protection, Poznańska St. 2, 35-084 Rzeszów, Poland
autor
- Rzeszow University of Technology, The Faculty of Civil and Environmental Engineering and Architecture, Dept. of Water Purification and Protection, Poznańska St. 2, 35-084 Rzeszów, Poland
Bibliografia
- 1. Arya V., Philip L. 2016. Removal of Pharmaceuticals from Water Using Adsorption, Trends in Asian Water Environmental Science and Technology , Chapter 9, 105–114.
- 2. Czech B. 2012. Removal of pharmaceuticals from water and wastewater using adsorption and photocatalytic methods, Science for the Economy, 2, 443–452.
- 3. Deziel N.2014. Pharmaceuticals in Wastewater Treatment Plant Effluent Waters, Scholarly Horizons: University of Minnesota, Morris Undergraduate Journal, 2(4), 1–20.
- 4. Guzik U. Marchlewicz A., Wojcieszyńska D. 2015. Properties, occurrence and biodegradation of ibuprofen in aquatic environment, Environmental Protection (1), 65 – 70.
- 5. Heberer T. , Feldmann D. 2004. Removal of Pharmaceutical Residues from Contaminated Raw Water Sources by Membrane Filtration, Pharmaceuticals in the Environment, 391–410.
- 6. Ho Y.S., McKay G.1990. Pseudo-second-order model for sorption processes, Process Biochemistry, 34, 451–465.
- 7. Khetan S. K., Collins T. J. 2007.Human pharmaceuticals in the aquatic environment: a challenge to green chemisty,” Chemical Reviews, 107 (6), 2319–2364.
- 8. Kruszelnicka I., Ginter-Kramarczyk D., Zając A., Zembrzuska J. 2012. The problem of the presence of pharmaceuticals in sewage, Water Supply and Sewerage (5), 96–99.
- 9. Kümmerer K. 2009. The presence of pharmaceuticals in the environment due to human use-present knowledge and future challenges,” Journal of Environmental Management, 90(8), 2354–2366.
- 10. Lach J., Szymonik A. 2012. Hazards of the aquatic environment by the presence of pharmaceuticals, Engineering and Environmental Protection, 3, 249–263.
- 11. Lima D. R. S. , Baêta B. E. L. , Aquino S. F. 2014. Removal of Pharmaceuticals and Endocrine Disruptor Compounds from Natural Waters by Clarification Associated with Powdered Activated Carbon, Water, Air, & Soil Pollution, 225:2170.
- 12. Miralles-Cuevas S., Oller I., Sanchez Perez J.A., Malato S. 2015. Application of solar photo-Fenton at circumneutral pH to nanofiltration concentrates for removal of pharmaceuticals in MWTP effluents, Environmental Science and Pollution Research, 22(2), 846–855.
- 13. Nikolaou A., Meric S., Fatta D. 2007. Occurrence patterns of pharmaceuticals in water and wastewater environments,” Analytical and Bioanalytical Chemistry, 387(4), 1225–1234.
- 14. Płaziński W., Rudziński W. 2011. Adsorption kinetics on the border of phases solution/solid. Meaning of pseudo-first order and pseudo-second order equations, Chemical News 65 (11–12), 1055–1067.
- 15. Rodriguez E. 2016. Campinas M., Acero J. L., Investigating PPCP Removal from Wastewater by Powdered Activated Carbon/Ultrafiltration Water, Air, & Soil Pollution 227:177.
- 16. Tomska A. 2016. Influence of selected pharmaceuticals on activated sludge dehydrogenase activity, Ecological Engineering; 48, 214–218.
- 17. Tong A. Y. C. , Braund R. 2012. TiO2-assisted photodegradation of pharmaceuticals – a review, Open Chemistry,10/4, 989–1027.
Uwagi
PL
Opracowanie ze środków MNiSW w ramach umowy 812/P-DUN/2016 na działalność upowszechniającą naukę (zadania 2017).
Typ dokumentu
Bibliografia
Identyfikator YADDA
bwmeta1.element.baztech-43c492ce-fa27-4859-ad64-be37988686be