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Kompozyty na osnowie polimeru przewodzącego z udziałem nanorurek węglowych w czujnikach gazu DMMP – przegląd literatury
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Abstrakty
A number of recent terrorist attacks make it clear that rapid response, high sensitivity and stability are essential in the development of chemical sensors for the detection of chemical warfare agents. Nerve agent sarin [2-(fluoro-methyl-phosphoryl) oxypropane] is an organophosphate (OP) compound that is recognized as one of the most toxic chemical warfare agents. Considering sarin’s high toxicity, being odorless and colorless, dimethyl methylphosphonate (DMMP) is widely used as its simulant in the laboratory because of its similar chemical structure and much lower toxicity. Thus, this review serves to introduce the development of a variety of fabricated chemical sensors as potential sensing materials for the detection of DMMP in recent years. Furthermore, the research and application of carbon nanotubes in DMMP polymer sensors, their sensitivity and limitation are highlighted. For sorption-based sensors, active materials play crucial roles in improving the integral performances of sensors. The novel active materials providing hydrogen-bonds between the polymers and carbon nanotubes are the main focus in this review.
Przeprowadzone w ostatnich latach liczne ataki terrorystyczne jasno wskazują, że w wypadku czujników do wykrywania chemicznych środków bojowych są niezbędne: ich wysoka czułość, szybka reakcja i stabilność. Środek paralityczno-konwulsyjny sarin (2-fluorometylofosforylooksypropan) to związek fosforoorganiczny (OP) uznawany za jeden z najbardziej toksycznych dostępnych chemicznych środków bojowych. Ze względu na to, że jest on bezwonny, bezbarwny, a ponadto bardzo toksyczny, w badaniach laboratoryjnych szeroko stosuje się jego symulator – metylofosfonian dimetylu (DMMP), o podobnej strukturze chemicznej i znacznie mniejszej toksyczności. W artykule przedstawiono rozwój technologii czujników chemicznych do wykrywania gazu DMMP. Omówiono badania dotyczące wykorzystania kompozytów polimerowych z udziałem nanorurek węglowych w czujnikach gazu DMMP. W wypadku czujników, w których wykorzystuje się zjawisko sorpcji, kluczową rolę w poprawie ich wydajności odgrywają materiały aktywne. W niniejszym przeglądzie skupiono się na nowatorskich materiałach aktywnych, w których występują wiązania wodorowe między polimerem a nanorurkami węglowymi.
Czasopismo
Rocznik
Tom
Strony
85--97
Opis fizyczny
Bibliogr. 81 poz., rys. kolor.
Twórcy
autor
- National Defence University of Malaysia, Centre for Defence Foundation Studies, Kem Sungai Besi, 57000 Kuala Lumpur, Malaysia
autor
- National Defence University of Malaysia, Centre for Defence Foundation Studies, Kem Sungai Besi, 57000 Kuala Lumpur, Malaysia
autor
- National Defence University of Malaysia, Centre for Defence Foundation Studies, Kem Sungai Besi, 57000 Kuala Lumpur, Malaysia
autor
- National Defence University of Malaysia, Centre for Defence Foundation Studies, Kem Sungai Besi, 57000 Kuala Lumpur, Malaysia
autor
- Universiti Teknikal Malaysia Melaka, Faculty of Mechanical Engineering, Hang Tuah Jaya, 76100 Durian Tunggal, Melaka, Malaysia
autor
- National Defence University of Malaysia, Centre for Defence Foundation Studies, Kem Sungai Besi, 57000 Kuala Lumpur, Malaysia
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Uwagi
Opracowanie rekordu ze środków MNiSW, umowa Nr 461252 w ramach programu "Społeczna odpowiedzialność nauki" - moduł: Popularyzacja nauki i promocja sportu (2021).
Typ dokumentu
Bibliografia
Identyfikator YADDA
bwmeta1.element.baztech-43ae0428-e29e-45e7-a491-d633e03963cb