Ammonium-Assisted Intercalation of Java Bentonite as Effective of Cationic Dye Removal

Hakim, Yusuf Mathiinul; Mohadi, Risfidian; Mardiyanto; Royani, Idha

doi:10.12911/22998993/156665

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Tytuł artykułu

Ammonium-Assisted Intercalation of Java Bentonite as Effective of Cationic Dye Removal

Autorzy

Hakim Yusuf Mathiinul , Mohadi Risfidian , Mardiyanto , Royani Idha

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DOI

10.12911/22998993/156665

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Abstrakty

Modification of Java bentonite assists by the multi-step intercalation of sodium and ammonium ions under low-temperature preparation. The adsorbent was examined to remove rhodamine B and methylene blue dyes in an aqueous solvent. The analysis of structural changes conducted by XRD analysis showed the peak shifting from 19.89° to 16.1° and specific peak spectra FTIR of 2846.93 cm^-1 due to increase basal spacing from ammonium intercalation. The total capacities of NH-bentonite, Na-bentonite, and Natural Bentonite adsorption to rhodamine B were 192.308 mg/g, 136.936 mg/g, and 116.279 mg/g, respectively, under acidic conditions. Furthermore, the total capacities of NH-bentonite, Na-bentonite, and Natural Bentonite adsorption to methylene blue were 270.27 mg/g, 158.73 mg/g, and 136.986 mg/g, respectively, under alkaline conditions. The adsorption mechanism described that the rhodamine B and methylene blue removal occurred endothermically, was feasible, and adhered to the kinetics model of pseudo-second-order and Langmuir isotherm. It concluded that the modified Java Bentonite from multi-step intercalation is affordable and effective as wastewater treatment.

Słowa kluczowe

bentonite intercalation ammonium intercalant adsorption rhodamine B methylene blue

Wydawca

Polskie Towarzystwo Inżynierii Ekologicznej
Lublin University of Technology

Czasopismo

Journal of Ecological Engineering

Rocznik

2023

Tom

Vol. 24, nr 2

Strony

184--195

Opis fizyczny

Bibliogr. 60 poz., rys., tab.

Twórcy

autor

Hakim Yusuf Mathiinul

Graduate School, Faculty of Mathematics and Natural Sciences, Sriwijaya University, Palembang, 30139, Indonesia

https://orcid.org/0000-0003-3350-8129

autor

Mohadi Risfidian

risfidian.mohadi@unsri.ac.id

Department of Chemistry, Faculty of Mathematics and Natural Sciences, Sriwijaya University, Palembang, 30139, Indonesia

https://orcid.org/0000-0003-4974-4329

autor

Mardiyanto

Pharmaceutical Department, Faculty of Mathematics and Natural Sciences, Sriwijaya University, Palembang, 30139, Indonesia

https://orcid.org/0000-0002-2951-4123

autor

Royani Idha

Department of Physics, Faculty of Mathematics and Natural Sciences, Sriwijaya University, Palembang, 30139, Indonesia

https://orcid.org/0000-0002-2068-9517

Bibliografia

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Uwagi

Opracowanie rekordu ze środków MEiN, umowa nr SONP/SP/546092/2022 w ramach programu "Społeczna odpowiedzialność nauki" - moduł: Popularyzacja nauki i promocja sportu (2022-2023).

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Bibliografia

Identyfikator YADDA

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