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We have supplemented the already formulated microscopic theory of optical properties of very ultrathin molecular films (quantum nanofilms), i.e., quasi 2D systems parallel to XY planes bounded by two surfaces. The exposure of nanofilms to the external electromagnetic fields has resulted in the creation of excitons, but different than bulk ones in one direction perpendicular to surfaces. The analysis of the dielectric response of the system to perturbation of an external electromagnetic field shows that optical properties of these crystalline nanosystems for low exciton concentration of Frenkel’s excitons strongly depend on boundary parameters and the thickness of the film. In addition, the dynamical absorption and the refraction coefficient show a very narrow and discrete dependence of external electromagnetic field frequency, which is the consequence of both resonance and quantum size effects. Influences of boundary conditions on optical characteristics (through the analyses of dynamical absorption and refraction indices) of these nanostructures were specially and in details explored. The emission and the luminescence spectrum of the whole film have been analyzed and the results compared to experimental data show very good behavior and very good coordination.
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641--649
Opis fizyczny
Bibliogr. 12 poz., wykr.
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autor
- University of Novi Sad, Faculty of Sciences, Department of Physics, Trg Dositeja Obradovica 4, 21000 Novi Sad, Vojvodina, Serbia
autor
- University of Banja Luka, Faculty of Technology, Vojvode Stepe Stepanovica 73, 78000 Banja Luka, Republic of Srpska, Bosnia and Herzegovina
autor
- University of East Sarajevo, Faculty of Technology in Zvornik, Karakaj bb, 75400 Zvornik, Republic of Srpska, Bosnia and Herzegovina
autor
- Academy of Criminalistic and Police Studies, Cara Dušana 196, 11080 Zemun – Belgrade, Serbia
autor
- University of Novi Sad, Faculty of Sciences, Department of Physics, Trg Dositeja Obradovica 4, 21000 Novi Sad, Vojvodina, Serbia
Bibliografia
- [1] ŠETRAJČIĆ J.P., ILIĆ D.I., MARKOSKI B., ŠETRAJČIĆ A.J., VUČENOVIĆ S.M., MIRJANIĆ D.LJ., ŠKIPINA B., PELEMIŠ S., Conformation and application of Green's functions method to optical properties of ultrathin molecular films searching, [In] 15th Central European Workshop on Quantum Optics, Belgrade, Serbia, 2008.
- [2] PELEMIŠ S.S., ŠETRAJČIĆ J.P., MARKOSKI B., DELIĆ N.V., VUČENOVIĆ S.M., Selective absorption in twolayered optic films, Journal of Computational and Theoretical Nanoscience 6(7), 2009, pp. 1474–1477.
- [3] ŠKIPINA B., MIRJANIĆ D.LJ., VUČENOVIĆ S.M., ŠETRAJČIĆ J.P., ŠETRAJČIĆ I.J., ŠETRAJČIĆ-TOMIĆ A.J., PELEMIŠ S.S., MARKOSKI B., Selective IR absorption in molecular nanofilms, Optical Materials 33(11), 2011, pp. 1578–1584.
- [4] ŠETRAJČIĆ J.P., PELEMIŠ S.S., VUČENOVIĆ S.M., ZORIĆ V.M., ARMAKOVIĆ S., ŠKIPINA B., ŠETRAJČIĆ A.J., Absorption features of symmetric molecular nanofilms, [In] 27th International Conference on Microelectronics Proceedings (MIEL), Nis, Serbia, 2010, pp. 127–130.
- [5] AGRANOVICH V.M., GINZBURG V.L., Crystal Optics with Space Dispersion – Theory of Excitons, Nauka, Moskwa, 1979, (in Russian).
- [6] AGRANOVICH V.M., TOSICH B.S., Collective properties of Frenkel excitons, ZhETF 53, 1967, pp. 149–173.
- [7] ŠETRAJČIĆ J.P., Exact Microtheoretical Approach to Calculation of Optical Properties of Ultralow Dimensional Crystals, arXiv:cond-mat/eprint:1004.2387, April 2010.
- [8] DZYALOSHINSKI I.E., PITAEVSKI L.P., Van-der-Vaals forces in anisotropic dielectric, ZhETF 36, 1959 pp. 1797–1805.
- [9] RONDA C.R. [Ed.], Luminescence – From Theory to Applications, Chapter 1, Wiley, Weinheim, 2008.
- [10] VRAGOVIĆ I.D., ŠETRAJČIĆ J.P., SCHOLZ R., Quantum size effects in the optical properties of organic superlattices containing 3, 4, 9, 10 perylene tetracarboxylic dianhydride (PTCDA), European Physical Journal B 66(2), 2008, pp. 185–190.
- [11] GALANIN M.D., Luminescence of Molecules and Crystals, Cambridge IPC, Cambridge, 1996. p. 116.
- [12] HIPPIUS C., VAN STOKKUM I.H.M., GSÄNGER M., GROENEVELD M.M., WILLIAMS R.M., WÜRTHNER F., Sequential FRET processes in calix[4]arene-linked orange-red-green perylene bisimide dye zigzag arrays, Journal of Physical Chemistry C 112(7), 2008, pp. 2476–2486.
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Bibliografia
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bwmeta1.element.baztech-428642e8-4868-4f7b-b4ad-62232e4b683d