Effect of pH on adsorption and desorption of hexadecyl trimethyl ammonium bromide from silicate surface

• Autorzy: Karaguzel C. , Xu Z.

Identyfikatory

DOI

10.5277/ppmp170206

• Języki publikacji: EN

Abstrakty

EN

Hexadecyl trimethyl ammonium bromide (HTAB), a cationic surfactant, is physically adsorbed on negatively charged silicate surfaces due to electrostatic forces. This reversible adsorption process is important for surfactant regeneration in some industrial applications such as waste water treatment. Cationic surfactant adsorption and desorption from silica surfaces were studied using several methods such as UV, FTIR, XPS, and XRD. However, most of these methods are time independent and ex situ in nature. Quartz crystal microbalance with dissipation monitoring (QCM-D) is a power tool that can determine the amount and thickness of the deposited material on the surface in situ as a function of time. In this study, the adsorption and desorption characteristic of HTAB was studied on the silica sensor surface by using QCM-D. The adsorption and desorption tests were performed at a constant HTAB concentration (5·10-4 M, close to CMC of HTAB) at different pH values (3, 5.5, 6.5 and 10). The results obtained from these studies clearly showed that pH is a critical factor determining the adsorption and desorption processes.

Słowa kluczowe

EN

adsorption; silica sensor; hexadecyl trimethyl ammonium bromide; quartz crystal micro-balance with dissipation monitoring

• Wydawca: Oficyna Wydawnicza Politechniki Wrocławskiej
• Czasopismo: Physicochemical Problems of Mineral Processing
• Rocznik: 2017
• Tom: Vol. 53, iss. 2
• Strony: 750--757
• Opis fizyczny: Bibliogr. 27 poz., rys., tab.

Twórcy

autor

Karaguzel C.

• University of Dumlupinar, Department of Mining Engineering, Kutahya, Turkey

autor

Xu Z.

• University of Alberta, Department of Chemical and Materials Engineering, Edmonton, Alberta, Canada

Bibliografia

• ATKIN R., CRAIG V.S.J., WANLESS E. J., BIGGS S., 2003, Mechanism of cationic surfactant adsorption at the solid–aqueous interface, Advances in Colloid and Interface Science, 103, 219–304.
• BAJPAI A.K. and RAJPOOT M., 1999, Adsorption Techniques- A Review, Journal of Scientific & Industrial Research, 58, 844-860.
• BELLO O.S., BELLO I.A. and ADEGOKE, K.A., 2013, Adsorption of dyes using different types of sand: A Review, S. Afr. J. Chem., 66, 117-129.
• BHATTACHARYYA K.G. and GUPTA S.S., 2008, Adsorption of a few heavy metals on natural and modified kaolinite and montmorillonite: A review, Advances in Colloid and Interface Science, 140, 114–131.
• CHERNYSHOVA I.V., RAO K.H, and VIDYADHAR A., 2000, Mechanism of adsorption of long-chain alkylamines on silicates. A spectroscopic study. 1. Quartz, Langmuir, 2000, 16(21), 8071–8084.
• CHURAEV N.V., SERGEEVA I.P., SOBOLEV V.D., JACOBASCH H. J., WEIDENHAMMER P., SCHMITT F. J., 2000, Modification of quartz surfaces using cationic surfactant solutions, Colloids and Surfaces A: Physicochemical and Engineering Aspects, 164, 121-129.
• ERSOY B., CELIK, M.S., 2003, Effect of hydrocarbon chainlength on adsorption of cationic surfactants onto clinoptilolite, Clays and Clay Minerals, 51, 173-181.
• HORR T.J., ARORA P.S., RALSTON J., SMART R.C., 1995, XPS film thickness and adsorption studies of alkyltrimethylammonium bromides and organosilans on silica surfaces, Colloids and Surfaces A: Physicochemical and Engineering Aspects, 102, 181-190.
• INDRA D. MALL, VIMAL C. SRIVASTAVA, NITIN K. AGARWAL., 2006, Removal of orange-G and methyl violet dyes by adsorption onto bagasse fly ash kinetic study and equilibrium isotherm analyses, Dyes and Pigments, 69,210-9223.
• ISMADJI S., SOETAREDJO F.E., AYUCITRA A., 2015, Natural clay minerals as environmental cleaning agents, Chapter 2, Clay Materials for Environmental Remediation, Springer Briefs in Green Chemistry for Sustainability, DOI 10.1007/978-3-319-16712-1_2, VIII, 124 p.
• JUNIOR J.A.A., BALDO J.B., 2014, The behavior of zeta potential of silica suspensions, New Journal of Glass and Ceramics, 4, 29-37.
• KARAKAS F., VAZIRI HASSAS B., 2016, Effect of surface roughness on interaction of particle in flotation, Physicochem. Probl. Miner. Process., 52(1), 18-34.
• KARATAS D., TEKIN A., CELIK M.S., 2013, Adsorption of quaternary amine surfactants and their penetration into the intracrystalline cavities of sepiolite, New Journal of Chemistry,37, 3936-3948.
• KOU J. and XU S., 2016, In situ kinetics and conformation studies of dodecylamine adsorption onto zinc sulfide using a quartz crystal microbalance with dissipation (QCM-D), Colloids and Surfaces A: Physicochemical and Engineering Aspects, 490, 110-120.
• KOU J., TAO D., and XU G., 2010, A study of adsorption of dodecylamine on quartz surface using quartz crystal microbalance with dissipation, Colloids and Surfaces a-Physicochemical and Engineering Aspects, 368(1-3), 75-83.
• KOU J., TAO D., and XU G., 2010, Fatty acid collectors for phosphate flotation and their adsorption behavior using QCM-D, International Journal of Mineral Processing, 95(1-4), 1-9.
• LAKHERWAL D., 2014, Adsorption of heavy metals: A review, International Journal of Environmental Research and Development, 4(1), 41-48.
• NOVIKOVA L. and BELCHINSKAYA L., 2016, Adsorption of industrial pollutants by natural and modified aluminosilicates, Chapter 4, InTech, http://dx.doi.org/10.5772/61678, pp. 89-128.
• OZDEMIR O., ARMAGAN B., TURAN M., CELIK M.S., 2004, Comparison of the adsorption characteristics of azo-reactive dyes on mezoporous minerals, Dyes and Pigments, 62, 49–60.
• RUTLAND M.W., PARKER J.L., 1994, Surface forces between silica surfaces in cationic surfactant solutions: Adsorption and bilayer formation at normal and high pH, Langmuir, 10, 1110-1121.
• SABAH E., TURAN M., CELIK M.S., 2002, Adsorption mechanism of cationic surfactants onto acid-and heat-activated sepiolites, Water Research, 36, 3957–3964.
• SAUERBREY G., 1959, Verwendung von Schwingquarzen zur wägung dünner schichten und zur mikrowägung, Z Phys., 155, 206–222.
• WANG S., PENG Y., 2010, Natural zeolites as effective adsorbents in water and wastewater treatment, Chemical Engineering Journal, 156, 11–24.
• YAPAR S. and YILMAZ, M., 2004, Removal of phenol by using montmorillonite, clinoptilolite and hydrotalcite, Adsorption, 10, 287–298.
• YESILYURT Z., BOYLU F., CINKU K., ESENLI F., CELIK M.S., 2014, Simultaneous purification and modification process for organobentonite production, Applied Clay Sci., 95, 176-181.
• ZDZIENNICKA A., SZYMCZYK K and JANCUK B., 2009, Correlation between surface free energy of quartz and its wettability by aqueous solutions of nonionic, anionic and cationic surfactants, Journal of Colloid and Interface Science, 340, 243-248.
• ZHU R., CHEN Q., ZHOU Q., XI Y., ZHU J., HE H., 2016, Adsorbents based on montmorillonite for contaminant removal from water: A review, Applied Clay Science, 123, 239–258.