Optimization of production process of epoxidized soybean oil with high oxygen content through response surface methodology

• Autorzy: Zhang Fengyan , Dong Yonglu , Lin Sudong , Gui Xuefeng , Hu Jiwen

Identyfikatory

DOI

10.2478/pjct-2023-0013

• Języki publikacji: EN

Abstrakty

EN

The epoxidation process of soybean oil (SBO) and peracid produced by 50 wt% hydrogen peroxide (H₂O₂) and formic acid (FA) was studied with sulfuric acid (H₂SO₄) as a catalyst. Three reaction parameters, including reaction temperature, FA-to-SBO ratio, and H₂O₂-to-SBO ratio, were investigated, along with the combined effect on oxirane value (OV). Based on response surface methodology (RSM), the Box-Behnken design (BBD) was used to optimize the process parameters. According to the results, the calculated OV (7.34%) and the experimental OV (7.31%) were significantly in agreement. The product was con firmed as epoxidized soybean oil (ESO) by IR and NMR characterization methods. These results demonstrated the reliability of RSM to optimize the SBO reaction to produce ESO with high oxygen content.

Słowa kluczowe

EN

soybean oil; response surface methodology; epoxidation; oxirane value

• Wydawca: West Pomeranian University of Technology. Publishing House
• Czasopismo: Polish Journal of Chemical Technology
• Rocznik: 2023
• Tom: Vol. 25, nr 2
• Strony: 21--29
• Opis fizyczny: Bibliogr. 29 poz., rys., tab., wz.

Twórcy

autor

Zhang Fengyan

• Guangzhou Institute of Chemistry, Chinese Academy of Sciences, Guangzhou 510650, P. R. China
• University of Chinese Academy of Sciences, Beijing 100049, P. R. China

autor

Dong Yonglu

• Management Committee of Shaoguan NanXiong Hi-teac Industry Development Zone, Nanxiong 512400, P. R. China

autor

Lin Sudong

• Guangzhou Institute of Chemistry, Chinese Academy of Sciences, Guangzhou 510650, P. R. China
• University of Chinese Academy of Sciences, Beijing 100049, P. R. China
• Guangdong Provincial Key Laboratory of Organic Polymer Materials for Electronics, Guangzhou 510650, P. R. China
• CAS Engineering Laboratory for Special Fine Chemicals, Guangzhou 510650, P. R. Chin
• CASH GCC Shaoguan Research Institute of Advanced Materials, Nanxiong 512400, P. R. Chin

autor

Gui Xuefeng

• Guangzhou Institute of Chemistry, Chinese Academy of Sciences, Guangzhou 510650, P. R. China
• Guangdong Provincial Key Laboratory of Organic Polymer Materials for Electronics, Guangzhou 510650, P. R. Chin
• CAS Engineering Laboratory for Special Fine Chemicals, Guangzhou 510650, P. R. China
• CASH GCC Shaoguan Research Institute of Advanced Materials, Nanxiong 512400, P. R. China

autor

Hu Jiwen

• Guangzhou Institute of Chemistry, Chinese Academy of Sciences, Guangzhou 510650, P. R. China
• University of Chinese Academy of Sciences, Beijing 100049, P. R. China
• Guangdong Provincial Key Laboratory of Organic Polymer Materials for Electronics, Guangzhou 510650, P. R. China
• CAS Engineering Laboratory for Special Fine Chemicals, Guangzhou 510650, P. R. China
• CASH GCC Shaoguan Research Institute of Advanced Materials, Nanxiong 512400, P. R. China
• Management Committee of Shaoguan NanXiong Hi-teac Industry Development Zone, Nanxiong 512400, P. R. China

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Uwagi

Opracowanie rekordu ze środków MEiN, umowa nr SONP/SP/546092/2022 w ramach programu "Społeczna odpowiedzialność nauki" - moduł: Popularyzacja nauki i promocja sportu (2022-2023).