Growth, electrical, thermal, mechanical and etching studies on 4-chloroanilinium hydrogen (2R, 3R)-tartrate monohydrate-an organic NLO single crystal

• Autorzy: Sivakumar R. , Nadaraj V.

Identyfikatory

DOI

10.2478/msp-2019-0054

• Języki publikacji: EN

Abstrakty

EN

An organic single crystal of 4-chloroanilinium hydrogen (2R,3R)-tartrate monohydrate (4CAHT) was grown by slow evaporation solution growth technique at room temperature. Single crystal XRD study confirmed that the crystal belongs to monoclinic system with the space group P2₁. Powder XRD analysis confirmed the crystalline nature of the compound. The presence of various functional groups in the compound was revealed by FT-IR analysis. UV studies showed the absence of absorption in the entire visible region. To determine the thermal stability of the grown crystals it was subjected to thermogravimetric and differential thermal analyses. Microhardness and etching studies were also carried out for the crystal. The powder second harmonic generation efficiency of 4CAHT was tested by Kurtz and Perry powder technique and the relative SHG efficiency of 4CAHT was found to be 1.44 times greater than that of standard KDP.

Słowa kluczowe

EN

nonlinear optics; TG-DTA; dielectric constant; Vickers hardness

• Wydawca: De Gruyter
• Czasopismo: Materials Science Poland
• Rocznik: 2019
• Tom: Vol. 37, No. 3
• Strony: 310--316
• Opis fizyczny: Bibliogr. 22 poz., rys., tab.

Twórcy

autor

Sivakumar R.

• Department of Chemistry, Hindusthan Institute of Technology, Coimbatore-641032, INDIA.

autor

Nadaraj V.

• Department of Chemistry, Tamilnadu College of Engineering, Coimbatore-641659, INDIA.

Bibliografia

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Uwagi

PL

Opracowanie rekordu w ramach umowy 509/P-DUN/2018 ze środków MNiSW przeznaczonych na działalność upowszechniającą naukę (2019).