Kinetic, isotherm and thermodynamics investigation on adsorption of divalent copper using agro-waste biomaterials, Musa acuminata, Casuarina equisetifolia L. and Sorghum bicolor

Mokkapati, R.P.; Mokkapati, J.; Ratnakaram, V.N.

doi:10.1515/pjct-2016-0031

Artykuł - szczegóły

Tytuł artykułu

Kinetic, isotherm and thermodynamics investigation on adsorption of divalent copper using agro-waste biomaterials, Musa acuminata, Casuarina equisetifolia L. and Sorghum bicolor

Autorzy

Mokkapati R.P. , Mokkapati J. , Ratnakaram V.N.

Treść / Zawartość

Pełne teksty:

Polish Journal of Chemical Technology_2_2016_Mokkapati.pdf

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Identyfikatory

DOI

10.1515/pjct-2016-0031

Warianty tytułu

Języki publikacji

Abstrakty

Three novel and distinct agricultural waste materials, viz., Casuarinas fruit powder (CFP), sorghum stem powder (SSP) and banana stem powder (BSP) were used as low cost adsorbents for the removal of toxic copper(II) from aqueous solutions. Acid treated adsorbents were characterized by SEM, EDX and FTIR. Different factors effecting adsorption capacity were analyzed and the efficiency order was BSP>SSP>CFP. Based on the extent of compatibility to Freundlich/Langmuir/D-R/Temkin adsorption isotherm and different models (pseudo-first and second order, Boyd, Weber’s and Elovich), chemisorption primarily involved in the case of CFP and SSP, whereas, simultaneous occurrence of chemisorption and physisorption was proposed in the case of BSP. Based on the observations, it was proposed that three kinetic stages involve in adsorption process viz., diffusion of sorbate to sorbent, intra particle diffusion and then establishment of equilibrium. These adsorbents have promising role towards removal of Cu(II) from industrial wastewater to contribute environmental protection.

Słowa kluczowe

banana bunch-stem powder casuarinas fruit powder sorghum stem powder removal copper adsorption

Wydawca

West Pomeranian University of Technology. Publishing House

Czasopismo

Polish Journal of Chemical Technology

Rocznik

2016

Tom

Vol. 18, nr 2

Strony

68--77

Opis fizyczny

Bibliogr. 55 poz., rys., tab.

Twórcy

autor

Mokkapati R.P.

Acharya Nagarjuna University, Department of Chemistry, ANUCET, Guntur – 522510, India

autor

Mokkapati J.

Acharya Nagarjuna University, Department of Biotechnology, Guntur – 522510, India

autor

Ratnakaram V.N.

doctornadh@yahoo.co.in

GITAM University – Bengaluru, Karnataka – 561203, India

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Uwagi

Opracowanie ze środków MNiSW w ramach umowy 812/P-DUN/2016 na działalność upowszechniającą naukę.

Typ dokumentu

Bibliografia

Identyfikator YADDA

bwmeta1.element.baztech-3f99f32c-2ded-4019-a5c2-5c32dca89bee