Immobilization of rambutan (Nephelium lappaceum) peel as a sorbent for Basic Fuchsin removal

• Autorzy: Lee H.-J. , Ong S.-T.

Identyfikatory

DOI

10.5277/epe170114

• Języki publikacji: EN

Abstrakty

EN

The potential of rambutan (Nephelium lappaceum) peel as a low-cost adsorbent in an immobilized condition to remove Basic Fuchsin from aqueous solution was studied. The effect of initial dye concentration, contact time, pH and adsorbent dosage for the dye removal was studied at room temperature (26±2 °C). Infrared spectrum of rambutan peel indicates the presence of C–O, –OH and C=C functional groups. The adsorption rate was found to be high at the first 30 min and the process reached equilibrium after 3 h with more than 80% of dye being removed. The uptake of Basic Fuchsin was more promising at pH slightly above 7. The study of sorption model and kinetic model showed that the adsorption of Basic Fuchsin on rambutan peel conformed to the Freundlich isotherm and pseudo-second order kinetics with a high correlation coefficient, R,sup>2 > 0.98. This indicates the Basic Fuchsin adsorbs chemically on the heterogeneous surface of rambutan peel. The maximum adsorption capacity determined from the Langmuir isotherm was 108.696 mg/g. It seems that rambutan peel has the potential to substitute activated carbon as an alternative low-cost adsorbent in the treatment of the dye effluent.

Słowa kluczowe

EN

fuchsin; Fourier transform infrared spectrophotometry; FTIR; Nephelium lappaceum

PL

fuksyna; FTIR; spektroskopia w podczerwieni z transformatą Fouriera; Nephelium lappaceum

• Wydawca: Oficyna Wydawnicza Politechniki Wrocławskiej
• Czasopismo: Environment Protection Engineering
• Rocznik: 2017
• Tom: Vol. 43, nr 1
• Strony: 169--181
• Opis fizyczny: Bibliogr. 22 poz., tab., rys.

Twórcy

autor

Lee H.-J.

• Department of Chemical Science, Faculty of Science, Universiti Tunku Abdul Rahman, Jalan Universiti, Bandar Barat, 31900 Kampar, Perak, Malaysia

autor

Ong S.-T.

• Department of Chemical Science, Faculty of Science, Universiti Tunku Abdul Rahman, Jalan Universiti, Bandar Barat, 31900 Kampar, Perak, Malaysia.
• Centre for Biodiversity Research, Universiti Tunku Abdul Rahman, Jalan Universiti, Bandar Barat, 31900 Kampar, Perak, Malaysia

Bibliografia

• [1] LAM S.M., SIN J.C., ABDULLAH A.Z., MOHAMED A.R., Degradation of wastewaters containing organic dyes photocatalysed by zinc oxide. A review, Des. Water Treat. J., 2012, 41, 131.
• [2] ONG S.T., SEOU C.K., Removal of reactive black 5 from aqueous solution using chitosan beads. Optimization by Plackett–Burmann design and response surface analysis, Des. Water Treat. J., 2014, 52, 7673.
• [3] SALEH T.A., AL-SAADI A.A., GUPTA V.K., Carbonaceous adsorbent prepared from waste tires: Experimental and computational evaluations of organic dye methyl orange, J. Mol. Liq., 2014, 191, 85.
• [4] GUPTA V.K., NAYAK A., Cadmium removal and recovery from aqueous solutions by novel adsorbents prepared from orange peel and Fe2O3 nanoparticles, Chem. Eng. J., 2012, 180, 81.
• [5] SALEH T.A., GUPTA V.K., Photo-catalyzed degradation of hazardous dye methyl orange by use of a composite catalyst consisting of multi-walled carbon nanotubes and titanium dioxide, J. Coll. Inter. Sci., 2012, 371, 101.
• [6] HEIBATI B., RODRIGUEZ-COUTO S., AL-GHOUTI M.A., ASIF M., TYAGI I., AGARWAL S., GUPTA V.K., Kinetics and thermodynamics of enhanced adsorption of the dye AR 18 using activated carbons pre-pared from walnut and poplar woods, J. Mol. Liq., 2015, 208, 99.
• [7] MAHMOODIAN H., MORADI O., SHARIATZADEHA B., SALEH T.A., TYAGI I., MAITY A., ASIF M., GUPTA V.K., Enhanced removal of methyl orange from aqueous solutions by poly HEMA–chitosan–MWCNT nanocomposite, J. Mol. Liq., 2015, 202, 189.
• [8] GUPTA V.K., JAIN R., MITTAL A., SALEH T.A., NAYAK A., AGARWAL S., SIKARWAR S., Photo-catalytic deg-radation of toxic dye amaranth on TiO2/UV in aqueous suspensions, Mat. Sci. Eng. C, 2012, 32, 12.
• [9] SARAVANAN R., GUPTA V.K., NARAYANAN V., STEPHEN A., Visible light degradation of textile effluent using novel catalyst ZnO/g-Mn2O3, J. Taiwan Inst. Chem. Eng., 2014, 45, 1910.
• [10] THITILERTDECHA N., TEERAWUTGULRAG A., KILBURN J.D., RAKARIYATHAM N., Identification of major phenolic compounds from Nephelium lappaceum L. and their antioxidant activities, Molecules, 2010, 15 (3), 1453.
• [11] Industrial Dyes. Chemistry, Properties, Applications, K. Hunger (Ed.), Wiley, Weinheim 2003.
• [12] ONG S.T., TAN S.Y., KHOO E.C., LEE S.L., HA S.T., Equilibrium studies for Basic Blue 3 adsorption onto durian peel (Durio zibethinus Murray), Des. Water Treat. J., 2012, 45 (1–3), 161.
• [13] SHI Q., ZHANG J., ZHANG C.L., NIE W., ZHANG B., ZHANG H., Adsorption of Basic Violet 14 in aqueous solution using KMnO4-modified activated carbon, J. Coll. Inter. Sci., 2010, 343, 188.
• [14] LANGERGREN S., SVENSKA B.K., Zur theorie der sogenannten adsorption geloester stoffe, Veterns-kapsakad Hand., 1898, 24, 1.
• [15] HO Y.S., MCKAY G., Pseudo-second order model for sorption processes, Proc. Biochem., 1999, 34, 451
• [16] BASHA S., MURTHY Z.V.P., JHA B., Sorption of Hg(I) onto Carica papaya: Experimental studies and design of batch sorber, Chem. Eng. J., 2009, 147 (2–3), 226.
• [17] HO Y.S., MCKAY G., The kinetics of sorption of divalent metals ions onto sphagnum moss peat, Water Res., 2000, 34, 735.
• [18] GUPTA V.K., MITTAL A., GAJBE V., MITTAL J., Adsorption of basic fuchsin using waste materials-bot-tom ash and deoiled soya-as adsorbents, J. Coll. Inter. Sci., 2008, 319, 30.
• [19] ONG S.T., KHOO E.C., HII S.L., HA S.T., Utilization of sugarcane bagasse for removal of basic dyes from aqueous environment in single and binary systems, Des. Water Treat. J., 2010, 20, 86.
• [20] LANGMUIR I., The adsorption of gases on plane surfaces of glass, mica and platinum, J. Am. Chem. Soc., 1918, 40, 1361.
• [21] FREUNDLICH H., Adsorption in solution, Phys. Chem. Soc., 1906, 40, 1361.
• [22] JIANG Y.X., XU H.J., LIANG D.W., TONG Z.F., Adsorption of Basic Violet 14 from aqueous solution on bentonite, C. R. Chimie, 2008, 11, 125.

Uwagi

PL

Opracowanie ze środków MNiSW w ramach umowy 812/P-DUN/2016 na działalność upowszechniającą naukę (zadania 2017).