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In this article there is discussed a possibility of forming the liquid crystal structure in ionic liquids and its influence on performance characteristics, especially tribological, of these liquids. Formation of such thermal phase might influence on, among other things, easier creation of the boundary lubricating film, which is characterized by high viscous anisotropy. The results of tribological tests showed better lubricity of selected ionic liquids than modern PFPE oils. Identification of mesophase in ionic liquids was necessary. This method is described in the paper. Biolar PL polarizing interference microscope with thermal stabilizing table, with birefraction system, and Brüker Discover 8 powder diffraction instrument with a Cu lamp and monochromator were used. There was being searched the state characterized simultaneously by optical anisotropy properties and liquid state of aggregation. For identification of phase transition temperature, the additional calorimetric tests were carried out during the cycle of heating and cooling. These researches were carried out within the framework of the development and research project no. PBR 15-249/2007/WAT-OR0002904, financed by Ministry of Science and Higher Education during 2007-2011.
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Czasopismo
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Tom
Strony
143--156
Opis fizyczny
Bibliogr. 20 poz., rys.
Twórcy
autor
- Military University of Technology, Faculty of Mechanical Engineering Faculty of New Technology and Chemistry Gen. S. Kaliskiego Street 2, 00-908 Warsaw, Poland tel. +48 261 837384, 261 839565, 261 839731
autor
- Military University of Technology, Faculty of Mechanical Engineering Faculty of New Technology and Chemistry Gen. S. Kaliskiego Street 2, 00-908 Warsaw, Poland tel. +48 261 837384, 261 839565, 261 839731
autor
- Military University of Technology, Faculty of Mechanical Engineering Faculty of New Technology and Chemistry Gen. S. Kaliskiego Street 2, 00-908 Warsaw, Poland tel. +48 261 837384, 261 839565, 261 839731
autor
- Tribochemistry Consulting, Salt Lake City, Utah 84117, USA
Bibliografia
- [1] Wassercheid, P., Welton, T., (Eds.), Ionic Liquids in Synthesis. Second, Completely Revised and Enlarged Edition, Wiley-WCH Verlag GmbH & Co. KgaA, Weinheim, 2008.
- [2] Chengfeng, Y., Weimin, L., Yangxia, Ch., Laingui, Y., Room temperature ionic liguids, a novel versatile lubricants. Chemical Comminication no 21, pp. 2244-2245, 2001.
- [3] Haizhong, W., Qiming, L., Chengfeng, Y., Weimin, L., Zhaojie, C., Friction and wear behaviors of ionic liquid of alkylimidazolium hexafluorophosphates as lubricants for steel-steel contact. Wear 2004, 256, pp. 44-48, 2004.
- [4] Qu, J., Truhan, .J, Dai, S., Luo, H., Blau, P.J., Ionic liquids with ammonium cations as lubricants or additives. Tribology Letters, no 22 (3), pp. 207-214, 2006.
- [5] Suzuki, A., Shinka, Y., Masuko, M., Tribological characteristics of imidazolium-based room temperature ionic liquids under high vacuum. Tribology Letters, vol. 27, pp. 307-3013, 2007.
- [6] Qu, J., Truhan, J., Dai, S., Luo, H., Blau, P. J., Ionic Liquids with ammonium cations as lubricants or additives. Tribology Letters 2006, vol. 22 (3), pp. 207-214, 2006.
- [7] Nakano, K., Sealing law on molecular orientation and effective viscosity of liquid crystalline boundary films. Tribology, Letters 2003, vol. 14, pp. 17-24, 2003.
- [8] Katayanagi, H., Hayashi, S., Hamaguchi, H., Nishikawa, K., Structure of an ionic-1-n-butyl-3-methylimidazolium iodide studied by wide-angle X-ray scattering and Raman Spectroscopy. Chemical Physics Letters, 392, pp. 460-464, 2004.
- [9] Neve, F., Francescangeli O., Crispini, A., Crystal architecture and mesophase structure of long-chain N-alkylpyridinium tetrachlorometallates. Inorganica Chimica Acta, 338, pp. 51-58, 2002.
- [10] Bradley, A. E., Hardacre, C., Holbrey, J. D., Johnston, S., McMath, S. E. J., Nieuwenhuyzen, M., Small-angle X-ray scattering studies of liquid crystalline 1-alkyl-3-methylimidazolium salts. Chemistry of Materials no 14, pp. 629-635, 2002.
- [11] Kałdoński, T. (Red.), Porowate łożyska ślizgowe nowej generacji – badania i prognozy (The new generation of porous sliding bearings – research and prognosis). Military University of Technology, Warsaw, 2013.
- [12] Kałdoński, T. J., Badania i ocena alkoksymetyloimidazolowych cieczy jonowych jako nowych smarów do stalowych węzłów tribologicznych (Doctor’s thesis – Testing and evaluation of alkoxymethylimidazole ionic liquids as new lubricants for the steel tribological nodes). Military University of Technology, Warsaw 2012.
- [13] Kałdoński, T. J., Ciecze jonowe – perspektywiczne oleje smarujące (Ionic liquids – perpective lubricating oils). Military University of Technology, Warsaw, 2014.
- [14] Patent specification PL 203064, 31.08.2009 WUP 08/09, Imidazolowe ciecze jonowe i sposób wytwarzania imidazolowych cieczy jonowych (Imidazole ionic liquids and the way of producting imidazole ionic liquids).
- [15] Inf. Mat. Chemical Reagents J.S.C. POCH S.A., Gliwice-Poland.
- [16] Inf. Mat. Sigma-Aldrich, ChemFiles-Enbling Technologies-Ionic Liquids, Vol. 5, No 6, 2005.
- [17] Inf. Mat. Solvay Solexis, Fomblin PEPE Lubricants (www.solvaysolexis.com).
- [18] Jones Jr., W. R., Properties of perfluoropolyethers for space applications. NASA TM 106616, 1994.
- [19] Jones Jr, W. R., Properties of perfluoropolyethers for space mechanism. Tribology Transactions, vol. 38 (3), pp. 557-564, 1995.
- [20] Polish Standard, PN-76/C-04147., Przetwory naftowe. Badanie właściwości smarnościowych olejów i smarów (Petroleum products. Research lubricating ability properties of oils and greases).
Typ dokumentu
Bibliografia
Identyfikator YADDA
bwmeta1.element.baztech-3f0a25ff-db83-4fd8-a261-6b91c27859f9
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