Comparative Studies on the Codeposition of Antimony and Tin from Acidic Chloride and Sulfate-Chloride Solutions

• Autorzy: Rudnik E. , Kostępski M.

Identyfikatory

DOI

10.24425/122397

• Języki publikacji: EN

Abstrakty

EN

Codeposition of antimony and tin from acidic chloride and chloride-sulfate baths was investigated. The calculations of distribution of species showed domination of neutral SnCl₂ and anionic SbCl₄^- complexes in chloride solution, while in the presence of sulfate ions neutral SnSO₄ and cationic SbCl²⁺ complexes were found. Cyclic voltammetry, anodic stripping analysis and potentiostatic measurements showed that antimony deposited favorably and the reaction run under limiting control. Analysis of chronoamperometric curves suggested instantaneous nucleation of the solid phase in the chloride bath, but progressive model was more probable in the presence of sulfate ions.

Słowa kluczowe

EN

antimony; electrolysis; speciation; tin; voltammetry

• Wydawca: Institute of Metallurgy and Materials Science of Polish Academy of Sciences ; Committee of Materials Engineering and Metallurgy of Polish Academy of Sciences
• Czasopismo: Archives of Metallurgy and Materials
• Rocznik: 2018
• Tom: Vol. 63, iss. 2
• Strony: 709--717
• Opis fizyczny: Bibliogr. 26 poz., rys., tab., wzory

Twórcy

autor

Rudnik E.

• AGH University of Science and Technology, Faculty of Non–Ferrous Metals, Department of Physical Chemistry and Metallurgy of Non-Ferrous Metals, Al. Mickiewicza 30, 30-059 Kraków, Poland

autor

Kostępski M.

• AGH University of Science and Technology, Faculty of Non–Ferrous Metals, Department of Physical Chemistry and Metallurgy of Non-Ferrous Metals, Al. Mickiewicza 30, 30-059 Kraków, Poland

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Uwagi

EN

1. This work was realized under AGH-UST research project No. 11.11.180.654.

PL

2. Opracowanie rekordu w ramach umowy 509/P-DUN/2018 ze środków MNiSW przeznaczonych na działalność upowszechniającą naukę (2018).