Tytuł artykułu
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Warianty tytułu
Języki publikacji
Abstrakty
Resistance to permeation of noxious chemical substances should be accompanied by resistance to mechanical factors because the glove material may be torn, cut or punctured in the workplace. This study reports on glove materials, protecting against mineral oils and mechanical hazards, made of carboxylated acrylonitrile–butadiene rubber (XNBR) latex. The obtained materials were characterized by a very high resistance of the produced materials to oil permeation (breakthrough time > 480 min). The mechanical properties, and especially tear resistance, of the studied materials were improved after the addition of modified bentonite (nanofiller) to the XNBR latex mixture. The nanocomposite meets the requirements in terms of parameters characterizing tear, abrasion, cut and puncture resistance. Therefore, the developed material may be used for the production of multifunctional protective gloves.
Wydawca
Rocznik
Tom
Strony
350--359
Opis fizyczny
Bibliogr. 29 poz., rys., tab.
Twórcy
autor
- Central Institute for Labour Protection - National Research Institute (CIOP-PIB), Poland
autor
- Technical University of Łódź, Poland
autor
- Secura B.C. Ltd, Poland
autor
- Secura B.C. Ltd, Poland
autor
- Rzeszow University of Technology, Poland
Bibliografia
- 1. European Committee for Standardization (CEN). Protective gloves against chemicals and micro-organisms - part 1 - terminology and performance requirements (Standard No. EN 374-1:2003). Brussels: CEN; 2003.
- 2. European Committee for Standardization (CEN). Protective gloves against mechanical risks (Standard No. EN 388:2003). Brussels: CEN; 2003.
- 3. Man VL, Bastecki V, Vandel G, et al. Permeation of protective clothing materials: comparison of liquid contact, liquid splashes and vapors on breakthrough times. Am Ind Hyg Assoc J. 1987;48:551-555.
- 4. Xu W, Que Hee SS. Permeation of a straight oil metalworking fluid through a disposable and chemically protective nitryle glove. J Hazard Mater. 2006;137:709-715.
- 5. Xu W, Que Hee SS. Permeation of a straight oil metalworking fluid through a disposable nitrile, chloroprene, vinyl, and latexgloves. J Hazard Mater. 2007;147:923-929.
- 6. Kmiotek M, Rzymski WM. Mieszaniny karboksylowanego kauczuku butadienowo-akrylonitrylowego i maleinowanego kopolimeru etylenu - sieciowanie i wybrane właściwości [Mixtures of carboxylated acrylonitrile-butadiene rubber and copolymer of ethylene maleic - curing and selected properties]. Elastomery. 2007;11(6):7-14.
- 7. Janowska G, Kucharska-Jastrząbek A, Rzymski WM, et al. Thermal properties and combustibility of cross-linked XNBR/CSM blends. Part II. Influence of the CSM kind. J Therm Anal Calorim. 2012;109:1481–1486.
- 8. Szczechura BJ, Austin HW, Durney Cronin R.L. Latex gloves with improved donnability. Patent EP 0486183. 2007 Dec 7.
- 9. Teoh SC, Turner CR, Chen SF. Elastomeric gloves. Patent EP 1128776. 2009 Apr 24.
- 10. Suddaby KG. Crosslinking of diene-type polymers. UK Patent GB2455409 (A). 2009 June 10.
- 11. Janowska G, Kucharska-Jastrząbek A, Rzymski WM, et al. Thermal properties and combustibility of cross-linked XNBR/CSM blends. Part I. Influence of the magnesium oxide. J Therm Anal Calorim. 2011;104:1107–1115.
- 12. Mirzaei Aliabadi M, Naderi G, Shahtaheri SJ, et al. Transport properties of carboxylated nitryle butadiene rubber (XNBR)-nanoclay composites; a promising material for protective gloves in occupational exposures. J Environ Health Sci Eng. 2014;12:51-8.
- 13. Coran AY. Chemistry of the vulcanization and protection of elastomers: a review of the achievements. J Appl Polymer Sci. 2003;87:24–30.
- 14. Heneczkowski M, Groszek G, Oleksy M, et al. Tiksotropowa kompozycja nienasyconej żywicy poliestrowej i sposób wytwarzania tiksotropowej kompozycji nienasyconej żywicy poliestrowej [Thixotropic unsaturated polyester resin composition of improved stability and method of obtaining same]. Polish Patent 178900. 2000 Jun. 30.
- 15. Heneczkowski M, Groszek G, Oleksy M, et al. Kompozycja nienasyconej żywicy poliestrowej i sposób wytwarzania kompozycji nienasyconej żywicy poliestrowej [Unsaturated polyester resin composition of improved stability and method of obtaining same]. Polish Patent 178866. 2000 Jun 30.
- 16. Irzmańska E, Dyńska-Kukulska K. Permeation of mineral oils through protective glove materials in view of literature data and authors’ own studiem. Rev Anal Chem. 2012;31:113-122.
- 17. European Committee for Standardization (CEN). Water quality - determination of hydrocarbon oil index – part 2: method using solvent extraction and gas chromatography (ISO 9377-2:2000) (Standard No. EN ISO 9377-2:2000). Brussels: CEN; 2000.
- 18. Krzemińska S, Rzymski WM. Barrier properties of hydrogenated acrylonitrile-butadiene rubber composites containing modified layered aluminosilicates. Mater Sci-Poland. 2011;29(4):285–291.
- 19. Mooney MJ. A theory of large elastic deformation. J Appl Phys. 1940;11:582–592.
- 20. Rivlin RS. Torsion of rubber cylinder. J. Appl. Phys. 1947;18:444-449.
- 21. Xu W, Que Hee SS. Swelling of four glove materials challenged by six metalworking fluids. Arch Environ Contam Toxicol. 2008;54:1-8.
- 22. Krzemińska S, Rzymski WM. Thermodynamic affinity of elastomer–solvent system and barrier properties of elastomer materials. Acta Phys Pol A. 2013;124(1):146–150.
- 23. Krzemińska S, Rzymski WM. Wpływ glinokrzemianów warstwowych na właściwości barierowe kauczuku butylowego [Effect of layered aluminosilicates on barrier properties of butyl rubber]. Polimery. 2012;57(7–8):551–557.
- 24. Patterson AL. The Scherrer formula for X-ray particle size determination. Phys Rev. 1939;56:978–982.
- 25. Gołębiewski J, Różański A, Gałęski A. Badanie procesu wytwarzania nanokompozytu polipropylenu z montmorylonitem [Study on the process of preparation of polypropylene nanocomposite with montmorillonite]. Polimery. 2006;51(5):374–381.
- 26. Oleksy M, Oliwa R, Heneczkowski M, et al. Kompozyty żywicy epoksydowej z modyfikowanymi bentonitami dla potrzeb przemysłu lotniczego [The composites of epoxy resin modified with bentonites for the aircraft industry]. Polimery. 2012;57(3):228–235.
- 27. Aina ZN, Azura AR. Effect of different types of filler and filler loadings on the properties of carboxylated acrylonitrile-butadiene rubber latex films. J Appl Polymer Sci. 2011;119:2815-2823.
- 28. George SC, Knōrgen M., Thomas S. Effect of nature and extent of crosslinking on swelling and mechanical behaviour of styrene-butadiene rubber membranes. J Membrane Sci. 1999;163:1–17.
- 29. Krzemińska S., Irzmańska E., Rzymski W.M, et al. Kompozycja elastomerowa do wytwarzania wyrobów cienkościennych metodą maczania [The elastomer composition for the manufacture of thin-walled products by dipping]. Polish Patent 219209. 2014 Aug 25.
Uwagi
PL
Opracowanie ze środków MNiSW w ramach umowy 812/P-DUN/2016 na działalność upowszechniającą naukę.
Typ dokumentu
Bibliografia
Identyfikator YADDA
bwmeta1.element.baztech-3e6bce60-7c50-483e-9c3b-216bc47400dc
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