Determination of Aldehydes in Wet Deposition

• Autorzy: Czaplicka M. , Jaworek K. , Wochnik A.

Identyfikatory

DOI

10.2478/aep-2014-0011

Warianty tytułu

PL

Oznaczanie aldehydów w depozycji mokrej

• Języki publikacji: EN

Abstrakty

EN

The paper presents two sample preparation procedures for the determination of aldehydes in wet deposition. In both cases the 2,4-dinitrophenylhydrazine derivatization and solid phase extraction were applied. The derivatization in method A was applied before the extraction, the extraction in method B was carried out with simultaneous derivatisation. Accuracy of both methods was evaluated on the basis of the analysis of aqueous solutions of selected carbonyl compounds. Both methods were characterized by good recovery, however, due to the precision of the method expressed as RSD for testing of environmental samples the method B was used. The analysis of environmental samples showed significant differences in the concentrations of aldehydes in wet deposition, depending on the location of the sampling point. In the case of samples taken from agricultural areas the predominant aldehydes were formaldehyde and acetaldehyde. Formaldehyde was from 31% to 47% of the determined compounds. While in samples collected near a traffic source, in the deposition acrolein was determined at the levels from 62% to 64% of the identified compounds.

PL

W pracy przedstawiono dwie procedury przygotowania próbek mokrej depozycji do oznaczeń aldehydów. W obydwóch przypadkach zastosowano derywatyzację 2,4-dinitrofenylohydrazyną oraz ekstrakcję do fazy stałej. W metodzie A derywatyzacja poprzedzała ekstrakcję, w metodzie B ekstrakcję prowadzono z równoczesną derywatyzacją. Na podstawie analiz wodnych roztworów wybranych związków karbonylowych oceniono precyzję obydwóch metod. Ze względu na odzysk oraz wartość względnego odchylenia do analiz próbek środowiskowych pobranych z obszarów silnie uprzemysłowionych i rolniczych wybrano metodę B. Analiza próbek środowiskowych wykazała znaczne zróżnicowanie stężeń aldehydów w mokrej depozycji w zależności od lokalizacji punktu pobierania próbek. W przypadku próbek pobranych z obszarów rolniczych dominującymi aldehydami były formaldehyd i acetaldehyd. Formaldehyd stanowił od 31% do 47% oznaczonych związków. Podczas gdy w próbkach pobranych w pobliżu źródeł komunikacyjnych w depozycji stwierdzono udział akroleiny w oznaczonych aldehydach na poziomie od 62% do 64% oznaczonych związków.

Słowa kluczowe

EN

aldehydes; wet deposition; derivatization; SPE; solid-phase extraction; HPLC; high performance liquid chromatography

PL

aldehydy; mokra depozycja; derywatyzacja; SPE; ekstrakcja w fazie stałej; HPLC; wysokosprawna chromatografia cieczowa

• Wydawca: Institute of Environmental Engineering, Polish Academy of Sciences
• Czasopismo: Archives of Environmental Protection
• Rocznik: 2014
• Tom: Vol. 40, no. 2
• Strony: 21--31
• Opis fizyczny: Bibliogr. 26 poz., tab., wykr.

Twórcy

autor

Czaplicka M.

• Institute of Non-Ferrous Metals Sowinskiego 5, 44-100 Gliwice, Poland
• Department of Analytical Chemistry, Faculty of Chemistry Silesian University of Technology Strzody 7M, 44-100 Gliwice, Poland

autor

Jaworek K.

• Institute of Non-Ferrous Metals Sowinskiego 5, 44-100 Gliwice, Poland

autor

Wochnik A.

• Department of Analytical Chemistry, Faculty of Chemistry Silesian University of Technology Strzody 7M, 44-100 Gliwice, Poland

Bibliografia

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