Characterization and components separation of corn stover by alkali and hydrogen peroxide treatments

• Autorzy: Cong L. , Li Z. , Guanqun Z. , Jianguo X. , Long .

Identyfikatory

DOI

10.1515/pjct-2015-0035

• Języki publikacji: EN

Abstrakty

EN

The dissolution of corn stover in alkaline solvent system composed of NaOH-H2O2 was reported and the separation of its ingredients combined with acid precipitation, ethanol extraction was proposed. It is proven that the residual after alkali solvent was cellulose, the filtrate by the acid precipitation of the liquor was lignin, the solid by the ethanol extraction of the liquor was hemicellulose. The optimum dissolution conditions were determined by single-factor experiment as follows: the concentration of H2O2 5.0%, pH 11.5, dissolution temperature 60°C, dissolution time 3.0 h, the ratio of liquid to solid 30 mL/g. And chemical analysis were employed to determine the purity of the components separated. The structure of the components separated were identifi ed by FT-IR, SEM, XRD and NMR. The cellulose recovery yield can achieve to 84.2% and lignin recovery yield is 86.6%, the hemicellulose recovery yield is 96.7%. After recycling the solvent 3 times, the recovery yield of cellulose, lignin and hemicellulose were 82.7, 87.6 and 97.4%, and the purity of cellulose, lignin and hemicellulose were 98.0, 96.5 and 98.7%, respectively.

Słowa kluczowe

EN

Corn stover; lignin; hemicellulose; cellulose; Component separation; NaOH-H2O2

• Wydawca: West Pomeranian University of Technology. Publishing House
• Czasopismo: Polish Journal of Chemical Technology
• Rocznik: 2015
• Tom: Vol. 17, nr 2
• Strony: 89--95
• Opis fizyczny: Bibliogr. 23 poz., rys.

Twórcy

autor

Cong L.

• Changchun University of Technology, Jilin Provincial Engineering Laboratory for the Complex Utilization of Petroresources and Biomass, Changchun, 130012. P. R. China

autor

Li Z.

• Changchun University of Technology, Jilin Provincial Engineering Laboratory for the Complex Utilization of Petroresources and Biomass, Changchun, 130012. P. R. China

autor

Guanqun Z.

• Changchun University of Technology, Jilin Provincial Engineering Laboratory for the Complex Utilization of Petroresources and Biomass, Changchun, 130012. P. R. China

autor

Jianguo X.

• Changchun University of Technology, Jilin Provincial Engineering Laboratory for the Complex Utilization of Petroresources and Biomass, Changchun, 130012. P. R. China

autor

Long .

• Changchun University of Technology, Jilin Provincial Engineering Laboratory for the Complex Utilization of Petroresources and Biomass, Changchun, 130012. P. R. China

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