Improvement of the corrosion behaviour of mild steel by deposition of Zn–Ni–Cu–Fe–Cd from an acetate sulphate bath

• Autorzy: Evecen Meryem , Alfalah Mothana Ghazi , Saracoglu Murat , Kandemirli Fatma

Identyfikatory

DOI

10.15199/40.2025.2.2

Warianty tytułu

PL

Poprawa właściwości antykorozyjnych stali miękkiej dzięki powłoce stopu Zn−Ni−Cu−Fe−Cd osadzanej w kąpieli octanowo-siarczanowej

• Języki publikacji: EN

Abstrakty

EN

Zn–Ni–Cu–Fe–Cd quinary alloy was successfully electrodeposited on mild steel from acetate-sulphate baths with only cathodic potential applied during linear sweep voltammetry. The influence of scan rate (1 mV/s, 5 mV/s and 10 mV/s) as well as the effect of organic additives: 4-(4-nitrophenyl)-3-thiosemicarbazide or 4-(3-methoxyphenyl)-3-thiosemicarbazide, on the surface appearance and deposit composition were investigated. Three electrochemical techniques, potentiodynamic polarisation (PDP), linear polarisation resistance (LPR) and electrochemical impedance spectroscopy (EIS) were used to investigate the corrosion behaviour of the alloy composition after immersion in a solution containing 1 M HCl. Energy dispersive X-ray (EDX) and scanning electron microscopy (SEM) were carried out after deposition to provide a visual aspect of the coating. The lowest corrosion current density, the highest corrosion resistance, and the highest impedance were observed in each alloy system at a scan rate of 1 mV/s. These values were: 67 μA/cm−2, 51 μA/cm−2, and 7.6 μA/cm−2 for PDP, 965 Ω · cm², 1117 Ω · cm², and 2853 Ω · cm² for LPR, and 1602 Ω · cm², 12938 Ω · cm², and 1595 Ω · cm² for EIS, corresponding to coatings without additives, coatings with the additive 4-(4-nitrophenyl)-3-thiosemicarbazide, and coatings with the additive 4-(3-methoxyphenyl)-3-thiosemicarbazide, respectively. From the SEM and EDX results it was concluded that 4-(3-methoxyphenyl)-3-thiosemicarbazide has a more pronounced effect on the coating than 4-(4-nitrophenyl)-3-thiosemicarbazide, probably due to its better adsorption on the surface of soft steel.

PL

Pięcioskładnikowy stop Zn–Ni–Cu–Fe–Cd został osadzony elektrolitycznie na stali miękkiej w kąpieli octanowo-siarczanowej z zastosowaniem tylko potencjału katodowego w woltamperometrii liniowej. Zbadano wpływ szybkości skanowania (1 mV/s, 5 mV/s, 10 mV/s), a także wpływ dodatków organicznych: 4-(4-nitrofenylo)-3-tiosemikarbazyd lub 4-(3-metoksyfenylo)-3-tiosemikarbazyd, na wygląd powierzchni i skład osadzanej powłoki. Do zbadania zachowania korozyjnego stopu po zanurzeniu w roztworze zawierającym 1 M HCl wykorzystano trzy techniki elektrochemiczne: polaryzację potencjodynamiczną (PDP), polaryzację liniową (LPR) i elektrochemiczną spektroskopię impedancyjną (EIS). Po osadzeniu przeprowadzono analizę za pomocą spektroskopii rentgenowskiej z dyspersją energii (EDX) i skaningowej mikroskopii elektronowej (SEM), aby wizualnie ocenić powłoki. Najniższą gęstość prądu korozyjnego, najwyższą odporność na korozję i najwyższą impedancję zaobserwowano w każdym układzie stopowym przy szybkości skanowania wynoszącej 1 mV/s. Wartości te wynosiły odpowiednio: 67 μA/cm−2, 51 μA/cm−2 i 7,6 μA/cm−2 dla PDP, 965 Ω · cm2, 1117 Ω · cm2 i 2853 Ω · cm2 dla LPR oraz 1602 Ω · cm2, 12 938 Ω · cm2 i 1595 Ω · cm2 dla EIS, co odpowiadało kolejno: powłokom bez dodatków, powłokom z dodatkiem 4-(4-nitrofenylo)-3-tiosemikarbazydu i powłokom z dodatkiem 4-(3-metoksyfenylo)-3-tiosemikarbazydu. Na podstawie wyników badań SEM i EDX stwierdzono, że 4-(3-metoksyfenylo)-3-tiosemikarbazyd ma większy wpływ na powłokę niż 4-(4-nitrofenylo)-3-tiosemikarbazyd, prawdopodobnie ze względu na jego lepszą adsorpcję na powierzchni miękkiej stali.

Słowa kluczowe

EN

quinary alloy Zn–Ni–Cu–Fe–Cd; electrodeposition; organic additives; EIS; SEM; scan rate

PL

pięcioskładnikowy stop Zn–Ni–Cu–Fe–Cd; elektroosadzanie; dodatki organiczne; EIS; SEM; szybkość skanowania

• Wydawca: Wydawnictwo SIGMA-NOT
• Czasopismo: Ochrona przed Korozją
• Rocznik: 2025
• Tom: nr 2
• Strony: 41--47
• Opis fizyczny: Bibliogr. 25 poz., fot., tab., wykr.

Twórcy

autor

Evecen Meryem

• Department of Physics, Faculty of Arts and Sciences, Amasya University, Amasya, Turkey

• https://orcid.org/0000-0001-7926-1323

autor

Alfalah Mothana Ghazi

• Metallurgy and Materials Engineering, Faculty of Engineering and Architecture, Kastamonu University, Kastamonu, Turkey
• Materials of Engineering Department, College of Engineering, University of Al-Qadissyah, Iraq

• https://orcid.org/0000-0002-8970-712X

autor

Saracoglu Murat

• Faculty of Education, Erciyes University, Kayseri, Turkey

• https://orcid.org/0000-0003-4027-9643

autor

Kandemirli Fatma

• Biomedical Engineering Department, Faculty of Engineering and Architecture, Kastamonu University, Kastamonu, Turkey

• https://orcid.org/0000-0001-6097-2184

Bibliografia

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