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Pomace from apples, grapes, blackcurrants, and oranges is a waste product of fruit processing, which is formed during the production of juices. Pomace is a rich source of biologically active compounds such as polyphenols, carotenoids, or vitamins. They also contain pectin, cellulose, lignin, proteins, and minerals. All these components, apart from having many beneficial properties for human health, also show sorption properties towards heavy metal ions. Therefore, this study aimed to evaluate the possibility of removing lead (II) and cadmium (II) ions from aqueous solutions by adding apple, grape, black currant, and orange pomace as well as to determine the adsorption efficiency of selected heavy metals. The studies were carried out in model systems. The results of the research showed that lead (II) and cadmium (II) ions are adsorbed on fruit pomace. The highest removal of cadmium (II) ions was observed in orange pomace and of lead (II) ions in apple pomace. The maximum tested cadmium ions absorption capacity was: 0.117235 mg/g in the case of freeze-dried apple pomace; 0.08618 mg/g in the case of freeze-dried currant pomace; 0.21915 m/g in the case of freeze-dried grape pomace and 0.29549 mg/g in the case of freeze-dried orange pomace. On the other hand, the maximum absorption of lead ions was: 0.457 mg/g in the case of freeze-dried apple pomace; 0.442 mg/g in the case of freeze-dried currant pomace; 0.3445 mg/g in the case of freeze-dried grape pomace and 0.421 mg/g in the case of freeze-dried orange pomace. On the basis of the performed measurements, it can be concluded that the tested waste can potentially be used as a cheap biosorbent for removing heavy metal ions from dilute aqueous solutions.
Słowa kluczowe
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Tom
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169--177
Opis fizyczny
Bibliogr. 29 poz., rys., tab.
Twórcy
autor
- Białystok University of Technology, Faculty of Civil Engineering and Environmental Sciences, Department of Agri-Food Engineering and Environmental Management, ul. Wiejska 45A, 15-351 Białystok, Poland
- Białystok University of Technology, Faculty of Civil Engineering and Environmental Sciences, Department of Agri-Food Engineering and Environmental Management, ul. Wiejska 45A, 15-351 Białystok, Poland
autor
- Białystok University of Technology, Faculty of Civil Engineering and Environmental Sciences, Department of Technology in Environmental Engineering, ul. Wiejska 45A, 15-351 Białystok, Poland
autor
- Białystok University of Technology, Faculty of Civil Engineering and Environmental Sciences, Department of Agri-Food Engineering and Environmental Management, ul. Wiejska 45A, 15-351 Białystok, Poland
Bibliografia
- 1. Anwar J., Shafique U., Waheed-uz-Zaman Dar A., Anw Sheibani S. 2010. Removal of Pb (II) and Cd (II) from water by adsorption on peels of banana. Bioresource Technology, 101, 1752–1755.
- 2. Aziz N., Jayasuriya N., Fan L. 2016. Adsorption study on Moringa oleifera seeds and Musa cavendish as natural water purification agents for removal of Lead, Nickel, and Cadmium from drinking water. Materials Science and Engineering, 136, 1–9.
- 3. Chakraborty, R., Saha, A.K., Bhattacharya, P. 2006. Modeling and simulation of parametric sensivity in primary freeze-drying of foodstuffs. Separation and Purification Technology, 49, 258-263.
- 4. Chen X., Tian Z., Cheng H., Xu G., Zhou H. 2021. Adsorption process and mechanism of heavy metal ions by different components of cells, using yeast (Pichia pastoris) and Cu2+ as biosorption models. RSC Advances, 11, 17080-17091.
- 5. Ciurzyńska A., Lenart A., Kawka P. 2013. Influence of freeze-drying temperature and drying methods on selected properties of dried pumpkin. Acta Agrophysica, 20(1), 39-51.
- 6. Dixit R., Malaviya D., Pandiyan K., Singh U.B., Sahu A., Shukla R., Singh B.P., Rai J.P., Sharma P.K., Lade H. 2015. Bioremediation of heavy metals from soil and aquatic environment: An overview of principles and criteria of fundamental processes. Sustainability, 7(2), 2189–2212.
- 7. Farinella N.V., Matos G.D., Lehmann E.L., Arruda M.A. 2008. Grape bagasse as an alternative natural adsorbent of cadmium and lead for effluent treatment. Journal of Hazardous Materials, 154(1-3), 1007–1012.
- 8. Hegazy, I., Ali, M.E.A., Zaghlool, E.H. 2021. Heavy metals adsorption from contaminated water using moringa seeds/olive pomace byproducts. Applied Water Science, 95(11), 9.
- 9. Ince M., Ince O.K. 2017. An overview of adsorption technique for heavy metal removal from water/wastewater: a critical review. International Journal of Applied and Pure Science and Agriculture, 3(2), 10–19.
- 10. Iqbal M., Saeed A., Zafar S.I . 2009. FTIR spectrophotometry, kinetics and adsorption isotherms modeling, ion exchange, and EDX analysis for understanding the mechanism of Cd2+ and Pb2+ removal by mango peel waste. Journal of Hazardous Materials, 164, 161–171.
- 11. Janiszewska E., Witrowa-Rajchert D., Kidon M., Czapski J. 2013. Effect of the applied drying method on the physical properties of purple carrot pomace, International Agrophysics, 27(2), 143-14.
- 12. Kalak T., Dudczak-Hałabuda J., Tachibana Y., Cierpiszewski R. 2020. Effective use of elderberry (Sambucus nigra) pomace in biosorption processes of Fe(III) ions. Chemosphere, 246, 125744.
- 13. Krol S., Nawirska A. 2003. Co-removal of metal ions with pomace in a dynamic system. Acta Scientiarum Polonorum. Technologia Alimentaria, (1), 21-29. (in Polish)
- 14. Nawirska A., Oszmiański J. 2001. Binding of metal ions by selected fractions of substances contained in fruit pomace. Food, 4(29), 66-77. (in Polish)
- 15. Olesinska K., Wilczynski K., Kalwa K. 2018. The effective method of preservation on selected bioactive compounds and antioxidant activity in blackthorn fruits (Prunus spinosa L.), Agronomy Science, 73(3), 46-54.
- 16. Patel S. 2012. Potential of fruit and vegetable wastes as novel biosorbents: Summarizing the recent studies. Reviews in Environmental Science and Bio/Technology, 11, 365-380.
- 17. Pavan F.A., Mazzocato A.C., Jacques R.A., Dias S.L.P. 2008. Ponkan peel: a potential biosorbent for removal of Pb (II)ions from aqueous solution. Biochemical Engineering Journal, 40(2), 357–362.
- 18. Ring T. 1996. Fundamentals of Ceramic Powder Processing and Synthesis. Academic Press, London.
- 19. Šćiban M., Radetić B., Kevrešan Ž., Klašnja M. 2007. Adsorption of heavy metals from electroplating wastewater by wood sawdust, Bioresource Technology, 98(1), 402-409.
- 20. Sheibani A., Shishehbor M.R., Alaei H. 2012. Removal of Fe(III) ions from aqueous solution by hazelnut hull as an adsorbent. Int J Chemistry & Industry 3, 1–4.
- 21. Shishehgarha, F., Makhlouf, J., Ratti, C. 2002. Freeze-drying characteristics of strawberries, Drying Technology, 20, 131-145.
- 22. Skoczko, I.; Szatyłowicz, E. 2018. Removal of heavy metal ions by filtration on the activated alumina-assisted magnetic field. Desalination and Water Treatment, 117, 345–352.
- 23. Sprynskyy M., Buszewski B., Terzyk P. A., Namieśnik J. 2006. Study of the selection mechanism of heavy metal (Pb2+, Cu2+, Ni2+, and Cd2+) adsorption on clinoptilolite, Journal of Colloid and Interface Science, 304(1), 21-28.
- 24. Sulyman M., Namiesnik J., Gierak A. 2017. Low-cost adsorbents derived from agricultural by-products/wastes for enhancing contaminant uptakes from wastewater: a review. Polish Journal of Environmental Studies, 26(2), 479–510.
- 25. Szatyłowicz, E.; Skoczko, I. 2019). Magnetic Field Usage Supported Filtration Through Different Filter Materials. Water, 11(8), 1584.
- 26. Thermo Scientific’s AAS iCE 3500 User Manual 2013. Spectro-Lab: Warsaw, Poland.
- 27. Tomczak E., Szczerkowska D. 2010. Sorption from multicomponent solutions on freeze dried chitosan. Ecological Chemistry and Engineering A, 17(2-3), 313-322.
- 28. Uzunkavak O. Patterer M. S., Medici F., Özdemir G. 2019. Modeling of single and binary adsorption of lead and cadmium ions onto modified olive pomace, Desalination and Water Treatment, 162, 278-289.
- 29. Volesky B. 2001. Detoxification of metal-bearing effluents: biosorption for the next century. Hydrometallurgy, 59(2–3), 203–216.
Uwagi
Opracowanie rekordu ze środków MEiN, umowa nr SONP/SP/546092/2022 w ramach programu "Społeczna odpowiedzialność nauki" - moduł: Popularyzacja nauki i promocja sportu (2022-2023).
Typ dokumentu
Bibliografia
Identyfikator YADDA
bwmeta1.element.baztech-3d2226b4-a122-434f-904e-c9b264282a10