Synthesis and characterization of methacrylamide- -based molecularly imprinted polymers for detection of di(2-ethylhexyl) phthalate

• Autorzy: Fauziah St , Soekamto Nunuk Hariani , Paulina Taba , Hustim Muralia , Achman Annisyah Aprilia , Andekan Nital , Husain Husnia Paraditha , Sapar Ajuk

Identyfikatory

DOI

10.14314/polimery.2025.6.3

Warianty tytułu

PL

Synteza i charakterystyka polimerów na bazie metakryloamidu z nadrukiem molekularnym do wykrywania ftalanu di(2-etyloheksylu)

• Języki publikacji: EN

Abstrakty

EN

Based on methacrylamide (MAM) and trimethylolpropane trimethacrylate (TRIM) as a cross-linking agent, molecularly imprinted polymers (MIPs) were obtained by precipitation polymerization and used for the detection of di(2-ethylhexyl)phthalate (DEHP) in drinking water in plastic packaging. The presence of functional groups –NH, –CH, –C=O, –C=C and –CO was confirmed by FT-IR. The formation of MIP_DEHP was also confirmed by EDS. Moreover, SAA analysis showed their mesoporous structure. The adsorption capacity was consistent with the isothermal Freundlich adsorption model, and the adsorption kinetics models with a pseudo-second-order reaction. Small, uniform, porous grains were observed in the MIP structure (SEM).

PL

Na bazie metakryloamidu (MAM) i trimetakrylanu trimetylopropanu (TRIM) jako środka sieciującego, metodą polimeryzacji strąceniowej, otrzymano polimery z nadrukiem molekularnym (MIP), które użyto do wykrywania di(2-etyloheksylo)ftalanu (DEHP) w wodzie pitnej w opakowaniach plastikowych. Obecność grup funkcyjnych –NH, –CH, –C=O, –C=C i –CO potwierdzono metodą FT-IR. Powstawanie MIP_DEHP potwierdzono również metodą EDS. Ponadto analiza SAA wykazała ich mezoporowatą strukturę. Pojemność adsorpcyjna była zgodna z izotermicznym modelem adsorpcji Freundlicha, a modele kinetyki adsorpcji z reakcją pseudodrugiego rzędu. W strukturze MIP zaobserwowano małe, jednolite, porowate ziarna (SEM).

Słowa kluczowe

EN

polymer; phthalates; DEHP; methacrylamide; TRIM

PL

polimer; ftalany; DEHP; metakryloamid; TRIM

• Wydawca: Sieć Badawcza Łukasiewicz – Instytut Chemii Przemysłowej
• Czasopismo: Polimery
• Rocznik: 2025
• Tom: Vol. 70, nr 6
• Strony: 386--393
• Opis fizyczny: Bibliogr. 23 poz., rys., tab., wykr.

Twórcy

autor

Fauziah St

• Department of Chemistry, Faculty of Mathematics and Natural Sciences, University of Hasanuddin, Makassar, 90245 Indonesia

• https://orcid.org/0000-0002-0599-4011

autor

Soekamto Nunuk Hariani

• Department of Chemistry, Faculty of Mathematics and Natural Sciences, University of Hasanuddin, Makassar, 90245 Indonesia

• https://orcid.org/0000-0001-8281-1752

autor

Paulina Taba

• Department of Chemistry, Faculty of Mathematics and Natural Sciences, University of Hasanuddin, Makassar, 90245 Indonesia

autor

Hustim Muralia

• Department of Environmental Engineering, Faculty of Engineering, University of Hasanuddin, Makassar, 90245 Indonesia

• https://orcid.org/0000-0001-8323-1549

autor

Achman Annisyah Aprilia

• Department of Chemistry, Faculty of Mathematics and Natural Sciences, University of Hasanuddin, Makassar, 90245 Indonesia

• https://orcid.org/0009-0008-2915-4800

autor

Andekan Nital

• Department of Chemistry, Faculty of Mathematics and Natural Sciences, University of Hasanuddin, Makassar, 90245 Indonesia

• https://orcid.org/0009-0005-4425-5966

autor

Husain Husnia Paraditha

• Department of Chemistry, Faculty of Mathematics and Natural Sciences, University of Hasanuddin, Makassar, 90245 Indonesia

• https://orcid.org/0009-0001-1716-5886

autor

Sapar Ajuk

• Department of Chemistry, Faculty of Mathematics and Natural Sciences, University of Tanjungpura, Pontianak, 78124 Indonesia

• https://orcid.org/0000-0002-7278-6159

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