Determination of volatile organochalcogens using liquid phase microextraction and gas chromatography with fluorine-induced chemiluminescence detection

• Autorzy: Hashemi M. , Montes R. A. , Chasteen T. G.
• Języki publikacji: EN

Abstrakty

EN

In this study, a simple and rapid liquid phase microextraction technique coupled with gas chromatography and fluorineinduced chemiluminescence detection has been developed for determination of volatile organochalcogens (dimethyl sulfide, dimethyl disulfide, dimethyl trisulfide and dimethyl diselenide and dimethyl telluride). The effects of extraction parameters such as extracting solvent and its volume, stirring time extraction time and salt effect were optimized. Also, analytical figures of merit such as response linearity, repeatability and reproducibility, and limits of detection have been evaluated. The proposed method was found to be a simple and rapid analytical procedure for determination of volatile organochalcogens in real aqueous samples with detection limits of 5-620ng·l-1. The relative recoveries of these analytes for spiked bacterial cultures, tap water and lake water ranged from 95 to 105% with the relative standard deviations of 0.3-11.0%.

Słowa kluczowe

EN

bacterial culture; fluorine-induced chemiluminescence; gas chromatography; microextraction; volatile organochalcogens

PL

hodowla bakterii; chemiluminescencja indukowana fluorem; chromatografia gazowa; mikroekstrakcja; lotne organochalkogeny

• Wydawca: University of Warmia and Mazury in Olsztyn, Poland
• Czasopismo: Environmental Biotechnology
• Rocznik: 2012
• Tom: Vol. 8, No. 2
• Strony: 55--62
• Opis fizyczny: Bibliogr. 35 poz., rys., tab., wykr.

Twórcy

autor

Hashemi M.

• Department of Analytical Chemistry, Faculty of Chemistry, Bu-Ali Sina University, Hamedan, Iran; Tel. [phone], Fax [phone]
• Department of Chemistry, Sam Houston State University, Huntsville, Texas 77340, U.S.A.

autor

Montes R. A.

• Department of Chemistry, Sam Houston State University, Huntsville, Texas 77340, U.S.A.

autor

Chasteen T. G.

• Department of Chemistry, Sam Houston State University, Huntsville, Texas 77340, U.S.A.

Bibliografia

• Abalos, M., X. Prieto, J.M. Bayona. 2002. Determination of volatile alkyl sulfides in wastewater by headspace solid-phase microextraction followed by gas chromatography-mass spectrometry. Journal of Chromatography A 963: 249-257.
• Bueno, M., F. Pannier. 2009. Quantitative analysis of volatile selenium metabolites in normal urine by headspace solid phase microextraction gas chromatography-inductively coupled plasma mass spectrometry. Talanta 78: 759-763.
• Burra, R., G.A. Pradenas, R.A. Montes, C.C. Vasques, T.G. Chasteen. 2010. Production of dimethyl triselenide and dimethyl diselenenyl sulfide in the headspace of metalloidresistant bacillus species grown in the presence of selenium oxyanions. Analytical Biochemistry 369: 217-222.
• Busto, O., J. Guasch. 2002. Application of solid phase microextraction to the determination of sulfur compounds with low volatility in wines. Journal of Chromatography A 954: 211-219.
• Campillo, N., R. Peñalver, M. Hernandez-Cordoba, C. Perez-Sirvent, M.-J. Martinez-Sanchez. 2007. Comparison of two derivatizing agents for the simultaneous determination of selenite and organoselenium species by gas chromatography and atomic emission detection after preconcentration using solid-phase microextraction. Journal of Chromatography A 1165: 191-199.
• Campillo, N., R. Peñalver, I. López-García, M. Hernández-Córdoba. 2009. Headspace solid-phase microextraction for the determination of volatile organic sulphur and selenium compounds in beers, wines and spirits using gas chromatography and atomic emission detection. Journal of Chromatography A 1216: 6735-6740.
• Cao, T.H., R.A. Cooney, M.M. Woznichak, S.W. May, R.F. Browner. 2001. Speciation and identification of organoselenium metabolites in human urine using inductively coupled plasma mass spectrometry and tandem mass spectrometry. Analytical Chemistry 73: 2898-2902.
• Chasteen, T.G., R. Bentley. 2003. Biomethylation of selenium and tellurium: Microorganisms and plants. Chemical Reviews 103: 1-26.
• Chasteen, T.G., G.M. Silver, J.W. Birks, R. Fall. 1990. Fluorineinduced chemiluminescence detection of biologically methylated tellurium, selenium, and sulfur compounds. Chromatographia 30: 181-185.
• Dadfarnia, S., A.M.H. Shabani. 2010. Recent development in liquid phase microextraction for determination of trace level concentration of metals. Analytica Chimica Acta 658: 107-119.
• Dietz, C., J. Sanz Landaluze, P. Ximenez-Embun, Y. Madrid-Albarran, C. Camara. 2004. Volatile organo selenium speciation in biological matter by solid phase microextractionmoderate temperature multicapillary gas chromatography with microwave induced plasma atomic emission spectrometry detection. Analytica Chimica Acta 501: 157-167.
• Dilli, S., I. Sutikno. 1984. Analysis of selenium at the ultra-trace level by gas chromatography. Journal of Chromatography 300: 265-302.
• Elaseer, A., G. Nickless. 1994. Determination of selenium by gas chromatography-electron-capture detection using a rapid derivatization procedure. Journal of Chromatography A 664: 77-87.
• Frankenberger, W.T., S. Benson. (Eds.). 1994. Selenium in the Environment. 456p. Marcel Dekker, New York.
• Gerbersman, C., R. Lobinski, F.C. Adams. 1995. Determination of volatile sulfur compounds in water samples, beer and coffee with purge and trap gas chromatography-microwaveinduced plasma atomic emission spectrometry. Analytica Chimica Acta 316: 93-104.
• Ghasemi, E., M. Sillanpaa, N.M. Najafi. 2011. Headspace hollow fiber protected liquid-phase microextraction combined with gas chromatography-mass spectroscopy for speciation and determination of volatile organic compounds of selenium in environmental and biological samples. Journal of Chromatography A 1218: 380-386.
• Gomez-Ariza, J.L., J.A. Pozas, I. Giraldez, E. Morales. 1998. Speciation of volatile forms of selenium and inorganic selenium in sediments by gas chromatography-mass spectrometry. Journal of Chromatography A 823: 259-277.
• Haberhauer-Troyer, C., E. Rosenberg, M. Grasserbauer. 1999. Evaluation of solid-phase microextraction for sampling of volatile organic sulfur compounds in air for subsequent gas chromatographic analysis with atomic emission detection. Journal of Chromatography A 848: 305-315.
• Haygarth, P. 1994. Global importance and global cycling of selenium. In: Selenium in the Environment (ed. W.T. Frankenberger, Jr., S. Benson), pp. 1-27. Marcel Dekker, New York.
• Hunter, W.J., L.D. Kuykendall. 2004. Determination of dimethylselenide and dimethyldiselenide by gas chromatography-photoionization detection. Journal of Chromatography A 1038: 295-297.
• Kapsimali, D.C., G.A. Zachariadis. 2009. Headspace and direct immersion solid phase microextraction procedures for selenite determination in urine, saliva and milk by gas chromatography mass spectrometry. Journal of Chromatography B 877: 3210-3214.
• Kataoka, H., H.L. Lord, J. Pawliszyn. 2000. Applications of solidphase microextraction in food analysis. Journal of Chromatography A 880: 35-62.
• Meija, J., M. Montes-Bayon, D.L. Le Duc, N. Terry, J.A. Caruso. 2002. Simultaneous monitoring of volatile selenium and sulfur species from Se accumulating plant (wild type and genetically modified) by GC/MS and GC/ICPMS using solid-phase microextraction for sample introduction. Analytical Chemistry 74: 5837-5844.
• Nogueira, C.W., V.C. Borges, G. Zeni, J.B.T. Rocha. 2005. Organochalcogens effects on δ-aminolevulinate dehydratase activity from human erythrocytic cells in vitro. Toxicology 191: 169-178.
• Palit, M., D. Pardasni, A.K. Gupta, D.K. Dubey. 2005. Application of single drop microextraction for analysis of chemical warfare agents and related compounds in water by gas chromatography/mass spectrometry. Analytical Chemistry 77: 711-717.
• Pena-Pereira, F., I. Lavilla, C. Bendicho. 2010. Liquid-phase microextraction techniques within the framework of green chemistry. TrAC Trends in Analytical Chemistry 29: 617-628.
• Pinel-Raffaitin, P., C. Pecheyran, D. Amouroux. 2008. New volatile selenium and tellurium species in fermentation gases produced by composting duck manure. Atmospheric Environment 42: 7786-7794.
• Prosen, H., L. Zupancic-Kralj. 1999. Solid-phase microextraction. TrAC Trends in Analytical Chemistry 18: 272-282.
• Psillakis, E., N. Kalogerakis. 2003. Developments in liquid-phase microextraction. TrAC Trends in Analytical Chemistry 22: 565-574.
• Rezaee, M., Y. Yamini, M. Faraji. 2010. Evolution of dispersive liquid-liquid microextraction method. Journal of Chromatography A 1217: 2342-2357.
• Sambrook, J., E. Fritsch, T. Maniatis. 1989. Molecular Cloning: A Laboratory Manual, Second Edition. Cold Spring Harbor Laboratory, New York.
• Sarafraz-Yazdi, A., A. Amiri. 2010. Liquid-phase microextraction. TrAC Trends in Analytical Chemistry 29: 1-14.
• Swearingen, J.W., Jr., M.A. Araya, M.F. Plishker, C.P. Saavedra, C.C. Vásquez, T.G. Chasteen. 2004. Identification of biogenic organotellurides in Escherichia coli K-12 headspace gases using solid-phase microextraction and gas chromatography. Analytical Biochemistry 331: 106-114.
• Swearingen, J.W., Jr., D.P. Frankel, D.E. Fuentes, C.P. Saavedra, C.C. Vasquez, T.G. Chasteen. 2006. Identification of biogenic dimethyl selenodisulfide in the headspace gases above genetically-modified Escherichia coli. Analytical Biochemistry 348: 115-122.
• Van Fleet-Stalder, V., T.G. Chasteen. 1998. Using fluorineinduced chemiluminescence to detect organo-metalloids in the headspace of phototrophic bacterial cultures amended with selenium and tellurium. Journal of Photochemistry and Photobiology 43: 193-203.