Geochemistry of the carboniferous coal-bearing series and the miocene cover within the Upper Silesian Coal Basin - a case study

• Autorzy: Krzeszowska Ewa

Identyfikatory

DOI

10.24425/gsm.2023.148166

Warianty tytułu

PL

Geochemia karbonu produktywnego i miocenu Górnośląskiego Zagłębia Węglowego - studium przypadku

• Języki publikacji: EN

Abstrakty

EN

This paper presents geochemical data for 171 core samples of the Carboniferous coal-bearing series and the Miocene cove from the central part of the Upper Silesian Coal Basin. Major oxide concentrations (Al₂O₃, SiO₂, Fe₂O₃, P₂O₅, K₂O, MgO, CaO, Na₂O, K₂O, MnO, TiO_{2, and Cr2}O₃) were obtained using XRF. Trace and major elements (Mo, Cu, Pb, Zn, Ni, Co, U, Cr, V, Mn, As, Th, Sr, Cd, Sb, Bi, Ba, Ti, W, Zr, Ce, Nb, Ta, Be Sc) were analysed ICP-MS. The main goals of this study were to demonstrate the distribution, as well as the stratigraphical variability, of the selected elements and to determine whether chemostratigraphy tools could be effectively applied to analyze Carboniferous and Miocene deposits of the USCB. Geochemical studies have shown showed different geochemical features of the samples from the Carboniferous and the Miocene. The diversity is mainly expressed in the enrichment of Miocene sediments in Ca and Sr related to biogenic carbonate material. It was also stated that the concentrations of trace elements associated with the detrital fraction, such as Zn, Cr, Co, Ba, Ti, Zr, Nb, and Sc show slightly higher values in Carboniferous sediments. On the basis of the content of Ti, Zr, and Nb, as well as ratios such as Th/U, Zr/Th, Ti/Zr, and TiO₂/K₂O, units with different inputs of the terrigenous fraction can be identified in both Carboniferous and Miocene formations. The paper shows that chemostratigraphy can be used as a stratigraphic and correlation tool for the Carboniferous and the Miocene deposits of the USCB.

PL

W pracy przedstawiono dane geochemiczne dla 171 próbek skał osadowych z karbońskiej serii węglonośnej i pokrywy mioceńskiej z centralnej części Górnośląskiego Zagłębia Węglowego. Udziały głównych tlenków (Al₂O₃, SiO₂, Fe₂O₃, P₂O₅, K₂O, MgO, CaO, Na₂O, K₂O, MnO, TiO₂ i Cr₂O₃)oznaczono za pomocą XRF. Pierwiastki główne i śladowe (Mo, Cu, Pb, Zn, Ni, Co, U, Cr, V, Mn, As, Th, Sr, Cd, Sb, Bi, Ba, Ti, W, Zr, Ce, Nb, Ta, Be i Sc) analizowano przy pomocy ICP-MS. Głównym celem badań była analiza koncentracji i zmienności stratygraficznej wybranych pierwiastków głównych i śladowych, jak również ocena możliwości stosowania chemostratygrafii w analizie karbońskich i mioceńskich osadów GZW. Badania geochemiczne wykazały odmienne właściwości geochemiczne próbek z karbonu produktywnego oraz miocenu. Zróżnicowanie to wyraża się głównie wzbogaceniem osadów miocenu w Ca i Sr, związane z biogenicznym materiałem węglanowym. Stwierdzono również, że stężenia pierwiastków śladowych, związanych z frakcją detrytyczną, takich jak: Zn, Cr, Co, Ba, Ti, Zr, Nb, Sc, wykazują nieco wyższe wartości w osadach karbonu. Na podstawie koncentracji pierwiastków Ti, Zr i Nb oraz wskaźników geochemicznych Th/U, Zr/Th, Ti/Zr, TiO₂/K₂O można zidentyfikować jednostki o różnym udziale frakcji terygenicznej, zarówno w osadach karbonu i miocenu. W pracy wykazano, że chemostratygrafia może być z powodzeniem wykorzystywana jako narzędzie stratygraficzne i korelacyjne dla utworów karbonu i miocenu Górnośląskiego Zagłębia Węglowego.

Słowa kluczowe

EN

Miocene; Carboniferous; USCB; Upper Silesian Coal Basin; chemostratigraphy

PL

GZW; Górnośląskie Zagłębie Węglowe; karbon; miocen; chemostratygrafia

• Wydawca: Instytut Gospodarki Surowcami Mineralnymi i Energią PAN ; Komitet Zrównoważonej Gospodarki Surowcami Mineralnymi PAN
• Czasopismo: Gospodarka Surowcami Mineralnymi
• Rocznik: 2023
• Tom: T. 39, z. 4
• Strony: 107--122
• Opis fizyczny: Bibliogr. 38 poz., tab., wykr.

Twórcy

autor

Krzeszowska Ewa

• Silesian University of Technology, Poland

• https://orcid.org/0000-0002-6258-6890

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