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Remediation of CO2 in Boudouard’s reaction as an example of reversible chemical reaction

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EN
Abstrakty
EN
One of the fundamental elements of a scientist's work is the ability to lead observations of the phenomena that surround us and based on them making conclusions. These observations are conducted within the so-called scientific experiments. Lessons learned based on the results obtained in experiments allow researchers to better understand the essence of the phenomena occurring in the world around us. Drawing conclusions is not always easy. In order to achieve this skill, we must possess a well-established knowledge in the field of the phenomenon that interests us. The most striking example of how important skills are observation and drawing proper conclusions is the phenomenon of global climate warming. The main parameter influencing temperatures registered on Earth is the concentration of greenhouse gases in the atmosphere, and especially carbon dioxide created from combustion processes. A significant role in studies of the reduction of CO2 emissions plays chemists. To be sure that conducted by them experiments are optimally designed, it is necessary to ensure them with proper education already at the secondary school level. The main aim of this article was to conduct the study in order to explain chemical issues that create the greatest cognitive difficulties among students. The second aim of the article was to propose a chemical experiment to students that would allow them to find out more about the phenomena governing in the area of problematic issues. The proposed experiment is based on the concept of solubility equilibrium. Results of preliminary tests that have been carried out after applying this experiment on a small group of students, indicated their better understanding of the studied subject.
Rocznik
Strony
101--111
Opis fizyczny
Bibliogr. 21 poz., rys., tab.
Twórcy
  • Faculty of Chemistry, Jagiellonian University, ul. Gronostajowa 2, 30-387 Kraków, Poland, phone +48 12 686 24 54
  • Faculty of Chemistry, Jagiellonian University, ul. Gronostajowa 2, 30-387 Kraków, Poland, phone +48 12 686 24 54
  • Faculty of Chemistry, Jagiellonian University, ul. Gronostajowa 2, 30-387 Kraków, Poland, phone +48 12 686 24 54
Bibliografia
  • [1] Orwat K, Bernard P, Migdał-Mikuli A. Alternative conceptions of common salt hydrolysis among upper-secondary-school students. J Balt Sci Educ. 2017;16:64-76. Available from: http://www.scientiasocialis.lt/jbse/?q=node/547.
  • [2] Walker PL Jr, Rusinko F Jr, Austin LG. Gas reactions of carbon. Adv Catalysis. 1959;11:133-221. DOI: 10.1016/S0360-0564(08)60418-6.
  • [3] Hunt J, Ferrari A, Lita A, Crosswhite M, Ashley B, Stiegman AE. Microwave-specific enhancement of the carbon-carbon dioxide (Boudouard) reaction. J Phys Chem C. 2013;117(51):26871-80. DOI: 10.1021/jp4076965.
  • [4] Quílez-Pardo J, Solaz-Portolés JJ. Students' and teachers' misapplication of le Chatelier's principle: Implications for the teaching of chemical equilibrium. J Res Sci Teach. 1995;32(9):939-57. DOI: 10.1002/tea.3660320906.
  • [5] Wheeler AE, Kass H. Student misconceptions in chemical equilibrium. Sci Educ. 1978;62:223-32. DOI: 10.1002/sce.3730620212.
  • [6] Hackling MW, Garnett PJ. Misconceptions of chemical equilibrium. Eur J Sci Educ. 1985;7:205-14. DOI: 10.1080/0140528850070211.
  • [7] Banerjee AC. Misconceptions of students and teachers in chemical equilibrium. J Sci Educ. 1991;13:487-94. DOI: 10.1080/0950069910130411.
  • [8] Niaz M. Response to contradiction: conflict resolution strategies used by students in solving problems of chemical equilibrium. J Sci Educ Technol. 2001;10(2):205-11. DOI: 10.1023/A:1009481416943.
  • [9] Ghirardi M, Marchetti F, Pettinari C, Regis A, Roletto E. Implementing an equilibrium law teaching sequence for secondary school students to learn chemical equilibrium. J Chem Educ. 2015;92:1008-15. DOI: 10.1021/ed500658s.
  • [10] Kostić VDj, Stankov-Jovanović VP, Sekulić TM, Takači DjB. Visualization of problem solving related to the quantitative composition of solutions in the dynamic GeoGebra environment. Chem Educ Res Pract. 2016;17:120-38. DOI: 10.1039/C5RP00156K.
  • [11] Gotlib LJ. Relating equilibrium, pH, and solubility product constant: An introductory chemistry laboratory experiment. J Chem Educ. 1990;67(11):937-8. DOI: 10.1021/ed067p937.
  • [12] Mickey ChD. Chemical equilibrium. J Chem Educ. 1980;57(11):801-4. DOI: 10.1021/ed057p801.
  • [13] Tang H, Xu M, Zhou X, Zhang Y, Zhao L, Ye G, et al. Acute toxicity and biodistribution of different sized copper nano-particles in rats after oral administration. Mater Sci Eng. 2018;93:649-63. DOI: 10.1016/j.msec.2018.08.032.
  • [14] Kamble NA. Copper sulphate induced metabolic stress and biochemical composition in aquatic snail Bellamya bengalensis (l). J Chem Biol Phys Sci Sec B. 2019;9(3):447-59. DOI: 10.24214/jcbps.b.9.3.44759.
  • [15] Srikrishna V, Monteiro-Riviere NA. The effects of sodium hydroxide and hydrochloric acid on isolated perfused skin. In Vitro Toxicol. 1991;4(3):207-15. Available from: https://www.researchgate.net/profile/Nancy_Monteiro-Riviere2/publication/285022693_The_effects_of_sodium_hydroxide_and_hydrochloric_acid_on_isolated_perfused_skin/links/56b3dfe508ae1f8aa4535750/The-effects-of-sodium-hydroxide-and-hydrochloric-acid-on-isolated-perfused-skin.pdf.
  • [16] Kolios L, Striepling E, Kolios G, Dorges J, Sturmer KM, Stuermer EK, et al. The nitric acid burn trauma of the skin. J Plastic Reconstructive Aesthetic Surgery. 2010;63(4):E358-63. DOI: 10.1016/j.bjps.2009.09.001.
  • [17] Roda E, Barni S, Milzani A, Dalle-Donne I, Colombo G, Coccini T. Single silver nanoparticle instillation induced early and persisting moderate cortical damage in rat kidneys. Int J Mol Sci. 2017;18(10):2115. DOI: 10.3390/ijms18102115.
  • [18] Panyala NR, Pena-Mendez EM, Havel J. Silver or silver nanoparticles: a hazardous threat to the environment and human health? J Appl Biomed. 2008;6(3):117-29. DOI: 10.32725/jab.2008.015.
  • [19] Steinborn C, Diegel Ch, Garcia-Kaufer M, Grundemann C, Huber R. Immunomodulatory effects of metal salts at sub-toxic concentrations. J Appl Toxicol. 2017;37:563-72. DOI: 10.1002/jat.3390.
  • [20] Sousa AB, Maiorka PC, Gonçalves ID, Sá LRM, Górniak SL. Evaluation of effects of prenatal exposure to the cyanide and thiocyanate in wistar rats. Reproductive Toxicol. 2007;23(4):568-77. DOI:10.1016/j.reprotox.2007.01.003.
  • [21] Ago M, Hayashi T, Ago K, Ogata M. Two fatalities associated with chloroform inhalation. Variation of toxicological and pathological findings. Legal Medicine. 2011;13:156-60. DOI: 10.1016/j.legalmed.2011.01.002.
Typ dokumentu
Bibliografia
Identyfikator YADDA
bwmeta1.element.baztech-3b6a2cff-8345-400f-9669-ea10e4a8328a
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