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Influence of Sr2+ Dopant on Microstructure and Electric Properties of (Ba0.85Ca0.15)(Zr0.1Ti0.9)O3 (BCZT) Ceramics

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EN
Abstrakty
EN
The discovery of (BaxCa1-x)(ZryTi 1-x)O3 lead-free ceramics drawn a lot of attention to those novel materials because of their excellent piezoelectric properties. However, quite a little attention has been paid to other features of the material. This article reports a wide range of research, including composition, structure and microstructure, dielectric response and impedance spectroscopy in order to systematize and expand knowledge about this peculiar ceramics and strontium doping effect on its properties. In order to test that influence a series of samples with various strontium concentration, precisely the admixtures of 0.02, 0.04 and 0.06 mol% were prepared, as well as basic ceramics to compare obtained results.
Twórcy
  • University of Silesia, Faculty of Computer Science and Material Science, Institute of Technology and Mechatronics, 12 Żytnia Str., 41-205 Sosnowiec, Poland
autor
  • University of Silesia, Faculty of Computer Science and Material Science, Institute of Materials Science, 75 Pulku Piechoty 1a, 41-500 Chorzow, Poland
autor
  • University of Silesia, Faculty of Computer Science and Material Science, Institute of Technology and Mechatronics, 12 Żytnia Str., 41-205 Sosnowiec, Poland
  • University of Silesia, Faculty of Computer Science and Material Science, Institute of Technology and Mechatronics, 12 Żytnia Str., 41-205 Sosnowiec, Poland
autor
  • University of Silesia, Faculty of Computer Science and Material Science, Institute of Technology and Mechatronics, 12 Żytnia Str., 41-205 Sosnowiec, Poland
autor
  • University of Silesia, Faculty of Computer Science and Material Science, Institute of Technology and Mechatronics, 12 Żytnia Str., 41-205 Sosnowiec, Poland
Bibliografia
  • [1] J. Hao, W. Bai, W. Li, J. Zhai, Correlation Between the Microstructure and Electrical Properties in High-Performance (Ba0.85Ca0.15)(Zr0.1Ti0.9)O3 Lead-Free Piezoelectric Ceramics, J. Am. Ceram. Soc. 95, 1998-2006 (2012) doi:10.1111/j.1551--2916.2012.05146.x.
  • [2] J. Suchanicz, Bezołowiowe tytaniany ferroelektryczne, Uniwersytet Pedagogiczny im. Komisji Edukacji Narodowej (Kraków), Wydawnictwo Naukowe, Wydawnictwo Naukowe Uniwersytetu Pedagogicznego, Kraków, 2016.
  • [3] W. Liu, X. Ren, Large Piezoelectric Effect in Pb-Free Ceramics, Phys. Rev. Lett. 103 (2009). doi:10.1103/PhysRevLett.103.257602.
  • [4] P. Parjansri, U. Intatha, S. Eitssayeam, Dielectric, ferroelectric and piezoelectric properties of Nb5+ doped BCZT ceramics, Mater. Res. Bull. 65, 61-67 (2015). doi:10.1016/j.materresbull.2015.01.040.
  • [5] C. Han, J. Wu, C. Pu, S. Qiao, B. Wu, J. Zhu, D. Xiao, High piezoelectric coefficient of Pr2O3-doped Ba0.85Ca0.15Ti0.9Zr0.1O3i ceramics, Ceram. Int. 38, 6359-6363 (2012). doi:10.1016/j.ceramint.2012.05.008.
  • [6] Y. Cui, C. Yuan, X. Liu, X. Zhao, X. Shan, Lead-free (Ba0.85-Ca0.15)(Ti0.9Zr0.1)O3-Y2O3 ceramics with large piezoelectric coefficient obtained by low-temperature sintering, J. Mater. Sci.Mater. Electron. 24, 654-657 (2012). doi:10.1007/s10854-012--0785-7.
  • [7] D. Zhang, Y. Zhang, S. Yang, Microstructure and electrical properties of tantalum doped (Ba0.85Ca0.15)(Ti0.9Zr0.1)O3 ceramics, J. Mater. Sci. Mater. Electron. 26, 909-915 (2014). doi:10.1007/s10854-014-2481-2.
  • [8] H. I. Humburg, M. Acosta, W. Jo, K. G. Webber, J. Rödel, Stress--dependent electromechanical properties of doped (Ba1−xCax)(ZryTi1−y)O3, J. Eur. Ceram. Soc. 35, 1209-1217 (2015). doi:10.1016/j.jeurceramsoc.2014.10.016.
  • [9] W. Li, Z. Xu, R. Chu, P. Fu, P. An, Effect of Ho doping on piezoelectric properties of BCZT ceramics, Ceram. Int. 38, 4353-4355 (2012). doi:10.1016/j.ceramint.2011.12.066.
  • [10] Y.-R. Cui, X.-Y. Liu, C.-L. Yuan, X. Zhai, Y.-B. Hu, R.-W. Li, Preparation and Properties of Sm2O3 Doped (Ba0.7Ca0.3)TiO3-Ba-(Zr0.2Ti0.8)O3 Lead-free Piezoelectric Ceramics, J. Inorg. Mater. 27, 731-734 (2012). doi:10.3724/SP.J.1077.2012.11517.
  • [12] T. Miki, A. Fujimoto, S. Jida, An evidence of trap activation for positive temperature coefficient of resistivity in BaTiO3 ceramics with substitutional Nb and Mn as impurities, J. Appl. Phys. 83, 1592-1603 (1998). doi:10.1063/1.366870.
  • [13] R. N. Schwartz, B. A. Wechsler, Electron-paramagnetic-resonance study of transition-metal-doped BaTiO3: Effect of material processing on Fermi-level position, Phys. Rev. B. 48, (1993). doi:10.1103/PhysRevB.48.7057.
  • [14] H. Herrig, R. Hempelmann, Microemulsion mediated synthesis of ternary and quaternary nanoscale mixed oxide ceramic powders, Nanostructured Mater. 9, 241-244 (1997). doi:10.1016/S0965-9773(97)90063-5.
  • [15] R.N. Viswanath, S. Ramasamy, Preparation and ferroelectric phase transition studies of nanocrystalline BaTiO3, Nanostructured Mater. 8, 155-162 (1997). doi:10.1016/S0965-773(97)00004-4.
  • [16] L. Zhang, L. Zhong, C. L. Wang, P. L. Zhang, Y.G. Wang, Dielectric Properties of Ba0.7Sr0.3TiO3 Ceramics with Different Grain Size, Phys. Status Solidi A. 168, 543-548 (1998). doi:10.1002/(SICI) 1521-396X(199808)168:2<543::AID-PSSA543>3.0.CO;2-J.
  • [17] N. C. Santhakumari, C. P. G. Vallabhan, Electrical conductivity, dielectric properties and phase transition in ethylenediammonium sulphate single crystals, J. Phys. Chem. Solids. 53, 697-701 (1992). doi:10.1016/0022-3697(92)90210-5.
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  • [19] S. J. Butcher, N. W. Thomas, Ferroelectricity in the system Pb(1−x) Bax(Mg13Nb23)O3, J. Phys. Chem. Solids. 52, 595-601 (1991). doi:10.1016/0022-3697(91)90153-Q.
  • [20] B. A. Boukamp, A Linear Kronig-Kramers Transform Test for Immittance Data Validation, J. Electrochem. Soc. 142, (1995). doi:10.1149/1.2044210.
  • [21] A. Lasia, Electrochemical Impedance Spectroscopy and its Applications, in: B.E. Conway, J. O. Bockris, R. E. White (Eds.), Mod. Asp. Electrochem., Springer US, 2002: pp. 143-248. http://link.springer.com/chapter/10.1007/0-306-46916-2_2 (accessed September 5, 2016).
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Uwagi
PL
1. Błąd w numeracji pozycji bibliogrficznych.
PL
2. Opracowanie rekordu w ramach umowy 509/P-DUN/2018 ze środków MNiSW przeznaczonych na działalność upowszechniającą naukę (2018).
Typ dokumentu
Bibliografia
Identyfikator YADDA
bwmeta1.element.baztech-3b692166-206a-49ea-816c-e4ddbf26ba95
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