Effect of Pyrolysis Temperature and Biomass Composition on Bio-Oil Characteristics

• Autorzy: Afrah Bazlina Dawami , Riady M. Ihsan , Arsadha Juliet Patricia , Rimadhina Rizky , Cundari Lia , Izzah Rosidah Zaatil

Identyfikatory

DOI

10.12912/27197050/181152

• Języki publikacji: EN

Abstrakty

EN

Pyrolysis is a method of producing oils from the raw materials of biomass by decomposing the thermochemical of organic materials at a given temperature. Free variables used in this research include pyrolysis temperaturę and biomass composition. The temperature variation of pyrolysis consists of three ranges: 100–200; 200–300; and 300–350 °C. Meanwhile, the composition of biomass consists of five combinations of waste rubber and coconut shells ranging from 0% coconut shell and 100% rubber wood to 80% coconut shell and 20% rubber shell. The physical characteristics of bio-oil analyzed include volume, pH, density, viscosity, and GC-MS analysis to determine its chemical characteristics. Research results showed that the pyrolysis temperature and composition of the biomass affected the characteristics of the bio-oil. The results of GC-MS analysis on bio-oil at 300–350 0C showed that bio-oil with a biomass composition of 80% coconut shells and 20% rubber wood yielded 50.19% phenol. The percentage of phenol is greater than that found in bio-oil with 20% coconut shells and 80% rubber wood, which is 18.78% phenol.

Słowa kluczowe

EN

biomass; waste to energy; rubber; wood waste; coconut shell; electric pyrolisis; spectrometric analysis; gas chromatography mass

• Wydawca: Lubelski Oddział Polskiego Towarzystwo Inżynierii Ekologicznej ; Lublin University of Technology ; WNGB Wydawnictwo Naukowe
• Czasopismo: Ecological Engineering & Environmental Technology
• Rocznik: 2024
• Tom: Vol. 25, iss. 3
• Strony: 264--274
• Opis fizyczny: Bibliogr. 33 poz., rys., tab.

Twórcy

autor

Afrah Bazlina Dawami

• Department of Chemical Engineering, Universitas Sriwijaya, South Sumatera, Indonesia

• https://orcid.org/0000-0002-0022-283X

autor

Riady M. Ihsan

• Department of Mechanical Engineering, Universitas Sriwijaya, South Sumatera, Indonesia

autor

Arsadha Juliet Patricia

• Department of Chemical Engineering, Universitas Sriwijaya, South Sumatera, Indonesia

autor

Rimadhina Rizky

• Department of Chemical Engineering, Universitas Sriwijaya, South Sumatera, Indonesia

autor

Cundari Lia

• Department of Chemical Engineering, Universitas Sriwijaya, South Sumatera, Indonesia

autor

Izzah Rosidah Zaatil

• Department of Chemical Engineering, Universitas Sriwijaya, South Sumatera, Indonesia

Bibliografia

• 1. Darmadji, P., Oramahi, H.A., and Armunanto, R. 2000. Optimasi produksi dan sifat fungsional asap cair kayu karet. Agritech: Jurnal Fakultas Teknologi Pertanian UGM, 20(3), 147–155.
• 2. Diatmika I.G.N.A.Y.A., Kencana P.K.D., Arda G. 2019. Characteristics of liquid smoke from pyrolyzed tabah bamboo (Gigantochloa nigrociliata Buse-Kurz) stems at different temperatures (in Indonesian). Jurnal Beta (Biosistem Dan Teknik Pertanian), 7(2), 278–285.
• 3. Dynamotive. 2006. The Bio Oil Information Book.
• 4. Fardhyanti, D.S., Damayanti, A. 2017. Analysis of bio-oil produced by pyrolysis of coconut shell. International Journal of Chemical and Molecular Engineering, 11(9), 651–654.
• 5. Fardhyanti, D.S., Damayanti, A., Larasati, A. 2017. Karakterisasi bio-oil dari hasil pirolisis terhadap biomasa. Proceedings of the National Seminar on Chemical Engineering “Kejuangan”, 5.
• 6. Fardhyanti, D.S., Kurniawan, C., Lestari, R.A.S., Triwibowo, B. 2018. Producing bio-oil from coconut shell by fast pyrolysis processing. MATEC Web of Conferences, 237, 02001.
• 7. Fardhyanti, D.S., Triwibowo, B., Istanto, H., Anajib, M.K., Larasati, A., Oktaviani, W. 2019. Liquid phase equilibrium of phenol extraction from bio-oil produced by biomass pyrolysis using thermodynamic models. Chinese Journal of Chemical Engineering, 27(2), 391–399.
• 8. Fauziati, F., Priatni, A., Adiningsih, Y. 2018. Pengaruh berbagai suhu pirolisis asap cair dari cangkang sawit sebagai bahan pengumpal lateks. Jurnal Riset Teknologi Industri, 12(2), 139–149.
• 9. Gracia-Vitoria, J., Gándara, S.C., Feghali, E., Ortiz, P., Eevers, W., Triantafyllidis, K.S., and Vanbroekhoven, K. 2023. The chemical and physical properties of lignin bio-oils, facts and needs. Current Opinion in Green and Sustainable Chemistry, 100781.
• 10.Harsono, S.S. 2018. Inovasi teknologi pembuatan asap cair dari tempurung kelapa di Kabupaten Situbondo. Warta Pengabdian, 11(4), 157–169.
• 11.Jacobson, K., Maheria, K.C., Dalai, A.K. 2013. Bio-oil valorization: A review. Renewable and Sustainable Energy Reviews, 23, 91–106.
• 12.Jayanudin, J., Suhendi, A., Uyun, J., Supriatna, A.H. 2012. Pengaruh suhu pirolisis dan ukuran tempurung kelapa terhadap rendemen dan karakteristik asap cair sebagai pengawet alami. Teknika: Jurnal Sains Dan Teknologi, 8(1), 46–55.
• 13.Lyu, G., Wu, S., Zhang, H. 2015. Estimation and comparison of bio-oil components from different pyrolysis conditions. Frontiers in Energy Research, 3, 28.
• 14.Machado, H., Cristino, A.F., Orišková, S., Galhano dos Santos, R. 2022. Bio-oil: the next-generation source of chemicals. Reactions, 3(1), 118–137.
• 15.Novita, S.A., Santosa, S., Nofialdi, N., Andasuryani, A., and Fudholi, A. 2021. Artikel review: Parameter Operasional Pirolisis Biomassa. Agroteknika, 4(1), 53–67.
• 16.Orhevba, B.A., Chukwu, O., Oguagwu, V., Osunde, Z.D. 2013. Effect of moisture content on some quality parameters of mechanically expressed neem seed kernel oil. Int. J. Eng. Sci.
• 17.Patra, S.C., Vijay, M., Panda, A.K. 2017. Production and characterisation of bio-oil from Gold Mohar (Delonix regia) seed through pyrolysis process. International Journal of Ambient Energy, 38(8), 788–793.
• 18.Phumichai, T., Tonusin, T., Rungtumnan, R., Chotchutima, S., Kasemsumran, S. 2020. Rubber wood properties testing for biomass energy by using visible–near infrared spectroscopy. Thai Journal of Agricultural Science, 53(2), 67–75.
• 19.Rizal, W.A., Maryana, R., Prasetyo, D.J., Pratiwi, D., Jatmiko, T.H., Ariani, D., Suwanto, A. 2020. Chemical composition of liquid smoke from coconut shell waste produced by SME in Rongkop Gunungkidul. IOP Conference Series: Earth and Environmental Science, 462(1), 012057.
• 20.Romadani, S., and Bahri, S. 2014. Konversi Pelepah Nipah Menjadi Bio-Oil Dengan Variasi Katalis Nimo/Lempung Cengar Memalui Proses Pirolisis. In Jom FTEKNIK, 1(2).
• 21.Rusydi, S.M. 2019. Prinsip Dasar Teknologi Pirolisa Biomassa, 1st ed (1 st edition). Unimal Press. Lhokseumawe.
• 22. Sa’diyah, H., Subagyono, R.R.D.J.N., Allo, V.L. 2021. Studi kinetika reaksi pirolisis makroalga hijau (Eucheuma cottonii) dengan analisis termogravimetri menggunakan metode friedman. MJoCE.
• 23.Sahrum, R.P., Syaiful, A.Z., Gazali, A. 2021. Uji Kualitas Asap Cair Tempurung Kelapa dan Serbuk Gergaji Kayu Metode Pirolisis. Jurnal Saintis, 2(2), 72–78.
• 24.Sakulkit, P., Palamanit, A., Dejchanchaiwong, R., Reubroycharoen, P. 2020. Characteristics of pyrolysis products from pyrolysis and co-pyrolysis of rubber wood and oil palm trunk biomass for biofuel and value-added applications. Journal of Environmental Chemical Engineering, 8(6), 104561.
• 25.Sangthong, S., Phetwarotai, W., Bakar, M.S.A., Cheirsilp, B., Phusunti, N. 2022. Phenol-rich biooil from pyrolysis of palm kernel shell and its isolated lignin. Industrial Crops and Products, 188, 115648.
• 26.Shah, Z., Cataluña Veses, R., Ceschi, M.A., Silva, R. da. 2017. Separation of phenol from bio-oil produced from pyrolysis of agricultural wastes. Modern Chemistry and Applications. Los Angeles. 5(1), 1000199.
• 27.Subagyono, R.R.D.J.N., Qi, Y., Chaffee, A.L., Amirta, R., Marshall, M. 2021. Pyrolysis-gc/ms analysis of fastgrowing wood macaranga species. Indonesian Journal of Science and Technology, 6(1), 141–158.
• 28. Sun, T., Chen, Z., Wang, R., Yang, Y., Zhang, L., Li, Y., Liu, P., Lei, T. 2023. Influences of the reaction temperature and catalysts on the pyrolysis product distribution of lignocellulosic biomass (aspen wood and rice husk). Polymers, 15(14), 3104.
• 29.Suyitno, Arifin, Z., Hadi, S., Hidayat, Y. 2009. Bio Oil Dari Pirolisis Lambat Sekam Padi Basah: Sifat Fisik Dan Unsur Kimia. Mekanika, 7(2).
• 30.Towaha, J., Aunillah, A., Purwanto, E.H. 2013. Pemanfaatan asap cair kayu karet dan tempurung kelapa untuk penanganan polusi udara pada lump. Bul. RISTRI.
• 31.Tüccar, G., Tosun, E., Uludamar, E. 2018. Investigations of effects of density and viscosity of diesel and biodiesel fuels on NOx and other emission formations. Academic Platform-Journal of Engineering and Science, 6(2), 81–85.
• 32.Weerachanchai, P., Tangsathitkulchai, C., Tangsathitkulchai, M. 2007. Fuel properties and chemical compositions of bio-oils from biomass pyrolysis. SAE Technical Paper.
• 33.Zulkania, A. 2016. Pengaruh temperatur dan ukuran partikel biomassa terhadap bio-oil hasil pirolisis ampas tebu/baggase. Teknoin, 22(5).

Uwagi

Opracowanie rekordu ze środków MNiSW, umowa nr SONP/SP/546092/2022 w ramach programu "Społeczna odpowiedzialność nauki" - moduł: Popularyzacja nauki i promocja sportu (2024).