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Mineral separation relies heavily on the process of flotation. This study explored the feasibility of using organosolv lignin nanoparticles and microparticles (OLP) as a greener alternative to xanthates in the flotation process for mineral separation. Xanthates are widely used but pose environmental and health risks. The efficiency of OLP as collectors was compared to collectorless flotation, resulting in approximately 50% copper recovery, indicating that OLP may not be a suitable replacement for xanthates. Further tests were conducted using a mixture of xanthates and OLP (birch nano and spruce micro) with varying substitution levels (20%, 30%, and 40%). The results demonstrated that increasing the dosage of OLP led to a decrease in flotation efficiency for copper. TOC analysis of the products revealed that high dosages (160 g/t) of birch nano and spruce micro as sole collectors showed beneficiation and selective recovery against copper. While OLPs did not prove effective as collectors, the study highlights their potential as substitutes for maltodextrin in selective flotation of the final concentrate. Two out of four tested OLPs were recommended for pilot scale testing.
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Tom
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art. no. 174363
Opis fizyczny
Bibliogr. 20 poz., rys., tab., wykr.
Twórcy
autor
- KGHM Cuprum Ltd. Research and Development Centre
- Wrocław University of Science and Technology
autor
- KGHM Cuprum Ltd. Research and Development Centre
autor
- Lulea University of Technology
Bibliografia
- BAJWA, D. S., POURHASHEM, G., ULLAH, A. H., BAJWA, S. G., 2019. A concise review of current lignin production, applications, products and their environmental impact. Industrial Crops and Products, 139, 111526
- BARTLETT, S., BURGESS, H., DAMJANOVIĆ, B., GOWANS, R., LATTANZI, C., 2013. Raport techniczny dotyczący produkcji miedzi i srebra przez KGHM Polska Miedź SA w Legnicko-Głogowskim Okręgu Miedziowym w południowozachodniej Polsce (Technical report on the production of copper and silver by KGHM Polish Copper JSC in the Legnica-Głogów Copper District in south-western Poland). KGHM Polska Miedź SA, Lubin (in Polish).
- ELIZONDO-ÁLVAREZ, M. A., URIBE-SALAS, A., BELLO-TEODORO, S., 2021. Chemical stability of xanthates, dithiophosphinates and hydroxamic acids in aqueous solutions and their environmental implications. Ecotoxicology and Environmental Safety, 207, 111509.
- FOSZCZ, D., DRZYMAŁA, J., 2011. Differentiation of organic carbon, copper and other metals contents by segregating flotation of final Polish industrial copper concentrates in the presence of dextrin. Physicochemical Problems of Mineral Processing, 47.
- HRUZOVA, K., MATSAKAS, L., SAND, A., ROVA, U., CHRISTAKOPOULOS, P., 2020. Organosolv lignin hydrophobic micro-and nanoparticles as a low-carbon footprint biodegradable flotation collector in mineral flotation. Bioresource technology, 306, 123235.
- HRŮZOVÁ, K., KOLMAN, K., MATSAKAS, L., NORDBERG, H., CHRISTAKOPOULOS, P., & ROVA, U. 2023. Characterization of Organosolv Lignin Particles and Their Affinity to Sulfide Mineral Surfaces. ACS Applied Nano Materials.
- KALOGIANNIS, K. G., MATSAKAS, L., ASPDEN, J., LAPPAS, A. A., ROVA, U., CHRISTAKOPOULOS, P., 2018. Acid assisted organosolv delignification of beechwood and pulp conversion towards high concentrated cellulosic ethanol via high gravity enzymatic hydrolysis and fermentation. Molecules, 23(7), 1647.
- KIJEWSKI, P., LESZCZYŃSKI, R., 2010. Węgiel organiczny w rudach miedzi-znaczenie i problemy. Zeszyty Naukowe Instytutu Gospodarki Surowcami Mineralnymi i Energią PAN, 131-146.
- KONIECZNY, A., DUCHNOWSKA, M., KALETA, R., PAWLOS, W., KOWALCZUK, P., KRZEMIŃSKA, M., DRZYMAŁA, J., 2015. Analiza wyników usuwania węgla organicznego z rudy miedzi za pomocą flotacji spieniaczami, 11. Międzynarodowa Konferencja Przeróbki Rud Metali Nieżelaznych ICNOP, 27-29.
- KONIECZNY, A., PAWLOS, W., KRZEMINSKA, M., KALETA, R., KURZYDŁO, P., 2013. Evaluation of organic carbon separation from copper ore by pre-flotation. Physicochemical Problems of Mineral Processing, 49(1), 189-201.
- KURZYDŁO, P., PAWLOS, W., 2021. Ocena efektywności wzbogacania minerałów siarczkowych miedzi przy zmianie reżimu odczynnikowego flotacji czyszczących. Szkoła Eksploatacji Podziemnej 2021, Materiały Konferencyjne.
- MATSAKAS, L., GERBER, M., YU, L., ROVA, U., CHRISTAKOPOULOS, P., 2020. Preparation of low carbon impact lignin nanoparticles with controllable size by using different strategies for particles recovery. Industrial Crops and Products, 147, 112243.
- MILLER, J. D., LIN, C. L., CHANG, S. S., 1984. Coadsorption phenomena in the separation of pyrite from coal by reserve flotation. Coal Perparation, 1(1), 21-38.
- NDORO, T. O., WITIK, L. K., 2017. A review of the flotation of copper minerals. Int. J. Sci.: Basic Appl. Res. (IJSBAR), 34(2), 145-165.
- NGUYEN, A.V., SCHULZE, H. J., 2004. Colloidal Science of Flotation. Surfactant Science Series Volume 118. Part 1: 3-16
- NIEĆ, M., PIETRZYŃSKI, A., 2007. Monografia KGHM POLSKA Miedź S.A., 157-159.
- NYAMEKYE, G.A, LASKOWSKI, J.S., 1991. The differential flotation of INCO matte with the use of polysaccharides, in: Dobby G.S., Argyropoulos, S.A., Rao, S.R., (Eds). Proc. Copper ’91 Int. Symp, 1991, 2, 231-243.
- SHEN, Y., NAGARAJ, D. R., FARINATO, R., SOMASUNDARAN, P., 2016. Study of xanthate decomposition in aqueous solutions. Minerals Engineering, 93, 10-15.
- SKORUPSKA, B., WIENIAWSKI, A., KUBACZ, N., 2011. The possibilities of producing copper concentrates featuring diversified organic components content. Mining and Geology, vol. 6, paper 2.
- SOONGPRASIT, K., SRICHAROENCHAIKUL, V., ATONG, D., 2020. Phenol-derived products from fast pyrolysis of organosolv lignin. Energy Reports, 6, 151-167.
Typ dokumentu
Bibliografia
Identyfikator YADDA
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