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Function and mechanism of sodium silicate in the cleaning process of ilmenite rough concentrate

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Identyfikatory
Warianty tytułu
Języki publikacji
EN
Abstrakty
EN
The grade of titanium dioxide (TiO2) from Panzhihua titanium concentrate (defined as the ilmenite rough concentrate in this paper) is generally around 47%. The high impurity content in the titanium concentrate causes difficulties for its successive use in the production of titania pigment. Further purification of the ilmenite concentrate will make it more useful for industrial use. In this study, a further cleaning process of the ilmenite rough concentrate is conducted using sodium silicate as the depressant, and the function of sodium silicate is determined by flotation, absorption measurements, Zeta potential measurements, and infrared spectral analysis. The results indicate that an ilmenite concentrate with a TiO2  grade of 50.37% can be achieved from 46.78% according to the stages on the flowsheet-one roughing, three cleaning and one scavenging-under the optimal conditions, and can also reflect the advantages of the excellent selectivity of sodium silicate. Sodium silicate can hinder the adsorption of salicylhydroxamic acid (SHA) on the titanaugite surface but has almost no effect on ilmenite. Multiple methods comprehensively confirm that sodium silicate provides a good selective depression effect for the further purification of the ilmenite rough concentrate.
Słowa kluczowe
Rocznik
Strony
1099--1107
Opis fizyczny
Bibliogr. 41 poz., rys., tab.
Twórcy
autor
  • College of Earth Science and Resources, Chang’an University, Xi’an 710064, China
  • State Key Laboratory of Complex Nonferrous Metal Resources Clean Utilization, Faculty of Land Resource Engineering, Kunming University of Science and Technology, Kunming 650093, China
autor
  • State Key Laboratory of Complex Nonferrous Metal Resources Clean Utilization, Faculty of Land Resource Engineering, Kunming University of Science and Technology, Kunming 650093, China
  • School of Chemical & Environmental Engineering, China University of Mining & Technology (Beijing), Beijing 100083, China
  • State Key Laboratory of Complex Nonferrous Metal Resources Clean Utilization, Faculty of Land Resource Engineering, Kunming University of Science and Technology, Kunming 650093, China
autor
  • State Key Laboratory of Complex Nonferrous Metal Resources Clean Utilization, Faculty of Land Resource Engineering, Kunming University of Science and Technology, Kunming 650093, China
Bibliografia
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  • DONG, H., JIANG, T., GUO, Y., CHEN, J., FAN, X., 2012. Upgrading a Ti-slag by a roast-leach process. Hydrometallurgy, 113, 119-121.
  • DRZYMALA, J., LUSZCZKIEWICZ, A., SIMICZYJEW, P., 1983. Flotation study on high-hercynite ilmenite ores. International Journal of Mineral Processing, 10(4), 289-296.
  • DUAN, C., LI, F., YANG, M., ZHANG, H., WU, Y., XI, H., 2018. Rapid Synthesis of Hierarchically Structured Multifunctional Metal–Organic Zeolites with Enhanced Volatile Organic Compounds Adsorption Capacity. Industrial & Engineering Chemistry Research, 57(45), 15385-15394.
  • FAN, G., LIU, J., CAO, Y., FENG, L., XU, H., 2016. Adsorption mechanism of sodium oleate on titanium dioxide coated sensor surface using quartz crystal microbalance with dissipation. Physicochemical Problems of Mineral Processing 52, 597-608.
  • FAN, G., LIU, J., CAO, Y., HUO, T., 2014. Optimization of fine ilmenite flotation performed in a cyclonic-static micro-bubble flotation column. Physicochemical Problems of Mineral Processing, 50(2), 823--834.
  • FAN, X., ROWSON, N., 2000. The effect of Pb (NO3) 2 on ilmenite flotation. Minerals Engineering, 13(2), 205-215.
  • HOU, T., ZHANG, Z., YE, X., ENCARNACION, J., REICHOW, M. K., 2011. Noble gas isotopic systematics of Fe–Ti–V oxide ore-related mafic–ultramafic layered intrusions in the Panxi area, China: The role of recycled oceanic crust in their petrogenesis. Geochimica et Cosmochimica Acta, 75(22), 6727-6741.
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  • LAI, H., DENG, J., FAN, G., XU, H., CHEN, W., LI, S., HUANG, L., 2019. Mechanism Study of Xanthate Adsorption on Sphalerite/Marmatite Surfaces by ToF-SIMS Analysis and Flotation. Minerals, 9(4), 205. .
  • LI, C., LIANG, B., GUO, L. H., WU, Z. B., 2006. Effect of mechanical activation on the dissolution of Panzhihua ilmenite. Minerals Engineering, 19(14), 1430-1438
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  • LIU, X., HUANG, G.-Y., LI, C.-X., CHENG, R.-J., 2015. Depressive effect of oxalic acid on titanaugite during ilmenite flotation. Minerals Engineering, 79, 62-67.
  • LIU, X., XIE, J., HUANG, G., LI, C., 2017. Low-temperature performance of cationic collector undecyl propyl ether amine for ilmenite flotation. Minerals Engineering, 114, 50-56.
  • MA, M., 2011. The dispersive effect of sodium silicate on kaolinite particles in process water: implications for iron-ore processing. Clays and Clay Minerals, 59(3), 233-239.
  • MAHMOUD, M. H., HESSIEN, M. M., ALHADHRAMI, A., GOBOURI, A. A., 2019. Physicochemical properties of pseudobrookite Fe 2 TiO 5 synthesized from ilmenite ore by co-precipitation route. Physicochemical Problems of Mineral Processing, 55(1), 290-300.
  • MEHDILO, A., IRANNAJAD, M. REZAI, B., 2014. Effect of oxidation roasting on ilmenite flotation. Physicochemical Problems of Mineral Processing, 50(2), 493-505.
  • MEHDILO, A., IRANNAJAD, M., REZAI, B., 2015. Effect of crystal chemistry and surface properties on ilmenite flotation behavior. International Journal of Mineral Processing, 137, 71-81.
  • PARAPARI, P. S., IRANNAJAD, M., MEHDILO, A., 2017. Effect of acid surface dissolution pretreatment on the selective flotation of ilmenite from olivine and pyroxene. International Journal of Mineral Processing, 167, 49- 60.
  • SILVA, J., BALTAR, C., GONZAGA, R., PERES, A., LEITE, J., 2012. Identification of sodium silicate species used as flotation depressants. Minerals and Metallurgical Processing, 29(4), 207.
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  • WANG, Y., WEN, S., ZHANG, J., WU, D., XIAN, Y., SHEN, H., 2017. Flotation behaviour and surface characteristic of anosovite in a sodium oleate solution. Physicochemical Problems of Mineral Processing 53(2), 714-723.
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  • YANG, Y., XU, L, TIAN, J., LIU, Y., HAN, Y., 2016. Selective flotation of ilmenite from olivine using the acidified water glass as depressant. International Journal of Mineral Processing, 157, 73-79.
  • ZHANG, G.-F., WANG, L., FENG, Q.-M., LU, Y.-P., OU, L.-M., 2009. Effect of titanaugite on flotation behavior of ilmenite. The Chinese Journal of Nonferrous Metals, 6, 025.
  • ZHANG, G.-F., YAN, D.-C., ZHU, Y.-G., FENG, Q.-M., WANG, W.-Q., 2011. Influence of pH on adsorption of sodium oleate on surface of ilmenite and titanaugite. Journal of Central South University (Science and Technology), 10, 004.
  • ZHANG, G.-F., ZHU, Y.-G., FENG, Q.-M., LU, Y.-P., OU, L.-M., 2009. Flotation mechanism of fine ilmenite by sodium oleate. The Chinese Journal of Nonferrous Metals, 2, 031.
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  • ZHAO, X., MENG, Q., YUAN, Z., ZHANG, Y., LI, L., 2019. Effect of sodium silicate on the magnetic separation of ilmenite from titanaugite by magnetite selective coating. Powder Technology, 344, 233-241.
  • ZHOU, M.-F., CHEN, W. T., WANG, C. Y., PREVEC, S. A., LIU, P. P., HOWARTH, G. H., 2013. Two stages of immiscible liquid separation in the formation of Panzhihua-type Fe-Ti-V oxide deposits, SW China. Geoscience Frontiers, 4(5), 481-502.
  • ZHOU, W., MORENO, J., TORRES, R., VALLE, H., SONG, S., 2013. Flotation of fluorite from ores by using acidized water glass as depressant. Minerals Engineering, 45, 142-145.
  • ZHU, Y.-G., ZHANG, G.-F., FENG, Q.-M., YAN, D.-C., WANG, W.-Q., 2011. Effect of surface dissolution on flotation separation of fine ilmenite from titanaugite. Transactions of Nonferrous Metals Society of China, 21(5), 1149-1154.
Uwagi
Opracowanie rekordu ze środków MNiSW, umowa Nr 461252 w ramach programu "Społeczna odpowiedzialność nauki" - moduł: Popularyzacja nauki i promocja sportu (2020).
Typ dokumentu
Bibliografia
Identyfikator YADDA
bwmeta1.element.baztech-39897606-805c-48f2-9400-98a742d64ae9
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