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Biodesulphurization of thiophene as a sulphur model compound in crude oils by Pseudomonas aeruginosa supported on polyethylene

Identyfikatory
Warianty tytułu
PL
Biodesulfuryzacja modelowego związku siarki w surowej ropie naftowej - tiofenu przez Pseudomonas aeruginosa na podłożu polietylenowym
Języki publikacji
EN
Abstrakty
EN
A new biodesulphurization method has been considered using Pseudomonas aeruginosa supported on polyethylene (PE) for biodesulphurization (BDS) of thiophene as an aromatic sulphur model compound of crude oils. Also the biodegradation of thiophene has been modified in the presence of potassium hexacyanoferrate(III) as a terminal electron acceptor to approach the maximum biodesulphurization efficiency. The obtaining results according to UV-Spectrophotometry at 240 nm, 83.3% of thiophene at the primary concentration of 50 mg/dm3, pH = 7, by 0.5 g of biocatalyst in 37°C after 4 h of contact time has been removed. The bacterial cells exhibited a greater and faster biodegradation in the presence of potassium hexacyanoferrate(III) and 94.8% of thiophene has been removed after 3 h of contact time. Kinetic study predicted chemisorption of thiophene on the surface of the biocatalyst, as it followed the pseudo-second-order rate equation. Morphology and surface functional groups of the biocatalyst have been investigated by SEM and FT-IR, respectively.
Rocznik
Strony
371--379
Opis fizyczny
Bibliogr. 44 poz., wykr., tab., fot.
Twórcy
autor
  • Department of Chemical Engineering, College of Engineering, Kermanshah Branch, Islamic Azad University, Kermanshah, Iran, phone +98 9183588590, fax +98 8337243196
autor
  • Department of Chemistry, College of Basic Sciences, Kermanshah Branch, Islamic Azad University, Kermanshah, 6718997551, Iran, phone +98 8337243181, fax +98 8337243196
autor
  • Department of Chemical Engineering, College of Engineering, Kermanshah Branch, Islamic Azad University, Kermanshah, Iran, phone +98 9388179853, fax +98 8337243196
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Uwagi
PL
Opracowanie ze środków MNiSW w ramach umowy 812/P-DUN/2016 na działalność upowszechniającą naukę (zadania 2017).
Typ dokumentu
Bibliografia
Identyfikator YADDA
bwmeta1.element.baztech-392f9d7c-9176-4fe4-a018-6e2c0117e6b7
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