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To enhance the rain erosion resistance of wind turbine blade leading-edge protection materials, a series of modified polyurethane (PU) composites were developed by optimizing the synthesis process of PU prepolymers – specifically by tuning the isocyanate (NCO) content, selecting polycaprolactone diols (PCL) with different molecular weights, and introducing an organic titanium catalyst (2210) and hydroxy-terminated polydimethylsiloxane (HO-PDMS). The effects of these components on the mechanical properties, rain erosion resistance, and thermal stability were systematically investigated. Results showed that optimizing the NCO content balanced strength and toughness, achieving a tensile strength of 25.0 MPa at 6% NCO and peak hardness (94.2 Shore A) at 9% NCO. Higher molecular weight PCL (2,000 g/mol) significantly enhanced tensile strength (27.72 MPa) and elongation at break (395.2%) due to improved microphase separation. The addition of 0.03 wt% catalyst 2210 reduced demolding time to 49 min and improved mechanical properties. PU containing 7 wt% HO-PDMS (Mn = 1,000 g/mol, sample SPU7) exhibited optimal rain erosion life (31.6 h), superior thermal stability, and high storage modulus. However, excessive HO-PDMS (e.g., SPU9) led to interfacial defects. This study provides a promising strategy for developing long-lasting, high-reliability protective materials for wind turbine blades.
Słowa kluczowe
Wydawca
Czasopismo
Rocznik
Tom
Strony
23--39
Opis fizyczny
Bibliogr. 24 poz., rys., tab.
Twórcy
autor
- State Key Laboratory of Power Grid Disaster Prevention and Reduction (Disaster Prevention and Reduction Center of State Grid Hunan Corporation) Changsha, China
autor
- State Key Laboratory of Power Grid Disaster Prevention and Reduction (Disaster Prevention and Reduction Center of State Grid Hunan Corporation) Changsha, China
Bibliografia
- [1] Hu, J., Min, C., Yang, X., Wang, K., Xie, L., Numerical andexperimental study on heat transfer characteristics of single vibrating blade in a channel flow, J. Therm. Sci.,2023, 32(3): 982–992. doi:10.1007/s11630-023-1814-y
- [2] Tian, L., Li, L., Hu, H., Hu, H., Experimental study of dynamic ice accretion process over rotating aeroen-gine fan blades, J. Thermophys. Heat. Trans., 2023, 37(2): 353–364. doi:10.2514/1.T6667
- [3] Brijder, R., Helsen, S., Ompusunggu, A.P., Switching kalman filtering-based corrosion detection and prognostics for offshore wind-turbine structures, Wind,2023, 3(1): 1–13. doi:10.3390/wind3010001
- [4] Zhang, X., Zhang, Z., Yu, F., Dual-responsive PU inverse photonic crystal film with high flexibility for anti-counterfeiting, J. Mater. Chem. C., 2023, 11(35): 11936–11942. doi:10.1039/d3tc02444j
- [5] Mirzaee, M., Mohebbi, T., A review of anti-corrosion and erosion protective coatings in offshore wind power devices, J. Stud. Color. World, 2024, 14(2): 133–159. doi:10.30509/JSCW.2024.82001
- [6] Ye, X.A., Zhou, X., Zeng, X.Y., Wang, G.G., Conductive composite inks comprised of waterborne polyurethane, silver nanosheets, and heat-treated MXene nanosheets for electromagnetic shielding and thermal management, ACS Appl. Nano Mater., 2024, 7(16): 19075–19088. doi:10.1021/acsanm.4c02902
- [7] Minoofar, G., Kandeloos, A.J., Koochaki, M.S., Momen, G., Progress in icephobic coatings for wind turbine protection: Merging chemical innovation with practical implementation, Crystals, 2025, 15(2): 139–142. doi:10.3390/cryst15020139
- [8] Huang, M., Huang, Y., Yang, H., Li, W., Ti3C2Tx MXene/Fe3O4/carbon fiber fabric/water polyurethane composite fabrics for electromagnetic interference shielding and thermal management, ACS Appl. Nano Mater., 2024, 7(13): 14921–14935. doi:10.1021/acsanm.4c00639
- [9] Hao, Y., Niu, Z., Yang, J., Wang, M., Liu, H., Qin, Y., et al., Self-powered terahertz modulators based on metamaterials, liquid crystals, and triboelectric nanogenerators, ACS Appl. Mater. Interfaces, 2024, 16(25): 32249–32258. doi:10.1021/acsami.4c04251
- [10] Zuo, D., Jia, Y., Xu, J., Fu, J., High-performance microwave absorption materials: Theory, fabrication, and functionalization, Ind. Eng. Chem. Res., 2023, 62(37): 14791–14817. doi:10.1021/acs.iecr.3c02150
- [11] Tuo, K., Li, J., Li, Y., Liang, C., Shao, C., Hou, W., et al., Construction of hierarchical porous and polydopamine/salicylaldoxime functionalized zeolitic imidazolate framework-8 via controlled etching for uranium adsorption, Mater. Horiz., 2024, 11(14): 3364–3374. doi:10.1039/d3mh02108d
- [12] Chai, C., Ma, Z., Yin, X., Pang, H., Self-lubricating and self-healing polyurethane nanocomposites based on aminated-Ti3C2Tx, ACS Appl. Nano Mater., 2024, 6(5): 2513–2523. doi:10.1021/acsapm.3c02629
- [13] Ma, Y.J., Wang, J.W., Zhuang, G.C., Zhang, Y., Zhang, Z.L., Zhang, M.Y., et al., Polysulfide polyurethane-urea-based dielectric composites with CeO2-loaded MXene exhibiting high self-healing efficiency, J. Mater. Chem. C., 2023, 11(36): 12261–12269. doi:10.1039/d3tc02101g
- [14] Bose, N., Danagody, B., Rajappan, K., Ramanujam, G.M., Anilkumar, A.K., Sustainable routed Mxene-based aminolyzed PU/PCL film for increased oxidative stress and a pH-sensitive drug delivery system for anticancer therapy, ACS Appl. Bio Mater., 2023, 7(1): 379–393. doi:10.1021/acsabm.3c00957
- [15] Xu, Y., Shen, R., Tang, J., Zou, X., Wan, W., Guo, H., Optimizing mechanical properties and corrosion resistance in core-shell nanofiber epoxy self-healing coatings: Impact of shell material variation, Polym. Eng. Sci., 2024, 64(4): 1770–1785. doi:10.1002/pen.26655
- [16] Fan, S., Shen, Z., Yin, J., Wang, Z., Pu, J., A high performance MBene substrate for improving the MnO2 cathodes for aqueous Zn-ion batteries, Chem. Commun., 2025, 61(9): 1838–1841. doi:10.1039/d4cc05835f
- [17] Wang, Q., Jia, C., Li, Z., Pu, L., Qiu, Y., Yan, C., et al., Association analysis between the distribution of surface physical characteristics and bonding performance of carbon fiber composites, Polym. Compos., 2024, 45(10): 8797–8809. doi:10.1002/pc.28377
- [18] Dimitriadi, M., Petropoulou, A., Vakou, D., Zinelis, S., Eliades, G., In vitro evaluation of a silane containing self-adhesive resin luting agent, Dent. Mater., 2023, 39(2): 181–191. doi:10.1016/j.dental.2022.12.007
- [19] Yakisan, K.I., Turkel, V., Celik, E., Production, characterization and mechanical behaviors of electrolytic metal-coated light polymeric cylinders for photogravure press applications, Arab. J. Sci. Eng., 2024, 49(11): 15679–15699. doi:10.1007/s13369-024-09136-w
- [20] Nie, C., Shi, Y., Jiang, S., Wang, H., Liu, M., Huang, R., et al., Constructing fireproof MXene-based cotton fabric/thermoplastic polyurethane hierarchical composites via encapsulation strategy, ACS Appl. Nano Mater., 2023, 5(9): 7229–7239. doi:10.1021/acsapm.3c01201
- [21] Wang, G., Wang, M., Zheng, M., Ebo, B., Xu, C., Liu, Z., et al., Thermoplastic polyurethane/carbon nanotube composites for stretchable flexible pressure sensors, ACS Appl. Nano Mater., 2023, 6(11): 9865–9873. doi:10.1021/acsanm.3c01543
- [22] Zhang, C., Zhang, Y., Gu, X., Ma, C., Wang, Y., Peng, J., et al., Radiation synthesis of MXene/Ag nanoparticle hybrids for efficient photothermal conversion of polyurethane films, Rsc Adv., 2023, 13(22): 15157–15164. doi:10.1039/d3ra02799f
- [23] Ran, A., Liang, F., Yu, S., Gan, Y., Yang, W., Fan, B., et al., Synthesis of silicone-modified self-healing polyurethane coatings with MXene@fluorinated polyaniline for prolonged corrosion resistance, J. Coat. Technol. Res., 2024, 21(6): 2035–2046. doi:10.1007/s11998-024-00952-1
- [24] He, J., Huang, C., Pu, M., Shu, Z., Duan, Z., Zeng, Z., et al., Preparation and performance study of SiO2 aerogel thermal insulation coating with nanoporous structure for wind turbine blade surface, J. Adhes. Sci. Technol., 2024, 38(13): 2425–2446. doi:10.1080/01694243.2024.2302262
Typ dokumentu
Bibliografia
Identyfikator YADDA
bwmeta1.element.baztech-39280e19-07c8-409a-aafe-8e8f790fec78
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