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Crystallization Process of Silicon Molybdenum Cast Iron

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Treść / Zawartość
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Warianty tytułu
Języki publikacji
EN
Abstrakty
EN
The article presents results of studies of silicon – molybdenum cast iron (4.42% Si, 2.59% Mo and 2.48% C wt.-%) crystallization process. Metallographic analysis was carried out using SEM-scanning electron microscopy with the EDS system. In order to determine the phase composition, X-ray diffraction studies were performed. Thermo-Calc, a computer simulation program, was used to simulate the crystallization process. . The obtained data allowed to describe the effect of some elements on the crystallization process. The silicon phase of MnSi could not be identified during metallographic studies. Also, computer simulation of the crystallization process did not answer the question at which point the silicon phase of MnSi crystallizes in the tested alloy. Therefore, not all results obtained were linked to the registered crystallization process (TDA process). The EDS analysis revealed an unusual distribution of molybdenum in the microstructure of the sample, where it is clearly visible that the area enriched with this element is also the separation of spheroidal graphite. The possibility of occurrence of Mo-rich micro-areas found in graphite is considered. The case is debatable and difficult to resolve at this stage. Perhaps, at such a high concentration of molybdenum (2.59% Mo) in the alloy, conditions are created for simultaneously crystallization of graphite and molybdenum phases.
Rocznik
Strony
100--104
Opis fizyczny
Bibliogr. 13 poz., rys., wykr.
Twórcy
autor
  • Silesian University of Technology, Department of Foundry Engineering, Towarowa 7, 44-100 Gliwice, Poland
Bibliografia
  • [1] Roedter, H. (2006). 4–6% Silicon ductile irons for high temperature service. Sorelmetal. Rio Tinto Iron& Titanium inc.
  • [2] Li, D. & Sloss, C. (2015). Heat treatment of heat-resistant ferrous cast alloys. International Journal of Metalcasting. 9(2), 7-20.
  • [3] Mervat, M.I., Nofal, A. & Mourad, M.M. (2016). Microstructure and hot oxidation resistance of SiMo ductile cast irons containing Si-Mo-Al. Metallurgical and Materials Transaction B. DOI 10.1007/s11663-016-0871-y.
  • [4] Magnusson Åberg, L. & Hartung, C. (2012). Solidification of SiMo nodular cast iron for high temperature applications. Trans Indian Inst Met. 65(6), 633-636. DOI 10.1007/s12666-012-0216-8.
  • [5] Stawarz, M. (2017). SiMo ductile iron crystallization process. Archives of Foundry Engineering. 17(1), 147-152. DOI: 10.1515/afe-2017-0027.
  • [6] Hervas, I., Thuault, A. & Hug, E. (2015). Damage analysis of a ferritic simo ductile cast iron submitted to tension and compression loadings in temperature. Metals. 5, 2351-2369. DOI:10.3390/met5042351.
  • [7] Stawarz, M., Nuckowski, P.M. & Dojka, M. (2017). High molybdenium silicon cast iron crystallization process. In Metal 2017: 26th International Conference on Metallurgy and Materials – Metal 2017. Ostrava: TANGER 2017, 229-234.
  • [8] Wilk-Kolodziejczyk, D., Regulski, K. & Gumienny, G. (2016) Comparative analysis of the properties of the nodular cast iron with carbides and the austempered ductile iron with use of the machine learning and the support vector machine. The International Journal of Advanced Manufacturing Technology. 87, 1077-1093. DOI: 10.1007/s00170-016-8510-y.
  • [9] Ouahrani, T., Faraoun, H.I. & Abderrahim, F.Z. (2012). Structure, bonding and stability of semi-carbides M2C and sub-carbides M4C (M=V, Cr, Nb, Mo, Ta, W): A first principles investigation. Physica B, Condensed Matter. 407, 3833-3838, DOI: 10.1016/j.physb.2012.05.070.
  • [10] Nowotny, H.N., Wayne, S.F., Kostiner, E. & Rapposch, M.H. (1983). Revue de Chimie Minerale. 20, 528-531.
  • [11] Wood I.G., Vocadlo L., Knight, K.S., Dobson D.P., Marshall, W.G., Price, G.D. & Brodholt, J. (2004). Thermal expansion and crystal structure of cementite, Fe3C, between 4 and 600 K determined by time-of-flight neutron powder diffraction. Journal of Applied Crystallography. 37, 82-90. DOI: 10.1107/S0021889803024695.
  • [12] Shoemaker, D.P. & Brink-Shoemaker, C. (1971). Acta Crystallographica B (24,1968-38,1982), 27, 227-235.
  • [13] Stolarz, S., Rutkowski, W. (1961) Tungsten and molybdenum. Warsaw: State Technical Publishing. (in Polish).
Uwagi
PL
Opracowanie rekordu w ramach umowy 509/P-DUN/2018 ze środków MNiSW przeznaczonych na działalność upowszechniającą naukę (2018).
Typ dokumentu
Bibliografia
Identyfikator YADDA
bwmeta1.element.baztech-37bbb479-6357-4e97-acbc-650c9e95f8b4
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