Ionic [Ru] complex with recyclability by electro-adsorption for efficient catalytic transfer hydrogenation of aryl ketones

• Autorzy: Yue C. J. , Xue Q. N. , Gu L. P. , Wang J. F.

Identyfikatory

DOI

10.1515/pjct-2017-0070

• Języki publikacji: EN

Abstrakty

EN

The efficient reuse of homogeneous catalyst is important. Cation complex of [Ru(η⁶ -p-cymene)(PPh₃ )(CH₃ CN) Cl]PF₆  with different ligands was synthesized and characterized by infrared spectroscopy (IR), ¹ H-, ¹³ C- and ³¹ P-nuclear magnetic resonance spectroscopy (¹ H-, ¹ 3C- and ³¹ P-NMR), element analysis (EA), and high resolution mass spectrometry (HR-MS). The complex was used as a catalyst for the hydrogen transfer reduction of carbonyl for the first time, presenting an excellent catalytic performance of 89%–98% conversion of acetophenone and its derivatives. The catalyst may be efficiently reused by the electro-adsorption of 10 times to one catalyst recovery. The cation [Ru] complex presented advantages of both homogeneous and heterogeneous catalysts.

Słowa kluczowe

EN

ionic Ru complex; transfer hydrogenation; electron-adsorption; catalyst recovery

• Wydawca: West Pomeranian University of Technology. Publishing House
• Czasopismo: Polish Journal of Chemical Technology
• Rocznik: 2017
• Tom: Vol. 19, nr 4
• Strony: 75--79
• Opis fizyczny: Bibliogr. 33 poz., rys.

Twórcy

autor

Yue C. J.

• School of Mathematics and Chemical Engineering, Changzhou Institute of Technology, Department of Chemical Engineering, Changzhou 213022, P.R. China

autor

Xue Q. N.

• School of Mathematics and Chemical Engineering, Changzhou Institute of Technology, Department of Chemical Engineering, Changzhou 213022, P.R. China

autor

Gu L. P.

• School of Mathematics and Chemical Engineering, Changzhou Institute of Technology, Department of Chemical Engineering, Changzhou 213022, P.R. China

autor

Wang J. F.

• School of Mathematics and Chemical Engineering, Changzhou Institute of Technology, Department of Chemical Engineering, Changzhou 213022, P.R. China

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Uwagi

Opracowanie rekordu w ramach umowy 509/P-DUN/2018 ze środków MNiSW przeznaczonych na działalność upowszechniającą naukę (2018).