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Synthesis of Silica Nanoparticles from Sodium Silicate and Carbon Dioxide as Reactants

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Warianty tytułu
Języki publikacji
EN
Abstrakty
EN
In this study, Taylor-vortex reactor was adopted to synthesize silica nanoparticles from sodium silicate solution and carbon dioxide. The outstanding advantages of the reactor have been demonstrated by comparing the synthesis results of silica nanoparticles by Erlenmeyer reactor. The results showed that silica particles synthesized from Taylor-vortex reactor are smaller in size than silica particles synthesized from the Erlenmeyer reactor. SEM images and histogram of particle size distribution obtained from experiments clearly exhibited that the concentration of SiO2 in the solution, reaction temperature, and rotation speed of the cylinder significantly affected morphology as well as size of the silica particles.
Twórcy
  • Tech University of Korea, Department of Chemical Engineering and Biotechnology, 237, Siheung-si, Gyeonggi-do 15073, Republic of Korea
  • Tech University of Korea, Department of Chemical Engineering and Biotechnology, 237, Siheung-si, Gyeonggi-do 15073, Republic of Korea
autor
  • Bio Nano Korea Co. Ltd., 237, Siheung-si, Gyeonggi-do 15073, Republic of Korea
  • Tech University of Korea, Department of Chemical Engineering and Biotechnology, 237, Siheung-si, Gyeonggi-do 15073, Republic of Korea
Bibliografia
  • [1] D.E. Canfield, E. Kristensen, B. Thamdrup, Aquatic Geomicrobiology. Adv. Mar. Biol. 48, 441-463 (2005). DOI: https://0.1016/S0065-2881(05)48017-7
  • [2] D. Savvas, G. Ntatsi, Review: Biostimulant activity of silicon in horticulture. Sci. Hortic. 196, 66-81 (2015). DOI: https://doi.org/10.1016/j.scienta.2015.09.010
  • [3] X. Cai, R.Y. Hong, L.S. Wang, X.Y. Wang, H.Z. Li, Y. Zheng, D.G. Wei, Synthesis of silica powders by pressured carbonation. Chem. Eng. J. 151, 380-386 (2009). DOI: https://doi.org/10.1016/j.cej.2009.03.060
  • [4] R. Dewatia, Suprihatinb, K. Sumadac, S. Muljani, Precipitated Silica from Sodium Silicate by CO2 on Fixed Bed Column. Materials Science Forum 966, 14-18 (2019). DOI: https://doi.org/10.4028/www.scientific.net/MSF.966.14
  • [5] B. Zhu, W. Wei, G. Ma, Y. Zhuang, J. Liu, L. Song, X. Hu, H. Wang, J. Li, A pressurized carbonation sol-gel process for preparing large pore volume silica and its performance as a flatting agent and an adsorbent. J. Supercrit. Fluids 97, 1-5 (2015). DOI: https://doi.org/10.1016/j.supflu.2014.11.006
  • [6] Y. Huang, P. Li, R. Zhao, L. Zhao, J. Liu A, S. Peng, X. Fu, X. Wang, R. Luo, R. Wang, Z. Zhang, Review: Silica nanoparticles: Biomedical applications and toxicity. Biomed. Pharmacother. 151, 113053 (2022). DOI: https://doi.org/10.1016/j.biopha.2022.113053
  • [7] W.H. Shin, S. Kim, H.M. Jeong, Synthesis and Characterization of Core-Shell Silica-Phosphor Nanoparticles via Sol-Gel Process. J. Korean Powder Metall. Inst. 25 (1), 12-18 (2018). DOI: https://doi.org/10.4150/KPMI.2018.25.1.12
  • [8] F. Akhter, A.A. Rao, M.N. Abbasi, S.A. Wahocho, M.A. Mallah, H. Anees-ur-Rehman, Z.A. Chandio, A Comprehensive Review of Synthesis, Applications and Future Prospects for Silica Nanoparticles (SNPs). Silicon 14, 8295-8310 (2022). DOI: https://doi.org/10.1007/s12633-021-01611-5
  • [9] Y. Zhang, Z. Zhang, D. Feng, F. Zhang, J. Gao, M. Xie, Y. Zhao, S. Sun, G. Chang, Y. Qin, Effect of microbubbles on preparation of precipitated silica by carbonization: physical-chemical structure, kinetic parameters and mass transfer characteristics. Carbon Capture Science & Technology 1, 100002 (2021). DOI: https://doi.org/10.1016/j.ccst.2021.100002
  • [10] T. Ogihara, M. Nomura, Continuous Synthesis of Monodispersed Alumina Particles by the Hydrolysis of Metal Alkoxide Using a Taylor Vortex. KONA Powder and Particle Journal 20, 231-237 (2002). DOI: https://doi.org/10.14356/kona.2002025
  • [11] S.A. Altmeyer, Effect of Axial and Radial Flow on the Hydrodynamics in a Taylor Reactor. Fluids 7 (10), 336 (2022). DOI: https://doi.org/10.3390/fluids7100336
  • [12] S. Musić, N. Filipović-Vinceković, L. Sekovanić, Precipitation of amorphous SiO2 particles and their properties. Braz. J. Chem. Eng. 28 (01), 89-94 (2011). DOI: https://doi.org/10.1590/S0104-66322011000100011
  • [13] I. Joni, Rukiah, C. Panatarani, Synthesis of Silica Particles by precipitation method of sodium silicate: Effect of temperature, pH and mixing technique. AIP Conference Proceedings 2219, 080018 (2020). DOI: https://doi.org/10.1063/5.0003074
Uwagi
This research was supported by grant from Ministry of SMEs and Startups (Collabo R&D, S3249683) and the National Research Foundation of Korea (NRF grant funded by the Korea government (MSIT) (No. RS-2023-00250648).
Typ dokumentu
Bibliografia
Identyfikator YADDA
bwmeta1.element.baztech-35a2461c-d81b-47e3-af68-f09de9fd2c2f
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