Impact of Zn and Ca on dissolution rate, mechanical properties and GFA of resorbable Mg–Zn–Ca metallic glasses

• Autorzy: Nowosielski R. , Cesarz-Andraczke K.

Identyfikatory

DOI

10.1016/j.acme.2017.05.009

• Języki publikacji: EN

Abstrakty

EN

This article presents investigations utility of Mg-based metallic glasses for resorbable orthopedic implants. Exploration of biocompatible Mg–Zn–Ca alloys in order to determine Zn and Ca optimum concentration were conducted, based on three criteria: sufficiently high GFA (glass forming ability), sufficiently high tensile strength, microhardness and the suitable dissolution rate (corrosion rate) in Ringer's solution. Fulfillment of these criteria should ensure bone union before implant dissolution. The optimatization of Ca and Zn concentration in the range of 4–6 at.% Ca and 28–32 at.% Zn was executed. The samples in form of ribbons (0.02–0.05 mm thickness) and rods (about diameter up to 4 mm) with amorphous structure were produced. These investigations allowed to determine the GFA. The optimal results for Mg66Zn30Ca4 and Mg64Zn32Ca4 alloys: tensile strength: 191–166 MPa, microhardness: 291–263 HV and volume of released hydrogen 0.04–0.12 ml/cm2/h. The corrosion studies - immersion and potentiodynamic methods were conducted (including measurement specific corrosion current density for Mg alloys). Finally, a comparative analysis was performed, which indicated the impact of Ca and Zn concentration on: GFA, mechanical properties and dissolution rate of studied metallic glasses.

Słowa kluczowe

EN

magnesium bulk metallic glasses; dissolution rate; hydrogen evolution; resorbable metallic alloys

PL

szkło; wodór; stopy metali

• Wydawca: Springer ; Wrocław University of Science and Technology
• Czasopismo: Archives of Civil and Mechanical Engineering
• Rocznik: 2018
• Tom: Vol. 18, no. 1
• Strony: 1--11
• Opis fizyczny: Bibliogr. 25 poz., rys., tab., wykr.

Twórcy

autor

Nowosielski R.

• Institute of Engineering Materials and Biomaterials, Silesian University of Technology, Gliwice, Poland

autor

Cesarz-Andraczke K.

• Institute of Engineering Materials and Biomaterials, Silesian University of Technology, Gliwice, Poland

Bibliografia

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Uwagi

PL

Opracowanie rekordu w ramach umowy 509/P-DUN/2018 ze środków MNiSW przeznaczonych na działalność upowszechniającą naukę (2018)