Analiza rozmieszczenia pierwiastków w badaniach archeometrycznych z zastosowaniem mikropróbkowania laserowego w spektrometrii mas z jonizacją w plazmie indukcyjnie sprzężonej

• Autorzy: Kępa L. , Then-Obłuska J. , Otmianowska M. , Wagner B.

Warianty tytułu

EN

Elemental distribution in archaeometric studies with the use of micro-destructive laser ablation inductively coupled plasma mass spectrometry

• Języki publikacji: PL

Abstrakty

EN

Laser Ablation Inductively Coupled Plasma Mass Spectrometry (LA-ICP-MS) is one of modern instrumental methods, which use in elemental analysis of cultural heritage objects has recently noticeably increased. The method requires almost no sample preparation and permits direct analysis of solid samples, availing only minute amount of the material. The micro-destructiveness of ablation processes remains usually within the scale acceptable for art historians, conservators, archaeologists and art curators, therefore the capability to perform multi-elemental, ultra trace and isotopic analysis can be fully used during studies of cultural heritage objects. The lack of appropriate matrix-matched certified reference materials and the fractionation effects, which may influence the final quantitative results to a different extent, are widely reported among the main limitations of LA-ICP-MS. Despite these constrains, LA-ICP-MS is a method that can be flexibly tuned to collect the desired elemental information about various cultural heritage objects. This paper focuses on advantages of using LA-ICP-MS in analysis of heterogeneous objects in respect of mapping of elemental distribution either during the onepoint or multi-line ablation executed directly from the surface of the investigated objects. The use of LA-ICP-MS allowed collection of chemical information availing reconstruction of distribution patterns, which reflected important structural characteristic of the small gilded decoration produced in mediaeval times (collection of Gallery of Medieval Art, the National Museum in Warsaw) and archaeological “metal-in-glass”/“sandwich” bead (Nubian collection, the Museum of Archaeology University of Stavanger, Norway). The mediaeval decoration was identified as the gilded (Ag+Au) copper object, which due to corrosion and re-painting has lost their original appearance. The bead was produced from two various types of glass and a metal foil (Ag+Au+Cu) between them. In both cases LA-ICP-MS was used successfully to determine the main elemental composition and to collect information about elemental distribution in the investigated artifact.

Słowa kluczowe

PL

LA-ICP-MS; spektrometria mas z jonizacją w plazmie indukcyjnie sprzężonej; archeometria; obiekty zabytkowe

EN

Inductively Coupled Plasma Mass Spectrometry; LA-ICP-MS; archaeometry; cultural heritage object

• Wydawca: Polskie Towarzystwo Chemiczne
• Czasopismo: Wiadomości Chemiczne
• Rocznik: 2015
• Tom: [Z] 69, 9-10
• Strony: 719--733
• Opis fizyczny: Bibliogr. 24 poz., rys., tab., wykr.

Twórcy

autor

Kępa L.

• Wydział Chemii, Uniwersytet Warszawski, ul. Pasteura 1, 02-093 Warszawa
• Centrum Nauk Biologiczno-Chemicznych Uniwersytetu Warszawskiego, ul. Żwirki i Wigury 101, 02-089 Warszawa

autor

Then-Obłuska J.

• Centrum Archeologii Śródziemnomorskiej Uniwersytetu Warszawskiego, ul. Nowy Świat 4, 00-497 Warszawa

autor

Otmianowska M.

• Muzeum Narodowe w Warszawie, Al. Jerozolimskie 3, 00-495 Warszawa

autor

Wagner B.

• Wydział Chemii, Uniwersytet Warszawski, ul. Pasteura 1, 02-093 Warszawa
• Centrum Nauk Biologiczno-Chemicznych Uniwersytetu Warszawskiego, ul. Żwirki i Wigury 101, 02-089 Warszawa

Bibliografia

• [1] A.L. Gray, Analyst, 1985, 110, 551.
• [2] W. Kopaliński, Słownik wyrazów obcych i zwrotów obcojęzycznych, http://www.slownik-online.pl/ oslowniku.php.
• [3] P.M. Outridge, W. Doherty, D.C. Gregoire, Spectrochim. Acta B, 1996, 51, 1451.
• [4] P.M. Outridge, W. Doherty, D.C. Gregoire, Spectrochim.Acta B, 1997, 52, 2093.
• [5] S.M. Eggins, L.P.J. Kinsley, J.M.G. Shelley, Appl.Surf.Sci., 1998, 127, 278.
• [6] J. Koch, D. Gűnther, Appl. Spectrosc., 2011, 65, 155A.
• [7] T. Luo, Y.Wang, Z. Hu, D. Gűnther, Y. Liu, S. Gao, J. Anal. At. Spectrom., 2015, 30, 941.
• [8] J. Gonzalez, X.L. Mao, J. Roy, S.S. Mao, R.E. Russo, J. Anal. At. Spectrom., 2002, 17, 1108.
• [9] C.C. Garcia, H. Lindner, K. Niemax, J. Anal. At. Spectrom., 2009, 24, 14.
• [10] D. Günther, B. Hattendorf, Trends Anal. Chem., 2005, 24, 255.
• [11] G. Spoto, G. Grasso, Trends Anal. Chem., 2011, 30, 856.
• [12] K.P. Jochum, B. Stoll, K. Herwig, M. Willbold, J. Anal. At. Spectrom., 2007, 22, 112.
• [13] R. Kovacs, S. Schlosser, S.P. Staub, A. Schmiderer, E. Pernicka, D. Günther, J. Anal. At. Spectrom., 2009, 24, 476.
• [14] B. Giussani, D. Monticelli, L. Rampazzi, Anal. Chim. Acta, 2009, 635, 6.
• [15] L. Kępa, M. Otmianowska, D. Walaszek, B. Wagner, Analityka, 2014, 4, 44.
• [16] K.P. Jochum, U. Weis, B. Stoll, D. Kuzmin, Q. Yang, I. Raczek, D.E. Jacob, A. Stracke, K. Birbaum, D.A. Frick, D. Günther, J. Enzweiler, Geostand. Geoanal.Res., 2011, 35, 397.
• [17] B. Wagner, A. Nowak, E. Bulska, J. Kunicki-Goldfinger, O. Schalm, K. Janssens, Microchim.Acta, 2008, 162, 415.
• [18] V. Van der Linden, P. Cosyns, O. Schalm, S. Cagno, K. Nys, K. Janssens, A.Nowak, B. Wagner, E. Bulska, Archaeometry, 2009, 51, 822.
• [18] S. Cagno, M. Mendera, T. Jeffries, K. Janssens, J. Archchaeol. Sci., 2010, 37, 3030.
• [19] L. Dussubieux, B. Gratuze, M. Blet-Lemarquand, J. Archaeol. Sci., 2010, 37, 1646.
• [20] P. Robertshaw, N. Benco, M. Wood, L. Dussubieux, E. Melchiorre, A. Ettahiri, Archaeometry, 2010, 52, 355.
• [21] V.S. Selih, J.T. van Elteren, Anal. Bioanal. Chem., 2011, 401, 745.
• [22] J. Then-Obłuska, Polish Archaeology in Mediterranean, Studies XXIV (2015) w druku.
• [23] J. Then-Obłuska, L. Dussubieux, Archaeological Research in Asia, (2015) w druku.
• [24] T. Säve-Söderbergh, G. Englund, H. Åke-Nordström, Late Nubian cemeteries. The Scandinavian Joint Expedition to Sudanese Nubia, Part 6. Copenhagen, Oslo, and Stockholm: Scandinavian University Books (1981).

Uwagi

Praca została opublikowana w specjalnym numerze „Wiadomości Chemicznych”, poświęconym pamięci Profesora Stanisława Głąba, w 70-tą rocznicę Jego urodzin

Błąd w numeracji bibliografii - podwójny numer 18.