Kinetic investigations of heterogeneous reactor processes – Optimization of experiments

• Autorzy: Szałek Adrian , Szukiewicz Mirosław , Chmiel-Szukiewicz Elżbieta

Identyfikatory

DOI

10.24425/cpe.2021.137337

• Języki publikacji: EN

Abstrakty

EN

A series of steps taken to determine a kinetic equation that describes hydrogenation of propene on nickel catalyst is presented in this study. Mixed factorial design approach, belongs to designing of experiments methods was used to plane experiments. The investigations showed that the method applied makes possible determination of the kinetic equation in a relatively fast and cheap manner since only a few measurement points is required. The equation obtained was verified experimentally and statistically. Both tests showed satisfactory precision of anticipated values of the process rate.

Słowa kluczowe

EN

kinetic equation; hydrogenation of propene; designing of experiments

PL

równanie kinetyczne; uwodornienie propenu; projektowanie eksperymentów

• Wydawca: Komitet Inżynierii Chemicznej i Procesowej Polskiej Akademii Nauk
• Czasopismo: Chemical and Process Engineering
• Rocznik: 2021
• Tom: Vol. 42, nr 1
• Strony: 35--–41
• Opis fizyczny: Bibliogr. 11 poz., rys., tab.

Twórcy

autor

Szałek Adrian

• Rzeszów University of Technology, Faculty of Chemistry, al. Powstańców Warszawy 6, 35-959 Rzeszów, Poland

autor

Szukiewicz Mirosław

• Rzeszów University of Technology, Faculty of Chemistry, al. Powstańców Warszawy 6, 35-959 Rzeszów, Poland

autor

Chmiel-Szukiewicz Elżbieta

• Rzeszów University of Technology, Faculty of Chemistry, al. Powstańców Warszawy 6, 35-959 Rzeszów, Poland

Bibliografia

• 1. Aaserud C., Hilmen A.-M., Bergene E.S.E., Schanke D., Holmena A., 2004. Hydrogenation of propene on cobalt Fischer–Tropsch catalysts. Catal. Lett., 94, 171–176. DOI: 10.1023/B:CATL.0000020541.28174.c7.
• 2. Ahmadigoltapeh, S., Mehranbod, N., Halimejani, H.Z., 2015. Propylene hydrogenation through structured and conventional catalyst beds: Experiment and modelling. J. Nat. Gas Sci. Eng., 27, 822–830. DOI: 10.1016/j.jngse.2015.09.030.
• 3. Brandao L., Fritsch D., Madeira LM., Mendes A.M., 2004. Kinetics of propylene hydrogenation on nanostructured palladium clusters. Chem. Eng. J., 103, 89–97. DOI: 10.1016/j.cej.2004.07.008.
• 4. Carturan G., Enzo S., Ganzerla R., Lenarda M., Zanoni R., 1990. Role of solid-state structure in propene hydrogenation with nickel catalysts. J. Chem. Soc. Faraday Trans., 86, 739–746. DOI: 10.1039/ft9908600739.
• 5. Esfe M.H.,. Rsotamian H, Shabani-Samghabadi A., Arani A.A.A., 2017. Application of three-level general factorial design approach for thermal conductivity of MgO/ water nanofluids. Appl. Therm. Eng., 127, 1194–1199. DOI: 10.1016/j.applthermaleng.2017.07.211.
• 6. Montgomery D.C., 2017. Design and analysis of experiments. 9th ed., Wiley.
• 7. Ozbay N., Yargıc A.Ş., Yarbay-Şahin R.Z., Onal E., 2013. Full factorial experimental design analysis of reactive dye removal by carbon adsorption. J. Chem., 234904. DOI: 10.1155/2013/234904.
• 8. Pachulski A., Schodel R., Claus P., 2012. Kinetics and reactor modeling of a Pd-Ag/Al2O3 catalyst during selective hydrogenation of ethyne. Appl. Catal., A, 445–446, 107–120. DOI: 10.1016/j.apcata.2012.08.018.
• 9. Schweitzer NM., Hu B., Das U., Hacksung K., Greeley J., Curtiss L.A., Stair P.C., Miller J.T., Hock A.S., 2014. Propylene hydrogenation and propane dehydrogenation by a single-site Zn2+ on silica catalyst. ACS Catal., 4, 1091–1098. DOI: 10.1021/cs401116p.
• 10. Sen G.A., 2016. Application of full factorial experimental design and response surface methodology for chromite beneficiation by Knelson concentrator. Minerals, 6, 5. DOI: 10.3390/min6010005.
• 11. Szukiewicz M., Chmiel-Szukiewicz E., Kaczmarski K., Szałek A., 2019. Dead zone for hydrogenation of propylene reaction carried out on commercial catalyst pellets. Open Chem., 17, 295–301. DOI: 10.1515/chem-2019-0037.

Uwagi

Opracowanie rekordu ze środków MNiSW, umowa Nr 461252 w ramach programu "Społeczna odpowiedzialność nauki" - moduł: Popularyzacja nauki i promocja sportu (2021).